To investigate the mechanical properties of tunnel lining concrete under different moderate-low strain rates after high temperatures, uniaxial compression tests in association with ultrasonic tests were performed. Test results show that the ultrasonic wave velocity and mass loss of concrete specimen begin to sharply drop after high temperatures of 600°C and 400°C, respectively, at the strain rates of 10‒5s‒1 to 10‒2s‒1. The compressive strength and elastic modulus of specimen increase with increasing strain rate after the same temperature, but it is difficult to obtain an evident change law of peak strain with increasing strain rate. The compressive strength of concrete specimen decreases first, and then increases, but decreases again in the temperatures ranging from room temperature to 800°C at the strain rates of 10‒5s‒1 to 10‒2s‒1. It can be observed that the strain-rate sensitivity of compressive strength of specimen increases with increasing temperature. In addition, the peak strain also increases but the elastic modulus decreases substantially with increasing temperature under the same strain rate.
The results presented in this article are part of the research on fatigue life of various foundry alloys carried out in recent years in the Lukasiewicz Research Network – Institute of Precision Mechanics and AGH University of Science and Technology, Faculty of Foundry Engineering. The article discusses the test results obtained for the EN-GJS-600-3 cast iron in an original modified low-cycle fatigue test (MLCF), which seems to be a beneficial research tool allowing its users to evaluate the mechanical properties of materials with microstructural heterogeneities under both static and dynamic loads. For a comprehensive analysis of the mechanical behaviour with a focus on fatigue life of alloys, an original modified low cycle fatigue method (MLCF) adapted to the actually available test machine was used. The results of metallographic examinations carried out by light microscopy were also presented. From the analysis of the results of the conducted mechanical tests and structural examinations it follows that the MLCF method is fully applicable in a quick and economically justified assessment of the quality of ductile iron after normalizing treatment.
The impacts of industrial wastewater contamination on the geotechnical properties of clayey soil have been studied in the research presented in this paper. The contaminant in question is industrial wastewater released from Thi-Qar oil refinery as a by-product of production, and the soil samples obtained from Thi-Qar oil refinery plant in Al-Nassyriah (a city located in the south of Iraq). The geotechnical properties of contaminated soil samples were compared with those of intact soil to measure the effects of such a contaminant. The soil samples were obtained from three locations in the study area; representing the highly contaminated area, the slightly contaminated area, and the intact area used as a reference for comparison of test results. The results of the tests showed that the contaminant causes an increase of natural moisture content, field unit weight, Atterberg’s limits, and maximum dry unit weight, as well as an increase of the compression index and the coefficient of vertical consolidation. Also, the contaminant causes a decrease in specific gravity, the optimum moisture content initial void ratio, the swelling index, the coefficient of permeability, and cohesion between soil particles.
Peat soils (FAO — Gelic Histosols) in the southern Bellsund coast area occur on slopes and terraces. They are formed in places favourable for plant growth, i.e. adequately moistened and fertilized largely with bird excrements. These formations belong to moss peats which are generally decomposed weakly and moderately to about 0.5 m depth. Their content of organic matter is equal to about 30-90%, but it is higher in terrace peats. The latter are more acidified than slope peats. The reaction both of slope and terrace peat soils is as a rule, slightly acid or neutral, and CaC03 content does not exceed 10%. As regards the content of macroelements, that of Al is the highest followed by Ca, Fe, Mg and P. Little K and Ti, and only traces of Na are found. Microelements occur in the following sequence: Mn, Zn, Cu, Cr, Ni, Pb, Co, Cd. Particularly Mn, Zn as well as Cu and Cd were found in a higher concentration. Slope peat soils are richer in macro- and microelements than terrace ones, e.g. 4 times in the case of Mg. Peat soils poor in ash parts (up to 25% ash), contain the fewest elements. Some regularities concern also a vertical distribution of the particular profiles but only with regard to terrace peat soils.
The Legnica deposit is one of the most prospective in the context of future lignite mining. Its extraction will be inseparable from the removal of the rocks of the overburden, the volume of which is very large. Due to the raw material properties, some of the rocks can be classified as accompanying minerals. The raw material identification of overburden sediments in the Legnica lignite deposit is insufficient. So far, they haven’t been the subject of detailed and comprehensive research to prove their usefulness. The article was a summary of the knowledge on this subject. The following should be included in the accompanying minerals: Quaternary sands and gravels, tertiary sands and clays (Poznan clays). They are present in two colour variants in the Legnica deposit - and fiery. The mineral composition of greenish-blue clays allows them to be included in illite-kaolinite- smectite varieties, in turn fiery clays as kaolinite-illite-smectite varieties. The tertiary clays are a very useful raw material for the production of building materials. In addition, they are potential mineral sorbents due to the nature of the association of clay minerals (occurrence of montmorillonite). They also show suitability for building waterproofing barriers. Quaternary gravels and sands, developed in the overburden Legnica deposit are differentiated raw materials. Some of them are raw materials for the construction industry. The glacial tills can be used as a component of ceramic mixtures. Tertiary sands can be used as a proppant material. The information on the raw material properties of these sediments will be one of the essential criteria for their treatment as accompanying minerals. Minerals accompanying those developed in the Legnica deposit should be exploited and deposited selectively. The creation of anthropogenic deposits accumulating these minerals will provide the possibility of their use for decades after the termination of operation.
For the purpose of making of a solid body of an electric guitar the acoustic- and mechanical properties of walnut- (Juglans regia L.) and ash wood (Fraxinus excelsior L.) were researched. The acoustic properties were determined in a flexural vibration response of laboratory conditioned wood elements of 430 × 186 × 42.8 mm used for making of a solid body of an electric guitar. The velocity of shearand compression ultrasonic waves was additionally determined in parallel small oriented samples of 80 × 40 × 40 mm. The research confirmed better mechanical properties of ash wood, that is, the larger modulus of elasticity and shear modules in all anatomical directions and planes. The acoustic quality of ash wood was better only in the basic vibration mode. Walnut was, on the other hand, lighter and more homogenous and had lower acoustic- and mechanical anisotropy. Additionally, reduced damping of walnut at higher vibration modes is assumed to have a positive impact on the vibration response of future modelled and built solid bodies of electric guitars. When choosing walnut wood, better energy transfer is expected at a similar string playing frequency and a structure resonance of the electric guitar.
Heating of steel or structural aluminum alloys at a speed of 2 to 50 K/min – characterizing the fire conditions – leads to a reduction in mechanical properties of the analyzed alloys. The limit of proportionality fp, real fy and proof f₀₂ yield limit, breaking strength fu and longitudinal limit of elasticity E decrease as the temperature increases. Quantitative evaluation of the thermal conversion in strengths of structural alloys is published in Eurocodes 3 and 9, in the form of dimensionless graphs depicting reduction coefficients and selected (tabulated) discrete values of mechanical properties. The author’s proposal for an analytical formulation of code curves describing thermal reduction of elasticity modulus and strengths of structural alloys recommended for an application in building structures is presented in this paper.
The transitional siliceous rocks from the Belchatow lignite deposit belong to the deposits with heterogeneous petrographic composition. The research allows us to identify among others, opoka-rocks and gaizes. The mineralogical-chemical analysis proves that the main ingredients of the studied rocks commonly used as building material are minerals of the SiO₂ group. Laboratory tests show that the nature of siliceous mineral phases has several effects on the geomechanical parameters of the studied transitional rocks. They are a reduction in water content and rock porosity, which leads to the transition of opal type A to opal type crystobalit and trydymit and then to quartz or microquartz. Their density and strength parameters are increased.
The author claims that Marx’s ideas have succeeded, the proletariat has been victorious in the class conflict but the victory is completely different from what Marx has expected. The vision of the proletariat state ended up in a total failure. The vestiges of Marx’s proposal testify to complete inapplicability of his main ideas to the circumstances of the contemporary world. The concept of a state managed by the proletariat class turned out to be defective. The ownership of the means of production has failed. The concept of private property defended itself and has even been strengthened. And where a public ownership won the upper hand, as in State Treasury, it turned out to be institutional and not collective. Moreover, the state interferes more and more vigorously in private businesses and their activities. On the other hand, however, the proletariat succeeded in the area of employment law where it won some durable legal guarantees. Thus Marx correctly perceived certain needs of the proletariat but proposed inapt solutions to them.
The article is a review of the current theoretical achievements in the context of the discussion on the shape and validity of the property tax reform in Poland, indicated in the endogenous development of municipalities. The conclusions contained in the article are an attempt to join in a scientifi c discussion on the subject of property taxation. They constitute a proposal of formulated recommendations necessary from the point of view of legitimacy of collecting property taxes and the implementation of the new system of ad valorem tax.
Faecal Enterococcus hirae from domestic ducks were studied for their bioactivity to select bioactive strain for more detailed study with its probable use in poultry and also to bring novelty in basic research. After defecation, faeces (n=23, faecal mixture of 40 ducks) were sampled from domestic ducks in eastern Slovakia; birds were aged from eight to 14 weeks. E. hirae strains were identified using Matrix-assisted laser desorption/ionization time-of flight mass spectrometry with a highly probable species identification score (2.300-3.000) or a secure genus identification/ /probable species identification score (2.000-2.299), confirmed by polymerase chain reaction and phenotypization in accordance with the properties for the type strain E. hirae ATCC 9790. Strains were hemolysis negative (γ-hemolysis), and did not have active enzyme stimulating disorders. Enterocin genes were detected in three strains out of seven. Three out of four Enterocin genes were detected in Kč1/b (Ent A, P, L50A); the most frequently detected was the Ent P gene. The strains inhibited indicator strains E. faecalis, listeriae, but also Escherichia coli and Buttiauxiella strains. Lactic-acid producing E. hirae were mostly susceptible to antibiotics. Based on parameter evaluation, E. hirae Kč1/b, Kč6 can be additionally studied to select the type of bioactive substance.
In this work, the influence of microwave drying parameters such as irradiation time and microwave power level on the properties of synthetic moulding sands is presented. Determination of compressive strength Rc s, shear strength Rt s and permeability Ps of synthetic moulding sands with the addition of two different bentonites, after drying process with variable microwave parameters were made. The research works were carried out using the microwave oven with regulated power range of the electromagnetic field. From the results obtained, the significant influence of both drying time and microwave power level on the selected properties of moulding sands was observed. In comparison to the conventional drying method, microwave drying allows to obtain higher compressive strength of the synthetic moulding sand. The influence of application microwave irradiation on permeability was not observed. Higher strength characteristics and shorter drying time are major advantages of application of the electromagnetic irradiation for drying of the synthetic moulding sand with regard to conventional drying method.
The article is a part of materials regarding current problems of Polish science and higher education. It provides an in-depth analysis of the Act on degrees and academic titles as well as several other laws which introduce the so-called Ph.D. implementation in Poland. These laws were adopted by the Sejm of the Republic of Poland in April 2017. The author focuses on several problems, discussing them in separate chapters. The article also tries to predict the far-reaching results of the new rules. At the same time, the author proposes specific solutions that should be included in the future in the Act on degrees and academic titles, or in the Act of industrial property. They should eliminate the negative effects of conflicts between the provisions of various legal acts.
The petrographic composition of coal has a significant impact on its technological and sorption properties. That composition is most frequently determined by means of microscope quantitative analyses. Thus, aside from the purely scientific aspect, such measurements have an important practical application in the industrial usage of coal, as well as in issues related to the safety in underground mining facilities. The article discusses research aiming at analyzing the usefulness of selected parameters of a digital image description in the process of automatic identification of macerals of the inertinite group using neural networks. The description of the investigated images was based on statistical parameters determined on the basis of a histogram and co-occurrence matrix (Haralick parameters). Each of the studied macerals was described by means of a 20-element feature vector. An analysis of its principal components (PCA) was conducted, along with establishing the relationship between the number of the applied components and the effectiveness of the MLP network. Based on that, the optimum number of input variables for the investigated classification task was chosen, which resulted in reduction of the size of the network’s hidden layer. As part of the discussed research, the authors also analyzed the process of classification of macerals of the inertinite group using an algorithm based on a group of MLP networks, where each network possessed one output. As a result, average recognition effectiveness of 80.9% was obtained for a single MLP network, and of 93.6% for a group of neural networks. The obtained results indicate that it is possible to use the proposed methodology as a tool supporting microscopic analyses of coal.
An emerging ultrasonic technology aims to control high-pressure industrial processes that use liquids at pressures up to 800 MPa. To control these processes it is necessary to know precisely physicochemical properties of the processed liquid (e.g., Camelina sativa oil) in the high-pressure range. In recent years, Camelina sativa oil gained a significant interest in food and biofuel industries. Unfortunately, only a very few data characterizing the high-pressure behavior of Camelina sativa oil is available. The aim of this paper is to investigate high pressure physicochemical properties of liquids on the example of Camelina sativa oil, using efficient ultrasonic techniques, i.e., speed of sound measurements supported by parallel measurements of density. It is worth noting that conventional low-pressure methods of measuring physicochemical properties of liquids fail at high pressures. The time of flight (TOF) between the two selected ultrasonic impulses was evaluated with a cross-correlation method. TOF measurements enabled for determination of the speed of sound with very high precision (of the order of picoseconds). Ultrasonic velocity and density measurements were performed for pressures 0.1–660 MPa, and temperatures 3–30XC. Isotherms of acoustic impedance Za, surface tension #27; and thermal conductivity k were subsequently evaluated. These physicochemical parameters of Camelina sativa oil are mainly influenced by changes in the pressure p, i.e., they increase about two times when the pressure increases from atmospheric pressure (0.1 MPa) to 660 MPa at 30XC. The results obtained in this study are novel and can be applied in food, and chemical industries.
The amount of waste from washing dolomite aggregates increases continuously. Aggregates are washed to remove clayey pollutants.They consist of a large amount of clay minerals and carbonates. Their properties and amount depends on the type of raw material and type of washing technology. Utilization of waste from washing aggregates is common problem and has not been sought out yet. Their usage as the raw material in ceramics might be environmentally friendly way to utilize them. This paper presents technological properties, phase composition and microstructure analysis of materials made of waste sludge from washing dolomite aggregates. Research was divided into three parts: technological properties analysis, phase composition analysis and microstructure analysis. Samples made of waste dolomite sludge were formed in laboratory clay brick vacuum extruder and fired at 900, 1000 and 1100°C. For final materials, apparent density, open porosity, water absorption, compressive strength and durability were examined. Results of technological research suggest the possibility of the application of the waste sludge from washing aggregates in building ceramics technology as bricks materials. Waste sludge from washing dolomite aggregates can be used as the main raw material of building ceramics masses. Without any additional technological operations (e.g. drying or grinding), the material with satisfactory properties was obtained. According to durability results all obtained materials can be used for masonry protected against water penetration and without contact with soil and ground water and also for masonry subjected to passive exposure (F0 – according to the standard EN 771-1).
Results of a research on influence of chromium, molybdenum and aluminium on structure and selected mechanical properties of Ni-Mn-Cu cast iron in the as-cast and heat-treated conditions are presented. All raw castings showed austenitic matrix with relatively low hardness, making the material machinable. Additions of chromium and molybdenum resulted in higher inclination to hard spots. However, a small addition of aluminium slightly limited this tendency. Heat treatment consisting in soaking the castings at 500 °C for 4 h resulted in partial transformation of austenite to acicular, carbon-supersaturated ferrite, similar to the bainitic ferrite. A degree of this transformation depended not only on the nickel equivalent value (its lower value resulted in higher transformation degree), but also on concentrations of Cr and Mo (transformation degree increased with increasing total concentration of both elements). The castings with the highest hard spots degree showed the highest hardness, while hardness increase, caused by heat treatment, was the largest in the castings with the highest austenite transformation degree. Addition of Cr and Mo resulted in lower thermodynamic stability of austenite, so it appeared a favourable solution. For this reason, the castings containing the highest total amount of Cr and Mo with an addition of 0.4% Al (to reduce hard spots tendency) showed the highest tensile strength.
Ablation casting is a technological process in which the increased cooling rate causes microstructure refinement, resulting in improved mechanical properties of the final product. This technology is particularly suitable for the manufacture of castings with intricate shapes and thin walls. Currently, the ablation casting process is not used in the Polish industry. This article presents the results of strength tests carried out on moulding sands based on hydrated sodium silicate hardened in the Floster S technology, intended for ablation casting of the AlSi7Mg (AK7) aluminium alloy. When testing the bending and tensile strengths of sands, parameters such as binder and hardener content were taken into account. The sand mixtures were tested after 24h hardening at room temperature. The next stage of the study describes the course of the ablation casting process, starting with the manufacture of foundry mould from the selected moulding mixture and ending in tests carried out on the ready casting to check the surface quality, structure and mechanical properties. The results were compared with the parallel results obtained on a casting gravity poured into the sand mould and solidifying in a traditional way at ambient temperature.
Magnesium alloys thanks to their high specific strength have an extensive potential of the use in a number of industrial applications. The most important of them is the automobile industry in particular. Here it is possible to use this group of materials for great numbers of parts from elements in the car interior (steering wheels, seats, etc.), through exterior parts (wheels particularly of sporting models), up to driving (engine blocks) and gearbox mechanisms themselves. But the use of these alloys in the engine structure has its limitations as these parts are highly thermally stressed. But the commonly used magnesium alloys show rather fast decrease of strength properties with growing temperature of stressing them. This work is aimed at studying this properties both of alloys commonly used (of the Mg-Al-Zn, Mn type), and of that ones used in industrial manufacture in a limited extent (Mg-Al-Sr). These thermomechanical properties are further on complemented with the microstructure analysis with the aim of checking the metallurgical interventions (an effect of inoculation). From the studied materials the test castings were made from which the test bars for the tensile test were subsequently prepared. This test took place within the temperature range of 20°C – 300°C. Achieved results are summarized in the concluding part of the contribution.
Superparamagnetic iron oxide nanoparticles (SPION) synthesised chemically usually need the modification of the particle surface. Other natural sources of magnetic particles are various magnetotactic bacteria. Magnetosomes isolated from magnetotactic bacteria are organelles consisting of magnetite (Fe3O4) or greigite (Fe3S4) crystals enclosed by a biological membrane. Magnetotactic bacteria produce their magnetic particles in chains. The process of isolation of magnetosome chains from the body of bacteria consists of a series of cycles of centrifugation and magnetic decantation. Using a high-energy ultrasound it is possible to break the magnetosome chains into individual nanoparticles – magnetosomes. This study presents the effect of sonication of magnetosome suspension on their acoustic properties, that is speed and attenuation of the sound. Acoustic propagation parameters are measured using ultrasonic spectroscopy based on FFT spectral analysis of the received pulses. The speed and attenuation of ultrasonic waves in magnetosome suspensions are analysed as a function of frequency, temperature, magnetic field intensity, and the angle between the direction of the wave and the direction of the field.
Natural gas is a mixture of 21 components and it is widely used in industries and homes. Knowledge of its thermodynamic properties is essential for designing appropriate processes and equipment. This paper presents simple but precise correlations of how to compute important thermodynamic properties of natural gas. As measuring natural gas composition is costly and may not be effective for real time process, the correlations are developed based on measurable real time properties. The real time properties are temperature, pressure and specific gravity of the natural gas. Calculations with these correlations are compared with measured values. The validations show that the average absolute percent deviation (AAPD) for compressibility factor calculations is 0.674%, for density is 2.55%, for Joule-Thomson coefficient is 4.16%. Furthermore, in this work, new correlations are presented for computing thermal properties of natural gas such as enthalpy, internal energy and entropy. Due to the lack of experimental data for these properties, the validation is done for pure methane. The validation shows that AAPD is 1.31%, 1.56% and 0.4% for enthalpy, internal energy and entropy respectively. The comparisons show that the correlations could predict natural gas properties with an error that is acceptable for most engineering applications.
The present study, aims to investigate the effect of minor Zr and Nb alloying on soft magnetic and electrical properties of Fe86(ZrxNb1-x)7B6Cu1 (x = 1, 0.75, 0.5, 0.25) alloys. The investigated alloys were prepared through the melt spinning process. Within the examined compositional range (Nb up to 5.25at%, respectively), the soft magnetic properties and electrical resistivity of the alloys continuously increase with increasing Nb content. However increasing the Nb content further decreases such properties. We could confirm the influence of ratio of Zr and Nb on grain growth and crystallization fraction during crystallization by using the soft magnetic properties and electrical properties.