The influence of ozone injection mode on the effectiveness of nitrogen monoxide oxidation to nitrogen dioxide by ozone in a flow reactor was investigated experimentally in laboratory apparatus. Nitrogen monoxide was diluted to the mole fraction 100 ppm in air which served as the carrier gas flowing through the tube of the diameter D = 60 mm into which ozone was injected. The effects of a number of ozone injecting nozzles and their configuration on the effectiveness of NO oxidation were examined. In the closest vicinity from the injection site the counter-current injection mode appeared to be superior to the co-current injection mode, but in areas located further from the injection site both injection systems were almost equally effective.
Coal in Poland is an available conventional fuel providing energy security and independence of the country. Therefore, conventional energy generation should be based on coal with the optimal development of renewable energy sources. Such a solution secures the energy supply based on coal and the independence of political and economic turmoil of global markets. Polish coal reserves can secure the energy supply for decades. Coal will surely be important for energy security in the future despite the growing share of oil and gas in energy mix. The development of renewable power generation will be possible with the conventional energy generation offsetting volatile renewable power generation as Poland’s climate doesn’t allow for the stable and effective use of renewable energy sources. Considering the policy of the European Union with respect to emission reductions of greenhouse gasses and general trends as reflected in the Paris agreement in 2016, as a country we will be forced to increase renewable energy production in our energy mix. However, this process cannot impact the energy security of the country and stability and the uninterrupted supply of energy to consumers. Therefore seeking the compromise with the current energy mix in Poland is the best way to its gradual change with the simultaneous conservation of each of the sources of energy. It’s obvious that Poland can not be lonely energy island in Europe and in the world, which increasingly develops distributed energy and/ renewable technologies as well as energy storage ones. One can notice that without renewable generation and the reduction of coal’s share in country’s energy mix we will become the importer of electricity with raising energy dependence.
Obtaining a pure product by mixing together raw materials, so as to carry out a chemical reaction at high selectivity, is a difficult part of manufacturing chemical products. How can we test reactors and mixers to ensure the efficient use of energy?
The progressive processes of globalization and changes in the global, European and local economy require integrated efforts aimed at solving problems related to development at the national regional and the local level involving the environment, energy sources, climate and technological transformation issues. European Union Member States are given right to create an individual Energy mix. Coal will continue to play a major role in Poland’s energy mix during the next decades. Polish coal reserves can provide energy security for decades. Despite crude oil and natural gas growth in fuel consumption, coal will continue to be the stabilizer of energy security for the country and play an important role in Poland’s energy mix in the years to come. However, further coal consumption requires investments in low carbon technologies which are of high efficiency and in high-efficiency cogeneration. The validity of the full utilization of cogeneration potential should be highlighted. Operating cogeneration plants are more expensive than power plants but they are more efficient and generate less carbon emissions. In accordance with the assumptions of the Energy policy of Poland, a low-carbon economy with renewable Energy sources and nuclear Energy should be supported and developed, however the obsolete coal generators should be replaced with low-carbon high-efficient ones.
In this study the formation of the polygenetic High Tatra granitoid magma is discussed. Felsic and mafic magma mixing and mingling processes occurred in all magma batches composing the pluton and are documented by the typical textural assemblages, which include: mafic microgranular enclaves (MME), mafic clots, felsic clots, quartz-plagioclase-titanite ocelli, biotite-quartz ocelli, poikilitic plagioclase crystals, chemically zoned K-feldspar phenocrysts with inclusion zones and calcic spikes in zoned plagioclase. Geochemical modelling indicates the predominance of the felsic component in subsequent magma batches, however, the mantle origin of the admixed magma input is suggested on the basis of geochemical and Rb-Sr, Sm-Nd and Pb isotopic data. Magma mixing is considered to be a first-order magmatic process, causing the magma diversification. The cumulate formation and the squeezing of remnant melt by filter pressing points to fractional crystallization acting as a second-order magmatic process.
The aim of the study was to present an experimental investigation of the influence of the RMF on mixing time. The obtained results suggest that the homogenization time for the tested experimental set-up depending on the frequency of the RMF can be worked out by means of the relationship between the dimensionless mixing time number and the Reynolds number. It was shown that the magnetic field can be applied successfully to mixing liquids.
Two systems of hydraulic mixing in a vertical cylindrical anaerobic digester: standard and modernised are discussed in the paper. Numerical investigations that were carried out are focused on a study of hydrodynamic processes in an aerobic digester using two various systems of hydraulic mixing as well as on analysis of the efficiency of methane fermentation process accomplished under different geometric parameters of an anaerobic digester and systems of hydraulic mixing.
The drainage consolidation method has been efficiently used to deal with soft ground improvement. Nowadays, it has been suggested to use a new sand soil which is a composite of sand and recycled glass waste. The permeability performance of glass-sand soil was explored to judge the feasibility of glass-sand soil backfilled in the drainage consolidation of sand-drained ground. For comparison purposes, different mix proportions of recycled glass waste, fineness modulus, and glass particle size were analyzed to certify the impact on the permeability coefficient and the degree of consolidation. The numerical results show that adding a proper amount of recycled glass waste could promote the permeability performance of glass-sand soil, and the glasssand soil drain could be consolidated more quickly than a sand drain. Experiments showed that glass-sand soil with the a 20% mix of recycled glass waste reveals the optimum performance of permeability.
This paper analyses the real behaviour of the fluid in the channels of a three-end membrane module. The commonly accepted mathematical model of membrane separation of gas mixtures in such modules assumes a plug flow of fluid through the feed channel and perfect mixing in the permeate channel. This article discusses the admissibility of accepting such an assumption regarding the fluid behaviour in the permeate channel. Throughout analysis of the values of the Péclet number criterion, it has been demonstrated that in the industrial processes of membrane gas separation, the necessary conditions for the perfect mixing in the permeate channel are not met. Then, CFD simulations were performed in order to establish the real fluid behaviour in this channel. It was proved that in the permeate channel the fluid movement corresponds to the plug flow, with the concentration differences at both ends of the module being insignificant. In view of the observations made, the admissibility of concentration stability assumptions in the mathematical models for the permeate channel was discussed.
Geometric parameters of a ribbon impeller were optimized on the basis of numerical calculations obtained from the solution of our own 3D/2D hybrid model. The optimization was made taking into account mixing power and homogenization time for ribbon impellers with a different number of ribbons and width operating in a laminar motion for Newtonian fluid. Due to minimum mixing energy required to stir a unit volume of liquid the most efficient impeller appeared to be that with one ribbon of width equal to 0.1 to 0.15 of the mixing vessel diameter. Impellers with more than one ribbon needed much higher mixing power but did not increase significantly secondary circulation in the vessel. These impellers increased first of all primary circulation, i.e. they increased only circular motion of liquid in the vessel.
The work presents a comparison of some sound attributes perceived at a multichannel and stereo playback of musical recordings. The width of the virtual source, coherence impression, total size of sound scene, general quality and balance were the subjects of interest after the format reduction in accordance with the ITU recommendation. The results showed that evaluation of these attributes depends on the way the original audiosphere has been created in the surround system, for example, for a narrow virtual source the mix-down process causes only a small change in its size but for a broad source the observed degradation is significant. In addition, different ways of conversion from the multichannel to stereo format have been tested for compatibility.
Simulations of turbulent mixing in two types of jet mixers were carried out using two CFD models, large eddy simulation and κ-ε model. Modelling approaches were compared with experimental data obtained by the application of particle image velocimetry and planar laser-induced fluorescence methods. Measured local microstructures of fluid velocity and inert tracer concentration can be used for direct validation of numerical simulations. Presented results show that for higher tested values of jet Reynolds number both models are in good agreement with the experiments. Differences between models were observed for lower Reynolds numbers when the effects of large scale inhomogeneity are important.
In this work a concept of energetic efficiency of mixing is presented and discussed; a classical definition of mixing efficiency is modified to include effects of the Schmidt number and the Reynolds number. Generalization to turbulent flows is presented as well. It is shown how the energetic efficiency of mixing as well as efficiencies of drop breakage and mass transfer in twophase liquid-liquid systems can be identified using mathematical models and test chemical reactions. New expressions for analyzing efficiency problem are applied to identify the energetic efficiency of mixing in a stirred tank, a rotor stator mixer and a microreactor. Published experimental data and new results obtained using new systems of test reactions are applied. It has been shown that the efficiency of mixing is small in popular types of reactors and mixers and thus there is some space for improvement.
Mixing of granular materials is unquestionably important. Mixing solids is common in industrial applications and frequently represents a critical stage of the processes. The effect of mixing determines the quality of the products. Achieving a gas or liquid mixture ideally homogeneous in terms of composition in the case of dissolving components is not that difficult, while in case of granular materials that usually differ in sizes and densities, obtaining a homogenous mixture is practically impossible. The aim of the paper is to present the kinetics of mixing of a multicomponent, nonhomogeneous granular mixture. For the first time in mixing of granular materials, a reference has been made to the terminology used in kinematics of fluid mixtures to determine the state of the mixture: turbulent or laminar. By means of statistical analysis the mixing process was divided into two stages. The initial phase of the process was called the stage of turbulent changes, due to large differences in the quality of the observed mixtures; the final step of the process was called the stage of laminar, stable changes, where further mixing did not result in a significant improvement in quality. The research was conducted in industrial conditions in a two-tonne mixer.
The main aim of this work is to study the thermal efficiency of a new type of a static mixer and to analyse the flow and temperature patterns and heat transfer efficiency. The measurements were carried out for the static mixer equipped with a new mixing insert. The heat transfer enhancement was determined by measuring the temperature profiles on each side of the heating pipe as well as the temperature field inside the static mixer. All experiments were carried out with varying operating parameters for four liquids: water, glycerol, transformer oil and an aqueous solution of molasses. Numerical CFD simulations were carried out using the two-equation turbulence k-ω model, provided by ANSYS Workbench 14.5 software. The proposed CFD model was validated by comparing the predicted numerical results against experimental thermal database obtained from the investigations. Local and global convective heat transfer coefficients and Nusselt numbers were detrmined. The relationship between heat transfer process and hydrodynamics in the static mixer was also presented. Moreover, a comparison of the thermal performance between the tested static mixer and a conventional empty tube was carried out. The relative enhancement of heat transfer was characterised by the rate of relative heat transfer intensification.
One of the important parameters describing pneumatic liquid atomisation is the air to liquid mass ratio (ALR). Along with the atomiser design and properties of the liquid it has extremely important influence on parameters of atomised liquid such as: mean droplet diameter, jet range and angle. Knowledge about real characteristics of an atomiser in this respect is necessary to correctly choose its operating parameters in industrial applications. The paper presents results of experimental research of two-fluid atomisers with internal mixing built according to custom design. Investigated atomizers were designed for spraying a urea aqueous solution inside the power boiler combustion chamber. They are an important element of SNCR (selective non-catalytic reduction) installation which is used to reduce nitrogen oxides in a flue gas boiler. Obtained results were used by authors in further research, among others to determine the boundary conditions in the SNCR installation modeling. The research included determining mean droplet diameter as a function of ALR. It has been based on the immersion liquid method and on the use of specialised instrumentation for determining distribution of droplet diameters in a spray – Spraytec by Malvern. Results obtained with both methods were later compared. The measurements were performed at a laboratory stand located at the Institute of Heat Engineering, Warsaw University of Technology. The stand enables extensive investigation of the water atomisation process.
Knowledge of the fluid dynamic characteristics in a stirred vessel is essential for reliable design and scale-up of a mixing system. In this paper, 3D hydrodynamics in a vessel agitated by a Rushton turbine were numerically studied (with the help of a CFD computer program (CFX 13.0)). The study was carried out covering a wide Reynolds number range: 104 - 105. Computations, based on control volume method, were made using the k-ε model. Our main purpose was to investigate the effect of vessel configuration and agitation rates on the flow structure and power consumption. Three types of vessels were used: unbaffled, baffled and a vessel with slots placed at the external perimeter of its vertical wall. The effect of slot length has been investigated. The comparison of our predicted results with available experimental data shows a satisfactory agreement.
The main topic of this study is the experimental measurement and mathematical modelling of global gas hold-up and bubble size distribution in an aerated stirred vessel using the population balance method. The air-water system consisted of a mixing tank of diameter T = 0.29 m, which was equipped with a six-bladed Rushton turbine. Calculations were performed with CFD software CFX 14.5. Turbulent quantities were predicted using the standard k-ε turbulence model. Coalescence and breakup of bubbles were modelled using the homogeneous MUSIG method with 24 bubble size groups. To achieve a better prediction of the turbulent quantities, simulations were performed with much finer meshes than those that have been adopted so far for bubble size distribution modelling. Several different drag coefficient correlations were implemented in the solver, and their influence on the results was studied. Turbulent drag correction to reduce the bubble slip velocity proved to be essential to achieve agreement of the simulated gas distribution with experiments. To model the disintegration of bubbles, the widely adopted breakup model by Luo & Svendsen was used. However, its applicability was questioned.
The main topic of this study is the mathematical modelling of bubble size distributions in an aerated stirred tank using the population balance method. The air-water system consisted of a fully baffled vessel with a diameter of 0.29 m, which was equipped with a six-bladed Rushton turbine. The secondary phase was introduced through a ring sparger situated under the impeller. Calculations were performed with the CFD software CFX 14.5. The turbulent quantities were predicted using the standard k-ε turbulence model. Coalescence and breakup of bubbles were modelled using the MUSIG method with 24 bubble size groups. For the bubble size distribution modelling, the breakup model by Luo and Svendsen (1996) typically has been used in the past. However, this breakup model was thoroughly reviewed and its practical applicability was questioned. Therefore, three different breakup models by Martínez-Bazán et al. (1999a, b), Lehr et al. (2002) and Alopaeus et al. (2002) were implemented in the CFD solver and applied to the system. The resulting Sauter mean diameters and local bubble size distributions were compared with experimental data.
The numerical investigation of the mixing process in complex geometry micromixers, as a function of various inlet conditions and various micromixer vibrations, was performed. The examined devices were two-dimensional (2D) and three-dimensional (3D) types of serpentine micromixers with two inlets. Entering fluids were perturbed with a wide range of the frequency (0 - 50 Hz) of pulsations. Additionally, mixing fluids also entered in the same or opposite phase of pulsations. The performed numerical calculations were 3D to capture the proximity of all the walls, which has a substantial influence on microchannel flow. The geometry of the 3D type serpentine micromixer corresponded to the physically existing device, characterised by excellent mixing properties but also a challenging production process (Malecha et al., 2009). It was shown that low-frequency perturbations could improve the average mixing efficiency of the 2D micromixer by only about 2% and additionally led to a disadvantageously non-uniform mixture quality in time. It was also shown that high-frequency mixing could level these fluctuations and more significantly improve the mixing quality. In the second part of the paper a faster and simplified method of evaluation of mixing quality was introduced. This method was based on calculating the length of the contact interface between mixing fluids. It was used to evaluate the 2D type serpentine micromixer performance under various types of vibrations and under a wide range of vibration frequencies.
The two chosen estates, Garnizon and Wiszace Ogrody have evolved during the last decade or so in Gdańsk. Both developed with the idea of balanced functionality and New Urbanism despite very diff erent locations. The aim was to combine apartment buildings with shops, other services, hotels, offi ce buildings and cultural venues. Numerous interesting and inviting public spaces were also high on the agenda. It was intended to create an interesting, multifunctional space, to maximise the use of the space throughout the day, also making it eco friendly by minimising the use of cars. That`s how an interesting, beautifull space impacts the energy. The centrally located Garnizon has been quite successful, whereas the more peripherally placed Wiszące Ogrody has not quite succeeded due to fi nancial restrictions and is mainly a housing estate at the moment. The hope is that it will grow into a similar entity with new development and helped by the new rail link.
The Polish language in Lithuania, Belorussia and Ukraine has been researched from many points of view, but it needs further studying. New material is required: records, letters, diaries, treatises, especially for researching standard Polish of the 20th century in its regional variant spoken by magnats, middle nobility, petty nobility living in villages, and by inteligentsia of cities and small towns. Also there are needed new methodological approaches to studying essential features of Polish mentioned above, which will take into account the frequent (common) traits as well as relict ones. The examination of these features will create a good base for distinguishing separate areas of the Polish language in Lithuania and Belorussia. The characteristic of vocabulary requests confrontation of words among others in synonymic pairs: native and foreign ones in register and in text, preferably based on computer text corps. To ascertain code mixing (also to find the homogenous/mixed character of the texts) it is necessary to apply both a panchronic approach (which regards all foreign elements), and a synchronic one (leaving out those foreign elements, which entered the grammatical or lexical systems of Polish). The paper proposes some ways for solving these problems
A pair of fast competitive reactions, neutralization and 2,2-dimetoxypropane (DMP) hydrolysis, has been applied do study mass transfer and micromixing in a T 50 Ultra-Turrax® - IKA rotor-stator device. In experiments the dispersed organic phase containing p-Toluenesulfonic acid (pTsOH) dissolved in diisopropyl ether, whereas the continuous phase was represented by the aqueous solution of sodium hydroxide, 2,2-dimetoxypropane (DMP) and ethanol. During mixing a fast mass transfer of a solute (pTsOH) from organic phase droplets, which were shrinking due to fast dissolution of the organic solvent, was followed by micromixing and chemical reactions in the continuous phase. Measured hydrolysis yields were applied to express effects of mixing on the course of chemical reactions. Modeling was based on application of models describing drop breakup, mass transfer in the liquid-liquid system and micromixing. Combined effects of mass transfer and drop breakage on drop population were expressed using the population balance equations. The model has been used to interpret experimental results, in particular to identify the efficiency of mixing.
Energetic efficiency depicting the fraction of energy dissipation rate used to perform processes of drop breakup and mass transfer in two-phase, liquid-liquid systems is considered. Results of experiments carried out earlier in two types of high-shear mixers: an in-line rotor-stator mixer and a batch rotor-stator mixer, have been applied to identify and compare the efficiency of drop breakage and mass transfer in both types of mixers. The applied method is based on experimental determination of both: the product distribution of chemical test reactions and the drop size distributions. Experimental data are interpreted using a multifractal model of turbulence for drop breakage and the model by Favelukis and Lavrenteva for mass transfer. Results show that the energetic efficiency of the in-line mixer is higher than that of the batch mixer; two stator geometries were considered in the case of the batch mixer and the energetic efficiency of the device equipped with a standard emulsor screen (SES) was higher than the efficiency of the mixer equipped with a general purpose disintegrating head (GPDH) for drop breakup but smaller for mass transfer.