Horizontal centrifugal casting is an effective method for the production of hollow metal with good mechanical properties, low defect, cast to size and relatively cheap. The ability of a metal to satisfy the above requirements highly depends on its microstructure. In this study, the relationship between microstructural parameters such as grain size and the amount of phases with bulk hardness of SnCu4Pb3 is concerned in three areas of the product. Consequently, to achieve the desired hardness of the product in a particular area, the interaction of two factors of the microstructure including, grain size and particles amount of the hard intermetallic compositions (Cu6Sn5) should be noted.
Particles of the Fe-Al type (less than 50 µm in diameter) were sprayed onto the 045 steel substrate by means of the detonation method. The TEM, SAED and EDX analyses revealed that the Fe-Al particles have been partially melted in the experiment of coating formation. Particle undergone melting even within about 80% of its volume. Therefore, solidification of the melted part of particles was expected. Solidification differed significantly due to a large range of chemical composition of applied particles (from 15 at.% Al up to 63 at.% Al). A single particle containing 63 at.% Al was subjected to the detailed analysis, only. The TEM / SAED techniques revealed in the solidified part of particle three sub-layers: an amorphous phase, A ε , periodically situated FeAl + Fe2Al5 phases, and a non-equilibrium phase, Nε . A hypothesis dealing with the inter-metallic phases formation in such a single particle of the nominal composition 0 N = 0.63 is presented. At first, the solid / liquid system is treated as an interconnection: substrate liquid nonmelted particle part / / . Therefore, it is suggested that the solidification occurs simultaneously in two directions: towards a substrate and towards a non-melted part of particle. The solidification mechanism is referred to the Fe-Al meta-stable phase diagram. It is shown that the melted part of particle solidifies rapidly according to the phase diagram of meta-stable equilibrium and at a significant deviation from the thermodynamic equilibrium.