Food additives, especially E numbers, are widely perceived by consumers as artificial and harmful. However, the fact is that they are an essential ingredient in numerous products, many have “natural” origins and none of them pose a risk to health.
This paper presents the results of research focused on the lowering of ash flow temperature at semianthracite coal from Donbas district by means of additive (calcite) dosing. Ash fusion temperatures were set for two coal samples (A, B) and for five various states (samples of ash without any additives, with 1%, with 3%, with 5% and with 7% of the additive) in total. The macroscopicphotographic method was used for identifying all specific temperatures. Obtained outputs prove that A type coal has a lower value of sphere temperature than B type coal in the whole scope of percentage representation of the additive. The flow temperature dropped in total from 1489 °C to 1280 °C, i.e. by 14% during the test of coal of type A with 7% of the additive; while it was near 10% for coal of type B (from 1450 °C to 1308 °C). Numerical simulations of the process showed that it is not effective to add an additive with a grain size lower than 280 μm by means of wastevapour burners.
Steel and cast-iron products, due to their low price and beneficial properties, are the most widely used among metals; their consumption has become an indicator of the economic development of countries. The characteristics of iron raw materials, in relation to current metallurgical requirements, are presented in the present this article. The globalization of the trade and development of steelmaking technologies have caused significant changes in the quality of raw materials in the last half-century forcing improvements in processing technologies. In many countries, standard concentrates (at least 60% Fe) are almost twice as rich as those processed in the mid-20th century. Methods of quality assessment have been improved and quality standards tightened. The quality requirements for the most important raw materials ‒ iron ores and concentrates, steel scrap, major alloy metals, coking coal, and coke, as well as gas and other energy media ‒ are reviewed in the present paper. Particular attention is paid to the quality testing methodology. The quality of many raw materials is evaluated multi-parametrically: both chemical and physical characteristics are important. Lower-quality parameters in raw materials equate to significantly lower prices obtained by suppliers in the market. The markets for these raw materials are diversified and governed by separate sets of newly introduced rules. Price benchmarks (e.g. for standard Australian metallurgical coal) or indices (for iron concentrates) apply. Some raw materials are quoted within the framework of the commodity market system (certain alloying components and steel scrap). The abandonment of the long-established system of multi-annual contracts has led to wide fluctuations in prices, which have reached a scale similar to that of other metals.
The study was conducted on 26 male, 30 days-old goats, separated from their mothers, divided into two equal groups: I - control and II - experimental, consisting of 13 animals each. All animals were fed with milk replacer, experimental group received additionally 50 g/kg body weight, additive of HMB, for 60 days. The following features were analyzed: body weight, daily increases of body weight, as well as hematological and biochemical blood features. Differences in body weight were found, between experimental and control group, after 60 days of experiment 0.57 kg (p≤0.01). The daily weight gain of experimental animals was higher in comparison with control group. Significant differences were also noted in results of hematological and biochemical blood parameters. Experimental animals showed a higher level of red blood cells as well as number of lymphocytes in comparison with the control group, (p≤0.01).Significant changes were also observed in the level of triglycerides, inorganic phosphorus and protein between both groups. The acid-base balance parameters and ionogram, showed a higher pH level (p≤0.05) HCO – act., HCO – std., BE, ctCO , O sat, K+, Cl– (p≤0.01), while the anion gap (AG) and Na+ were significantly lower in control group (p≤0.01).
The paper presents the results of the electrodeposition of nickel composite coatings reinforced with the ceramic SiC particles. A Watts type galvanic bath modified with various organic additives was used. These additives were: 2-sulfobenzoic acid imide (LSA), dioctyl sulfosuccinate sodium salt (DSS), sodium dodecyl sulfate (SDS), tris (hydroxymethyl) aminomethane (THAM) and hexamethyldisilizane (HMDS). The nickel composite coating was electrodeposited on a 2xxx aluminum alloy series substrate (EN-AW 2017) with zinc interlayer. Studies concerned the effect of the applied organic additives on properties of composite coatings such as: microstructure, microhardness, adhesion to the substrate, corrosion resistance and roughness. The structure of the coatings was assessed by scanning electron microscopy and light microscopy. Based on the studies of zeta potential it was found that the bath modification had a significant impact on the amount of the ceramic phase embedded in metal matrix. The tests conducted in a model 0.01 M KCl solution were not fully representative of the true behavior of particles in a Watts bath.
The method of a phase shift angle measurement using conditional averaging of delayed signal absolute value (CAAV) is presented in this paper. The input sinusoidal signal x(t) is without noise. White noise with normal distribution and band limited to low frequencies has been applied as disturbance of delayed sinusoidal signal z(t). Noise n(t) - N(0, σn) is added to the delayed signal - the noised and delayed signal z(t) is obtained. The phase angle shift is proportional to time location of CAAV's minimum (minimum of the characteristic of conditional averaging of delayed signal's absolute value). The phase angle shift can be determined on the basis of conditional averaging value of elaborated algorithm. The characteristics of conditional average of delayed signal's absolute value in the surrounding of the minimum of this function (the results of practical investigations and theoretical calculation) are presented. The experimental variance of characteristic CAAV in surroundings of the minimum (obtained from practical investigations and calculation) is illustrated in the paper. The algorithms of conditional averaging have been elaborated and practically realized in the LabVIEW environment.
Additive manufacturing (AM) is a process that joins similar or dissimilar materials into application-oriented objects in a wide range of sizes and shapes. This article presents an overview of two additive manufacturing techniques; namely Laser metal deposition (LMD) and Wire arc additive manufacturing (WAAM). In LMD, metallic powders are contained in one or more chambers, which are then channelled through deposition nozzles. A laser heats the particles to produce metallic beads, which are deposited in layers with the aid of an in-built motion system. In WAAM, a high voltage electric arc functions as the heat source, which helps with ensuring deposition of materials, while materials in wire form are used for the feedstock. This article highlights some of the strengths and challenges that are offered by both processes. As part of the authors’ original research work, Ti-6Al-4V, Stainless steel 316L and Al-12Si were prepared using LMD, while the WAAM technique was used to prepare two Al alloys; Al-5356 and CuAl8Ni2. Microstructural analysis will focus on similarity and differences in grains that are formed in layers. This article will also offer an overall comparison on how these samples compare with other materials that have been prepared using LMD and WAAM.
The purpose of the present paper was to investigate the effect of shot peening on the condition of the surface layer and abrasion resistance of specimens made of Ti-6Al-4V titanium alloy produced by Direct Metal Laser Sintering (DMLS) process. The specimens have been produced by means of EOSINT M280 system dedicated for laser sintering of metal powders and their surfaces have been subjected to the shot peening process under three different working pressures (0.2, 0.3 and 0.4 MPa) and by means of three different media i.e. CrNi steel shot, crushed nut shells and ceramic balls. The specimens have been subjected to profilometric analysis, to SEM examinations, microhardness tests and to tribological tests on ball-on-disc stand in Ringer fluid environment. The general results of all tests indicate to favourable effect of shot peening process on the hardness and tribological performance of titanium alloy.
Thermal/cold spray deposition were used for additive manufacture of oxide dispersion strengthened (ODS) steel layers. Mechanically alloyed F/M ODS steel powders (Fe(bal.)-10Cr-1Mo-0.25Ti-0.35Y2O3 in wt.%) were sprayed by a high velocity oxygen fuel (HVOF) and cold spray methods. HVOF, as a thermal method, was used for manufacturing a 1 mm-thick ODS steel layer with a ~95% density. The source to objective distance (SOD) and feeding rate were controlled to achieve sound manufacturing. Y2Ti2O7 nano-particles were preserved in the HVOF sprayed layer; however, unexpected Cr2O3 phases were frequently observed at the boundary area of the powders. A cold spray was used for manufacturing the Cr2O3-free layer and showed great feasibility. The density and yield of the cold spray were roughly 80% and 45%, respectively. The softening of ODS powders before the cold spray was conducted using a tube furnace of up to 1200°C. Microstructural characteristics of the cold sprayed layer were investigated by electron back-scattered diffraction (EBSD), the uniformity of deformation amount inside powders was observed.
The effects of silica additive (Poraver) on selected properties of BioCo3 binder in form of an aqueous poly(sodium acrylate) and dextrin (PAANa/D) binder were determined. Based on the results of the thermoanalytical studies (TG-DTG, FTIR, Py-GC/MS), it was found that the silica additive results in the increase of the thermostability of the BioCo3 binder and its contribution does not affect the increase in the level of emissions of organic destruction products. Compounds from group of aromatic hydrocarbons are only generated in the third set temperature range (420-838°C). The addition of silicate into the moulding sand with BioCo3 causes also the formation of a hydrogen bonds network with its share in the microwave radiation field and they are mainly responsible for maintaining the cross-linked structures in the mineral matrix system. As a consequence, the microwave curing process in the presence of Poraver leads to improved strength properties of the moulding sand (���� �� ). The addition of Poraver's silica to moulding sand did not alter the permeability of the moulding sand samples, and consequently reduced their friability. Microstructure investigations (SEM) of microwave-cured samples have confirmed that heterogeneous sand grains are bonded to one another through a binder film (bridges).
The aim of the study was to determine the applicability of a new product added to water glass-containing foundry sands hardened with ethylene glycol diacetate. The new additive designated by the symbol "B" is a composition of aqueous solutions of modified polyalcohols, improving the sand knocking out properties. The scope of studies included testing various mechanical and technological properties of foundry sand mixtures, such as permeability, friability, life cycle of cores and knocking out properties. In the technological studies, two types of water glass with different values of the silica modulus and density, designated as R145 and R150, were used. Moulding sands were prepared with the additive "B". For comparison, reference sands with water glass but without the additive "B" were also made. In Part I of the article, the results of studies of the effect of additive "B" on the properties of foundry sands with water glass hardened by CO2 blowing were discussed.
Transverse effective thermal conductivity of the random unidirectional fibre-reinforced composite was studied. The geometry was circular with random patterns formed using random sequential addition method. Composite geometries for different volume fraction and fibre radii were generated and their effective thermal conductivities (ETC) were calculated. Influence of fibre-matrix conductivity ratio on composite ETC was investigated for high and low values. Patterns were described by a set of coordination numbers (CN) and correlations between ETC and CN were constructed. The correlations were compared with available formulae presented in literature. Additionally, symmetry of the conductivity tensor for the studied geometries of fibres was analysed.
Analysis of the use of the Russian materials (liquid glass and softening additives) has been made in accordance with the modern requirements for use in the technological processes of casting as binding materials in the production of large-sized steel railway casting. The reasons for poor knockout of liquid glass mixtures have been investigated. A complex action softening additive has been recommended for a better knocking-out ability. This solution provides a softening effect at the points of maximum formation of the liquid glass matrix strength in the processes of polymorphic transformation of the material under the influence of elevated temperatures as the result of filling the mold cavity by the melt. It has been shown that the use of additives of complex action leads to the decrease in the specific work of the knockout by four – seven times depending on the composition of the mixture and the design features of the casting. Experimental-industrial tests of the proposed method for softening the liquid glass mixtures have been made and the "Front Buffer Stop" casting has been made (for the rolling stock of locomotives and railway wagons). The tests confirmed the effectiveness and expediency of implementation of new liquid glass mixtures with softening additives in conditions of foundry enterprises.
This paper deals with the amplitude estimation in the frequency domain of low-level sine waves, i.e. sine waves spanning a small number of quantization steps of an analog-to-digital converter. This is a quite common condition for high-speed low-resolution converters. A digitized sine wave is transformed into the frequency domain through the discrete Fourier transform. The error in the amplitude estimate is treated as a random variable since the offset and the phase of the sine wave are usually unknown. Therefore, the estimate is characterized by its standard deviation. The proposed model evaluates properly such a standard deviation by treating the quantization with a Fourier series approach. On the other hand, it is shown that the conventional noise model of quantization would lead to a large underestimation of the error standard deviation. The effects of measurement parameters, such as the number of samples and a kind of the time window, are also investigated. Finally, a threshold for the additive noise is provided as the boundary for validity of the two quantization models
The aim of this paper was to attain defect free, pure copper castings with the highest possible electrical conductivity. In this connection, the effect of magnesium additives on the structure, the degree of undercooling (ΔTα = Tα-Tmin, where Tα – the equilibrium solidification temperature, Tmin – the minimum temperature at the beginning of solidification), electrical conductivity, and the oxygen concentration of pure copper castings have been studied. The two magnesium doses have been investigated; namely 0.1 wt.% and 0.2 wt.%. A thermal analysis was performed (using a type-S thermocouple) to determine the cooling curves. The degree of undercooling and recalescence were determined from the cooling and solidification curves, whereas the macrostructure characteristics were conducted based on a metallographic examination. It has been shown that the reaction of Mg causes solidification to transform from exogenous to endogenous. Finally, the results of electrical conductivity have been shown as well as the oxygen concentration for the used Mg additives.
In the present study, a titanium cellular lattice structure with a mathematical designed porosity gradient was successfully fabricated using the selective laser melting method. The samples with smooth gradient transition of porosity of between 60% and 80% were received for different elementary cell geometries. Elementary cells belong to the triply periodic minimal surfaces family (G, D, I2Y, IWP). Each sample was subjected to a comprehensive analysis including: dimensional metrology and assessment of material defects (X-ray micro-tomography), surface morphology tests (scanning electron microscopy) and mechanical properties (universal testing machine). It has been shown that a cellular lattice with high dimensional accuracy (+0.16/–0.08 mm) and full dense struts can be obtained. According to the assumption, the gradient increases the strength of the cellular lattice samples. The highest increase in plateau stress between the samples with and without gradient was found for the I2Y series (about 185%). Furthermore, it was found that the stress-strain response of the samples depends not only on total porosity, but also on the 3D geometry of the cellular lattice. The stress-strain curves for G, IWP and I2Y samples are smooth and exhibit three characteristic regions: linear elasticity, plateau region and densification region. The size of regions depends on the geometric features of the cellular lattice. For series D, in the plateau region, the fluctuations in stress value are clearly visible. The smoothest stress-strain curve can be noted for the G series, which combined with good mechanical properties (the plateau stress and energy absorbed, at respectively 25.5 and 43.2 MPa, and 46.3J and 59.5J for Gyr_80 and Gyr_6080, which corresponds to a strain of almost 65% and 50%) positively affects the applicability of cellular structures with such geometry.
Along with the increase in popularity of the sewage sludge thermal treatment methods in Poland resulting from the implementation of European Union law, a management problem with ash, which is produced as a result of this process, appeared. The paper analyses the chemical composition and physical properties of fl y ash from thermal treatment of municipal sewage sludge in terms of its use in concrete technologies in relation to EN 450-1 Fly ash for concrete. Defi nition, specifi cations and conformity criteria (2012) and EN 197-1 Cement. Composition, specifi cations and conformity criteria for common cements (2011) standards. The tested material did not meet the requirements related to use of fl y ash for concrete production (chemical composition, low activity index, high water demand and fi neness), and as main and minor components for cement production. On the basis of the carried out research and analyses, it was found that the hardening slurry technology creates the greatest possibilities related to the management of fl y ash from thermal treatment of municipal sewage sludge.