Spectral remote sensing is a very popular method in atmospheric monitoring. The paper presents an approach that involves mid-infrared spectral measurements of combustion processes. The dominant feature in this spectral range is CO2 radiation, which is used to determine the maximum temperature of nonluminous flames. Efforts are also made to determine the temperature profile of hot CO2, but they are limited to the laboratory conditions. The paper presents an analysis of the radiation spectrum of a non-uniform-temperature gas environment using a radiative transfer equation. Particularly important are the presented experimental measurements of various stages of the combustion process. They allow for a qualitative description of the physical phenomena involved in the process and therefore permit diagnostics. The next step is determination of a non-uniform-temperature profile based on the spectral radiation intensity with the 8 m optical path length.
This paper addresses problems arising from in situ measurement of gas content and temperature. Such measurements can be considered indirect. Transmittance or natural radiation of a gas is measured directly. The latter method (spectral radiation measurement) is often called spectral remote sensing. Its primary uses are in astronomy and in the measurement of atmospheric composition. In industrial processes, in situ spectroscopic measurements in the plant are often made with an open path Fourier Transform Infrared (FTIR) spectrometer. The main difficulty in this approach is related to the calibration process, which often cannot be carried out in the manner used in the laboratory. Spectral information can be obtained from open path spectroscopic measurements using mathematical modeling, and by solving the inverse problem. Determination of gas content based on spectral measurements requires comparison of the measured and modeled spectra. This paper proposes a method for the simultaneous use of multiple lines to determine the gas content. The integrated absorptions of many spectral lines permits calculation of the average band absorption. An inverse model based on neural networks is used to determine gas content based on mid-infrared spectra at variable temperatures.
Open-Path Fourier Transform Infrared OP-FTIR spectrometers are commonly used for the measurement of atmospheric pollutants and of gases in industrial processes. Spectral interpretation for the determination of gas concentrations is based on the HITRAN database line-by-line modeling method. This article describes algorithms used to model gas spectra and to determine gas concentration under variable temperatures. Integration of individual rotational lines has been used to reduce the impact of spectrometer functions on the comparison of both measured and synthetic modeled spectra. Carbon monoxide was used as an example. A new algorithm for gas concentration retrieval consisting of two ensemble methods is proposed. The first method uses an ensemble of local models based on linear and non-linear PLS (partial least square) regression algorithms, while the second is an ensemble of a calibration set built for different temperatures. It is possible to combine these methods to decrease the number of regression models in the first ensemble. These individual models are appropriate for specific measurement conditions specified by the ensemble of the calibration set. Model selection is based on comparison of gas spectra with values determined from each local model
The paper presents a method of measuring the angle of rotation and twist using a tilted fibre Bragg grating (TFBG) periodic structure with a tilt angle of 6◦, written into a single-mode optical fibre. It has been shown that the rotation of the sensor by 180◦ causes a change in the transmission coefficient from 0.5 to 0.84 at a wavelength of 1541.2 nm. As a result of measurements it was determined that the highest sensitivity can be obtained for angles from 30◦ to 70◦ in relation to the basic orientation. The change in the transmission spectrum occurs for cladding modes that change their intensity with the change in the polarization of light propagating through the grating. The same structure can also be used to measure the twist angle. The possibility of obtaining a TFBG twist by 200◦ over a length of 10 mm has been proved. This makes it possible to monitor both the angle of rotation and the twist of an optical fibre with the fabricated TFBG.