Methane (CH4) sensitivity of zinc oxide (ZnO) thin film has been studied in the present work. The sensor element comprises of a chemically fabricated ZnO semiconducting layer and a layer of palladium (Pd) as catalyst. The catalyst layer was formed on the surface of semiconducting ZnO following a wet chemical process from palladium chloride (PdCl2) solution. Fundamental features of a sensor element e.g. sensitivity, response time and recovery process has been studied. The effect of operating temperature on performance of the sensor material has been investigated and a choice of optimum temperature was made at around 200oC. The sensor element exhibited reasonable sensitivity of about 86% at this temperature in presence of 1 vol% methane (CH4) in air.
Experimental investigation was conducted on the thermal performance and pressure drop of a convective cooling loop working with ZnO aqueous nanofluids. The loop was used to cool a flat heater connected to an AC autotransformer. Influence of different operating parameters, such as fluid flow rate and mass concentration of nanofluid on surface temperature of heater, pressure drop, friction factor and overall heat transfer coefficient was investigated and briefly discussed. Results of this study showed that, despite a penalty for pressure drop, ZnO/water nanofluid was a promising coolant for cooling the micro-electronic devices and chipsets. It was also found that there is an optimum for concentration of nanofluid so that the heat transfer coefficient is maximum, which was wt. %=0.3 for ZnO/water used in this research. In addition, presence of nanoparticles enhanced the friction factor and pressure drop as well; however, it is not very significant in comparison with those of registered for the base fluid.
Single crystalline cesium doped ZnO nanorods with homogeneous size and shape were grown hydrothermally on ITO substrates that are presented in our previous work. According to the previous work, XRD analysis showed that cesium doped ZnO nanorods are wurtzite single crystals and are grown preferentially along the c-axis. Also, the electrical conductivity of doped ZnO showed higher values for the 1% cesium, which confirmed incorporation of the cesium dopant. Cesium doped ZnO nanorods are suitable candidates for applications in solar cells. So, in this research, we employed cesium doped ZnO nanorods with the different dopant concentration in inverted polymer solar cell. By comparing the effect of doped ZnO nanorods with diverse dopant concentration (0, 0.5, 1.0, 1.5 and 2%) on the performance of devices, 1.0% cesium doped ZnO was found as the most effective doping level among the selected doping concentrations. Also, using 1.0% cesium doped ZnO nanorods, Jsc of 8.21 mA/cm², Voc of 0.541V and Fill Factor of 63.01% were achieved, which led to power conversion efficiency of 2.80%.
The aim of the present study was to develop a modifier for water glass. The method of thermal generation of metal oxide nanoparticles was adapted and used in the research. Nanoparticles of ZnO from the thermal decomposition of basic zinc carbonate were used. A method for the modifier introduction was developed, and the effect of modifier content and organic solvent type on the physico-chemical properties of binder (viscosity) and quartz wettability was determined. Binder viscosity was examined from the flow curves plotted with the help of a RHEOTEST 2 rotational rheometer equipped with proper software. Quartz wettability was determined examining timerelated changes in the value of the contact angle in a quartz-binder system, until full stabilisation of the angle value has been achieved. Binder modification was carried out on sodium water glass designated as R"145". The water glass modifiers were suspensions of ZnO nanoparticles in propanol and methanol at a fixed concentration of c = 0.3 M and with the size of nanoparticles comprised in a range of <61 - 981 nm>. Water glass modification with the suspensions of ZnO nanoparticles in methanol and propanol showed the effect of modifier on the water glass viscosity and quartz wettability. This effect depends on the type of alcohol used. The ZnO suspension in propanol (alcohol with a longer hydrocarbon chain) affects more strongly the viscosity of binder and quartz wettability than the methanol suspension.
The purpose of the presented experiment was to develop an effective water glass modifier. In the conducted research, an attempt was made to determine the effect of modifier addition on the wettability of quartz grains, viscosity and cohesion of binder and strength Rm U of the sand mixture. Water glass modification was carried out with, obtained in electrochemical process , colloidal suspension of ZnO nanoparticles in methanol (modifier I) or propanol (modifier II), characterised by a constant molar concentration of c = 0.3 M. It was demonstrated that the addition of a colloidal suspension of ZnO nanoparticles in propanol (modifier II) had a significant effect on wettability of quartz grains improvement without the accompanying increase in binder viscosity. Testing the mechanical properties Rm U of sand mixtures containing modified binder (modifier II) hardened at ambient conditions showed an approximately 28% increase in strength compared with the Rm U of the sand bonded with an unmodified binder.
The paper presents the results of investigations concerning the application of zinc oxide - a wideband gap semiconductor in optical planar waveguide structures. ZnO is a promising semiconducting material thanks to its attractive optical properties. The investigations were focused on the determination of the technology of depositions and the annealing of ZnO layers concerning their optical properties. Special attention was paid to the determination of characteristics of the refractive index of ZnO layers and their coefficients of spectral transmission within the UV-VIS-NIR range. Besides that, also the mode characteristics and the attenuation coefficients of light in the obtained waveguide structures have been investigated. In the case of planar waveguides, in which the ZnO layers have not been annealed after their deposition, the values of the attenuation coefficient of light modes amount to a~ 30 dB/cm. The ZnO layers deposited on the heated substrate and annealed by rapid thermal annealing in an N2 and O2 atmosphere, are characterized by much lower values of the attenuation coefficients: a~ 3 dB/cm (TE0 and TM0 modes). The ZnO optical waveguides obtained according to our technology are characterized by the lowest values of the attenuation coefficients a encountered in world literature concerning the problem of optical waveguides based on ZnO. Studies have shown that ZnO layers elaborated by us can be used in integrated optic systems, waveguides, optical modulators and light sources.
A laboratory study was performed to study the effects of various operating factors, viz. adsorbent dose, contact time, solution pH, stirring speed, initial concentration and temperature on the adsorption of triphenyltin chloride (TPT) onto coal fly ash supported nZnO (CFAZ). The adsorption capacity increases with increase in the adsorbent amount, contact time, pH, stirring speed and initial TPT concentration, and decrease with increase in the solution temperature. The adsorption data have been analyzed by Langmuir, Freundlich, Temkin and Dubinin-Radushkevich (D-R) adsorption models to determine the mechanistic parameters associated with the adsorption process while the kinetic data were analyzed by pseudo first-order, pseudo second-order, Elovich, fractional power and intraparticle diffusivity kinetic models. The thermodynamic parameters of the process were also determined. The results of this study show that 0.5 g of CFAZ was able to remove up to 99.60% of TPT from contaminated natural seawater at 60 min contact time, stirring speed of 200 rpm and at a pH of 8. It was also found that the equilibrium and kinetic data fitted better to Freundlich and pseudo second-order models, respectively. It can therefore be concluded that CFAZ can be effectively used for shipyard process wastewater treatment