Nauki Techniczne

Archives of Foundry Engineering

Zawartość

Archives of Foundry Engineering | 2013 | No 2 |

Abstrakt

The high mechanical properties of the Al-Li-X alloys contribute to their increasingly broad application in aeronautics, as an alternative forthe aluminium alloys, which have been used so far. The aluminium-lithium alloys have a lower specific gravity, a higher nucleation andcrack spread resistance, a higher Young’s module and they characterize in a high crack resistance at lower temperatures. The aim of theresearch planned in this work was to design an aluminium alloy with a content of lithium and other alloy elements. The research includedthe creation of a laboratorial melt, the microstructure analysis with the use of light microscopy, the application of X-ray methods to identify the phases existing in the alloy, and the microhardness test.
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A proper management of sand grains of moulding sands requires knowing basic properties of the spent matrix after casting knocking out. This information is essential from the point of view of the proper performing the matrix recycling process and preparing moulding sands with reclaimed materials. The most important parameter informing on the matrix quality – in case of moulding sands with organic binders after casting knocking out – is their ignition loss. The methodology of estimating ignition loss of spent moulding sands with organic binder– after casting knocking out - developed in AGH, is presented in the paper. This method applies the simulation MAGMA software, allowing to determine this moulding sand parameter already at the stage of the production preparation.
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Magnesium alloys due to their low density and high strength-to-weight ratio are promising material for the automotive and aerospace industries. Many elements made from magnesium alloys are produced by means of sand casting. It is essential to investigate impact of the applied mould components on the microstructure and the quality of the castings. For the research, six identical, 100x50x20mm plates has been sand cast from the Elektron 21 magnesium casting alloy. Each casting was fed and cooled in a different way: one, surrounded by mould sand, two with cast iron chills 20mm and 40mm thick applied, another two with the same chills as well as feeders applied and one with only the feeder applied. Solid solution grain size and eutectics volume fraction were evaluated quantitatively in Met-Ilo program, casting defects were observed on the scanning electron microscope Hitachi S3400N. The finest solid solution grain was observed in the castings with only the chills applied. Non metallic inclusions were observed in each plate. The smallest shrinkage porosity was observed in the castings with the feeders applied.
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In this paper the effects of titanium addition in an amount up to 0.13 wt.% have been investigated to determine their effect on the microstructure and mechanical properties of Thin Wall Vermicular Graphite Iron Castings (TWVGI). The study was performed for thinwalled iron castings with 3-5 mm wall thickness and for the reference casting with 13 mm. Microstructural changes were evaluated by analyzing quantitative data sets obtained by image analyzer and also using scanning electron microscope (SEM). Metallographic examinations show that in thin-walled castings there is a significant impact of titanium addition to vermicular graphite formation. Thinwalled castings with vermicular graphite have a homogeneous structure, free of chills, and good mechanical properties. It may predispose them as a potential use as substitutes for aluminum alloy castings in diverse applications.
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This publication describes research on the course of the process of cross-linking new BioCo polymer binders - in the form of water-based polymer compositions of poly(acrylic acid) or poly(sodium acrylate)/modified polysaccharide - using selected physical and chemical factors. It has been shown that the type of cross-linking factor used influences the strength parameters of the moulding sand. The crosslinking factors selected during basic research make it possible to obtain sand strengths similar to those of samples of sands bonded with commercial binders. Microwave radiation turned out to be the most effective cross-linking factor in a binder-matrix system. It was proven that adsorption in the microwave radiation field leads to the formation of polymer lattices with hydrogen bonds which play a major role in maintaining the formed cross-linked structures in the binder-matrix system. As a result, the process improves the strength parameters of the sand, whereas the hardening process in a microwave field significantly shortens the setting time.
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Due to the presence of harmful substances in resins those mould sands may be hazardous to the natural environment and workers. The general assessment of harmfulness of sands used for molds and cores encompasses 2 basic points: emission of hazardous substances during processes of preparing sands, pouring mold with liquid metals (high temperatures), cooling and shaking-out; possibility of washing out hazardous substances from used sands to the environment, during storage or economic use outside foundries. We present the results of research on the emission of BTEX compounds from mould sands with phenolic resins during pouring liquid metal of different temperature (cast iron and Al alloy). The research was conducted according to the original method prepared by the authors, which has been used for years in cooperation with various foundries (Poland, abroad).
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More and more foundry plants applying moulding sands with water-glass or its substitutes for obtaining the high-quality casting surface at the smallest costs, consider the possibility of implementing two-layer moulds, in which e.g. the facing sand is a sand with an organic binder (no-bake type) and the backing sand is a sand with inorganic binder. Both kinds of sands must have the same chemical reaction. The most often applied system is the moulding sand on the water-glass or geopolymer bases – as the backing sand and the moulding sand from the group of self-hardening sands with a resol resin – as the facing sand. Investigations were performed for the system: moulding sand with inorganic GEOPOL binder or moulding sand with water glass (as a backing sand) and moulding sand, no-bake type, with a resol resin originated from various producers: Rezolit AM, Estrofen, Avenol NB 700 (as a facing sand). The LUZ apparatus, produced by Multiserw Morek, was adapted for investigations. A special partition with cuts was mounted in the attachment for making test specimens for measuring the tensile strength. This partition allowed a simultaneous compaction of two kinds of moulding sands. After 24 hours of hardening the highest values were obtained for the system: Geopol binder - Avenol resin.
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This paper presents the results of research which is part of studies carried out under the project POIG.01.01.02-00-015/09 "Advanced Materials and Technologies", one of the aims of which is to introduce new, environment-friendly, inorganic binders to the production of castings from non-ferrous metals. The paper presents the results of research on the management of waste moulding sands prepared according to the new technology, including their multiple reclamation and management of post-reclamation waste. Studies of multiple reclamation are a continuation of the preliminary research described earlier. The programme of the studies described in this paper also included validation of the results under industrial conditions.
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Abstrakt

Due to the presence of harmful substances in resins those mould sands may be hazardous to the natural environment and workers. The general assessment of harmfulness of sands used for molds and cores encompasses 2 basic points: emission of hazardous substances during processes of preparing sands, pouring mold with liquid metals (high temperatures), cooling and shaking-out; possibility of washing out hazardous substances from used sands to the environment, during storage or economic use outside foundries. We present the results of research on the emission of BTEX compounds from mould sands with phenolic resins during pouring liquid metal of different temperature (cast iron and Al alloy). The research was conducted according to the original method prepared by the authors, which has been used for years in cooperation with various foundries (Poland, abroad).
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Abstrakt

Determined was quantitative effect of nickel equivalent value on austenite decomposition degree during cooling-down castings of Ni-MnCu cast iron. Chemical composition of the alloy was 1.8 to 5.0 % C, 1.3 to 3.0 % Si, 3.1 to 7.7 % Ni, 0.4 to 6.3 % Mn, 0.1 to 4.9 % Cu, 0.14 to 0.16 % P and 0.03 to 0.04 % S. Analysed were castings with representative wall thickness 10, 15 and 20 mm. Scope of the examination comprised chemical analysis (including WDS), microscopic observations (optical and scanning microscopy, image analyser), as well as Brinell hardness and HV microhardness measurements of structural components.
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Bending strength, thermal and electric conductivity and microstructure examinations of Cu based composite materials reinforced with Saffil alumina fibres are presented. Materials were produced by squeeze casting method applying the designed device and specially elaborated production parameters. Applying infiltration pressure of 90MPa and suitable temperature parameters provided manufacturing of copper based composite materials strengthened with Saffil alumina fibres characterized by the low rest porosity and good fibre-matrix interface. Three point bending tests at temperatures of 25, 100 and 300ºC were performed on specimens reinforced with 10, 15 and 20% of Saffil fibres. Introduced reinforcement effected on the relatively high bending strengths at elevated temperatures. In relation to unreinforced Cu casting strength of composite material Cu – 15vol.% Saffil fibres increase by about 25%, whereas at the highest applied test temperature of 300o C the improvement was almost 100%. Fibres by strengthening of the copper matrix and by transferring loads from the matrix reduce its plastic deformation and hinder the micro-crack developed during bending tests. Decreasing of thermal and electrical conductivity of Cu after incorporating fibres in the matrix are relatively small and these properties can be acceptable for electric and thermal applications.
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A technology of sands with water glass hardened by liquid esters is a cheap and ecologic method of producing moulding sands. Due to these advantages, this technology is still very important in several foundry plants for production of heavy iron and steel castings. Reclamation of the mixed moulding and core sands generates significant amounts of dusts, which require further treatments for their reuse. The results of investigations of a pressureless granulation of dusts generated in the dry mechanical reclamation process of the mixture consisting in app. 90 % of moulding sands from the Floster S technology and in 10 % of core sands with phenolic resin resol type, are presented in the hereby paper. Investigations were aimed at obtaining granulates of the determined dimensional and strength parameters. Granules were formed from the mixture of dusts consisting of 75 mass% of dusts after the reclamation of sands mixture and of 25 mass% of dusts from bentonite sands processing plant. Wetted dusts from bentonite sands were used as a binding agent allowing the granulation of after reclamation dusts originated from the mixed sands technology.
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High-vanadium cast iron is the white cast iron in which the regular fibrous γ + VC eutectic with the volume fraction of vanadium carbide amounting to about 20% crystallises. This paper presents the results of studies on high-vanadium cast iron subjected to the inoculation treatment with magnesium master alloy. The aim of this operation is to change the morphology of the crystallising VC carbides from the fibrous shape into a spheroidal one. The study also examines the effect of the amount of the introduced inoculant on changes in the morphology of the crystallising VC carbides. To achieve the goals once set, metallographic studies were performed on high-vanadium cast iron of eutectic composition in base state and after the introduction of a variable content of the inoculant. The introduction of magnesium-based master alloy resulted in the expected changes of microstructure. The most beneficial effect was obtained with the introduction of 1.5% of magnesium master alloy, since nearly half of the crystallised vanadium carbides have acquired a spheroidal shape.
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The study presents the results of research aimed at the construction of a model of the relationship between the physical properties of metal and the types of toughening treatment and modifiers used in the modification of BA1044 alloy. Samples of melts were subjected to four variants of the heat treatment and to five types of modification. Studies of the samples consisted in measurements of five physical parameters. Consequently, it was necessary to seek a relationship between the nine input parameters and five output parameters. With this number of the variables and a limited number of samples, searching for the relationships by way of statistical methods was obviously impossible, so it was decided to create an approximate model through the use of fuzzy logic. This study describes the process of creating a model and presents the results of some simulation experiments that confirm the validity of the correct approach.
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The purpose of the presented experiment was to develop an effective water glass modifier. In the conducted research, an attempt was made to determine the effect of modifier addition on the wettability of quartz grains, viscosity and cohesion of binder and strength Rm U of the sand mixture. Water glass modification was carried out with, obtained in electrochemical process [1], colloidal suspension of ZnO nanoparticles in methanol (modifier I) or propanol (modifier II), characterised by a constant molar concentration of c = 0.3 M. It was demonstrated that the addition of a colloidal suspension of ZnO nanoparticles in propanol (modifier II) had a significant effect on wettability of quartz grains improvement without the accompanying increase in binder viscosity. Testing the mechanical properties Rm U of sand mixtures containing modified binder (modifier II) hardened at ambient conditions showed an approximately 28% increase in strength compared with the Rm U of the sand bonded with an unmodified binder.
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Organic binders applied in foundry plants based on synthetic resins, from the one side influence obtaining the required technological properties by the moulding sand and – in consequence – obtaining good quality castings, and on the other side are the source of volatile organic compounds (VOC). Together with synthetic resins their hardeners, which although added in very small amounts emit during their thermal decomposition substances negatively influencing the natural environment, are also used. Both, resins and hardeners only at the influence of high temperatures accompanying moulds pouring with liquid metal generate harmful volatile organic compounds including compounds from the BTEX group. Investigations of the temperature influence on the kind and amount of organic compounds formed during the thermal decomposition of selected binders and hardeners and their mixtures allow to determine temperature ranges the most favourable for emitting harmful substances as well as to compare their emission from the selected materials. The aim of this study was the determination the temperature influence on formation substances from the BTEX group, during thermal decomposition of the selected binder, its hardener and their mixture. The BTEX group emission constitutes one of the basic criteria in assessing the harmfulness of materials applied for moulding and core sands and it can undergo changes in dependence of the applied system resin-hardener. Investigations were carried out on the specially developed system for the thermal decomposition of organic substances in the temperature range: 5000 C – 13000 C, at the laboratory scale. The investigations subject was the furan resin, its hardener and hardened furan resin. The assessment of the emission degree of the BTEX group in dependence of the system subjected to the temperature influence was performed, within the studies. The temperature range, in which maximal amounts of benzene, toluene, ethylbenzene and xylenes were emitted from tested materials – was defined. The qualitative and quantitative analysis of the BTEX group were carried out with using the gas chromatography technique coupled with the mass spectrometry (GC/MS).
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The possibility of controlling the solidification and cooling time of castings creates prospects of improving their structure and by the same their properties. Thermal properties of the mould constitute therefore an important factor which is necessary to consider while seeking for the mentioned improvement. The presented work illustrates the method of determining some basic thermal coefficients of moulding material, i.e. the coefficient of temperature equalisation a2, known also as the temperature diffusivity, and the heat accumulation coefficient b2, which characterises the ability of moulding material to draw away the heat from a casting. The method consists in experimental determining the temperature field within the mould during the processes of pouring, solidification and cooling of the casting. The performed measurements allow for convenient and exact calculations of the sought-after coefficients. Examinations were performed for the oil bonded moulding sand of trade name OBB SAND ‘E’. The experiment showed that the obtained value of b2 coefficient differs from the value calculated on the basis of theoretical considerations available in publications. Therefore it can be stated that theoretical calculations of the heat accumulation coefficient are thus far not sufficient and not quite reliable, so that these calculations should be verified experimentally.
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The paper summarises results of measurements of remelting area geometry, thermal efficiency and melting efficiency characterising the surface remelting process applied to castings of MAR-M-509 cobalt alloy. The remelting process was carried out with the use of GTAW (Gas Tungsten Arc Welding) method in protective atmosphere of helium, at the electric current intensity in the range from 100 A to 300 A, and the electric arc scanning velocity vs in the range from 200 mm/min to 800 mm/min. The effect of current intensity and electric arc scanning velocity on geometrical parameters of remeltings, thermal efficiency, and melting efficiency characterising the remelting process has been determined.
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Substituting of ethyl silicate with ecologic sols of colloidal silica in the investment casting technology, resulting from the increased demands concerning environmental protection, caused the prolongation of production cycle for precision castings produced in multi-layer thin-walled ceramic shell moulds. Modification of Sizol 030 binder with benzoyl peroxide, proposed in the paper, was aimed at restriction of time needed for realization of a single layer of the shell mould, and by the same, of such a mould as a whole. Examination of kinetics of the drying process were held for the layers made of prepared moulding material and the influence of binder modification on the mould curing time was determined.
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The Mg-RE alloys are attractive, constructional materials, especially for aircraft and automotive industry, thanks to combination of low density, good mechanical properties, also at elevated temperature, and good castability and machinability. Present paper contains results of fatigue resistance test carried out on Elektron 21 magnesium alloy, followed by microstructural and fractographical investigation of material after test. The as-cast material has been heat treated according to two different procedures. The fatigue resistance test has been conducted with 106 cycles of uniaxial, sine wave form stress between 9 MPa and 90 MPa. Fractures of specimens, which ruptured during the test, have been investigated with scanning electron microscope. The microstructure of specimens has been investigated with light microscopy. Detrimental effect of casting defects, as inclusions and porosity, on fatigue resistance has been proved. Also the influence of heat treatment's parameters has been described.
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The new investigation method of a permeability of ceramic moulds applied in the investment casting technology, is presented in the paper. Some concepts of performing permeability measurements are shown. Investigations in which the influence of the solid phase fraction in the liquid ceramic moulding sand (LCMS) on a permeability of a multi-layer ceramic mould were performed and discussed. The permeability was estimated during two the most important stages of the technological process: in the first – after wax melting and in the second – after mould annealing. Also an influence of the matrix grain sizes (material for sprinkling) on a ceramic mould permeability was estimated.
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The paper present the examination results concerning mechanical properties of castings made of AlSi7MG alloy in correlation both with the most significant squeeze casting parameters and with the modification treatment. Experiments were planned and held according to the 2 3 factorial design. The regression equations describing the influence of the squeeze pressure, the mould temperature, and the quantity of strontium modifier on the strength and elongation of the examined alloy were obtained. It was found that the main factor controlling the strength increase is the squeeze pressure, while the plasticity (A5 ) of the alloy is affected most advantageously by modification. The application of modification treatment in squeeze casting technology enables for production of the slab-type castings made of AlSi7Mg alloy exhibiting strength at the level of 230 MPa and elongation exceeding 14%.
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Redakcja

CHIEF EDITORS
Editor
J. Szajnar
Deputy Editor
J. Jezierski

SUBJECT EDITORS
Theoretical Aspects of Casting Processes
K. Eigenfeld – Freiberg, Germany
E. Guzik – Kraków, Poland
T. G. Mathia - Lyon, France
W. Wołczyński – Kraków, Poland
Innovative Foundry Technologies and Materials
T. Elbel – Ostrava, Czech Republic
Z. Ignaszak – Poznań, Poland
O. P. Pandey – Punjab, India
A. Pereira - Vigo, Spain
Foundry Processes Computer Aiding
B. Mochnacki – Częstochowa, Poland
J. Roučka – Brno, Czech Republic
J.S. Suchy – Kraków, Poland
Mechanization, Automation and Robotics in Foundry
J. Bast – Freiberg, Germany
R. Wrona – Kraków, Poland
Transport Systems in Foundry
J. Dańko – Kraków, Poland
Z. Li – Shijiazhuang, China
Castings Quality Management
D. Bolibruchova– Żilina, Slovak Republic
J. D. B. de Mello - Santa Monica, Brazil
M. Perzyk – Warszawa, Poland
Environment Protection
M. Holtzer – Kraków, Poland
H. Polzin – Freiberg, Germany
J. Sobczak – Kraków, Poland
I. Volchok – Zaporizhzhya, Ukraine

EDITORIAL ADVISORY BOARD
J. Braszczyński – Częstochowa, Poland
B. K. Dhindaw – Rupnagar, India
L. A. Dobrzański – Gliwice, Poland
W. A. Hufenbach – Dresden, Germany
P. Jelínek – Ostrava, Czech Republic
L. Jeziorski – Częstochowa, Poland
J. Lacaze – Toulouse, France
V. L. Naydek – Kiev, Ukraine
A. Passerone – Genova, Italy
I. Riposan – Bucharest, Romania
F. Romankiewicz – Zielona Góra, Poland
A. Sládek – Żilina, Slovak Republic

INTERNATIONAL SCIENTIFIC REVIEW COMMITTEE
S. A. Argyropoulos – Toronto, Canada
M. Azadi – Tehran, Iran
Y. Babaskin – Kiev, Ukraine
K. Bako – Miskolc, Hungary
E. Bayraktar – Paris, France
L. Bechný – Zilina, Slovak Republic
V. Bednarova - Ostrava, Czech Republic
F. Bińczyk – Katowice, Poland
A. Bokota – Częstochowa, Poland
G.P. Borisov – Kiev, Ukraine
A. Bydałek – Kraków, Poland
C. H. Cáceres – Brisbane, Australia
J. Čech – Brno, Czech Republic
L. Q. Chen – Shenyang, China
A. Chojecki – Kraków, Poland
M. Cholewa – Gliwice, Poland
I. A. Dibrov – Moscow, Russia
D. Dispinar – Istanbul, Turkey
S. M. Dobosz – Kraków, Poland
V. I. Dubodelov – Kiev, Ukraine
A. Fedoryszyn – Krakow, Poland
J. Głownia – Kraków, Poland
K. Granat – Wrocław, Poland
J. Hampl – Ostrava, Czech Republic
J. Helber – Düsseldorf, Germany
M. Hetmańczyk – Katowice, Poland
M. Horáček – Brno, Czech Republic
M. Kaczorowski – Warszawa, Poland
W. Kapturkiewicz – Kraków, Poland
R. Kawalla – Freiberg, Germany
Z. Konopka – Czestochowa, Poland
D. Kopyciński – Kraków, Poland
W. K. Krajewski – Kraków, Poland
Z. Libo – Beijing, China
P. Lichy – Ostrava, Czech Republic
Y. P. Lim – Setapak, Malaysia
T. Lipiński – Olsztyn, Poland
E. Majchrzak – Gliwice, Poland
A. Mityayev - Zaporizhzhya, Ukraine
M. Murgaš – Trnava, Slovak Republic
I. Nová – Liberec, Czech Republic
W. Orłowicz – Rzeszów, Poland
T. Pacyniak – Łódź, Poland
B. Piekarski – Szczecin, Poland
A. Rimmer – West Bromwich, United Kingdom
S. Samavedam – Hyderabad, India
P. Schumacher – Leoben, Austria
N. Sczygiol – Częstochowa, Poland
P. Skočovský – Żilina, Slovak Republic
M.S. Soiński – Częstochowa, Poland
J. Sokolowski – Ottawa, Kanada
K. V. Sudhakar – Butte, USA
B. G. Thomas - Champaign, USA
M. Trbižan – Ljubljana, Slovenia
J. Vuorinen – Tampere, Finland
E. Ziółkowski – Kraków, Poland
J. Zych – Kraków, Poland

ASSOCIATE EDITORS
D. Bartocha – Gliwice, Poland, - editorial secretary
J. Suchoń – Gliwice, Poland - editorial secretary
J. Szymszal – Katowice, Poland, Statistic Editor
A. Dulska – Gliwice, Poland
M. Kondracki – Gliwice, Poland
C. Borek –Chicago, USA, Language Editor

 

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