Unique and independent historical observations, carried out in the central Arctic during the early twentieth century warming (ETCW) period, were used to evaluate the older (20CRv2) and newer (20CRv2c) versions of the 20th Century Reanalysis and the HIRHAM5 regional climate model. The latter can reduce several biases compared to its forcing data set (20CRv2) probably due to higher horizontal resolution and a more realistic cloud parameterization. However, low-level temperature and near-surface specific humidity agree best between 20CRv2c and the surface-based observations. This better performance results from more realistic lower boundary conditions for sea ice concentration and sea surface temperature, but it is limited mainly to polar night. Although sea level pressures are very similar, the vertical stratification and baroclinicity change in the transition from 20CRv2 to 20CRv2c. Compared to observed temperature profiles, the systematic cold bias above 400 hPa remains almost unchanged indicating an incorrect coupling between the planetary boundary layer and free troposphere. In addition to surface pressures, it is therefore recommended to assimilate available vertical profiles of temperature, humidity and wind speed. This might also reduce the large biases in 10 m wind speed, but the reliability of the sea ice data remains a great unknown.
The aim of this research was to study the biodiversity of cyanobacteria and microalgae in hydro-terrestrial habitats from the area of Hornsund fjord (Svalbard archipelago). This research is particularly important, because hitherto no complex research (including all taxonomic groups) has previously been conducted on the cyanobacterial and microalgal flora in Arctic water ecosystems. The research was conducted during the summer seasons of 2011 and 2013. Shannon’s diversity index was used to describe species diversity and evenness. Data on cyanobacteria and microalgae were analyzed using the MVSP and PCA. Additionally, a basic analysis of the physicochemical properties of water in the studied ecosystems was performed. A total of 506 taxa were noted in the studied hydro-terrestrial habitats. The most numerous group was cyanobacteria, constituting 35% of all recorded taxa. Ochrophyta and Chlorphyta were almost equally numerous (percentage again as for cyanobacteria). Nineteen types of assemblages were noted in all studied hydro-terrestrial habitats. The diversity of cyanobacteria and microalgae and the assemblages formed by them were used to determine the characteristics of the studied ecosystems. Each type of water ecosystem was represented by specific phycoflora and assemblages. Ecological parameters along with biological data (the diversity of cyanobacteria and microalgae) allowed us to sort the studied hydro-terrestrial habitats by similarity. Our analyses clearly distinguished water ecosystem groups differing in species composition determining their trophic status. The research shows the usefulness of cyanobacteria and microalgae diversity defined by the Shannon-Weaver index for characterizing bodies of water and determining the trophic status of these habitats.
Beach pollution is one of the most common hazards in present-day anthropogenic environments. Even in the remote Svalbard Archipelago, pollution impacts the beach system and can pose environmental threats. The significant increase in human activity observed in Svalbard over the last 20–30 years has resulted in a visible change in the amount of coastal pollution. A 5 km long transect of modern beach developed along Calypsostranda (Recherchefjorden, Bellsund) was surveyed in the summer of 2015 in order to characterize the beach pollution. During the survey 296 pieces of trash were found on beach surface. 82% of found trash was plastic, followed by glass (8%), and metal (5%). The comparison with previous pollution survey showed the significant increase of plastic waste in local beach environment. Similar problem has been recently recorded in other parts of Svalbard suggesting an urgent need for coastal pollution monitoring.
Usnea aurantiaco-atra is the dominant flora around King George Island, Antarctica, whose specimens exhibited various phenotypes, even for those with the same ITS sequences in both mycobiont and photobiont. A comprehensive analysis of morphological traits of U. aurantiaco-atra including the reproductive structures, growth forms and ornamentation, cross section of the branches, and the substratum was carried out. Four arbitrary groups were identified based on their reproductive characters, but these groups cannot be distinguished from molecular phylogenetic trees based on fungal or algal ITS sequences. Further, the complicated morphological diversity of the thalli with the same ITS haplotypes in both mycobiont and photobiont suggest that some other factors in addition to the symbionts could influence the morphology of lichens. This implies that lichen is indeed a complex-mini-ecosystem rather than a dual symbiotic association of fungus and alga. Also, a lichenous fungi Phacopsis sp. was identified based on its anatomical characters and ITS sequence, which was also responsible for the black burls-like structures on U. aurantiaco-atra.
The Antarctic Peninsula region has experienced a recent cooling for about 15 years since the beginning of the 21st century. In Livingston Island, this cooling has been of 0.8°C over the 12-yr period 2004–2016, and of 1.0°C for the summer average temperatures over the same period. In this paper, we analyse whether this observed cooling has implied a significant change in the density of the snowpack covering Hurd and Johnsons glaciers, and whether such a density change has had, by itself, a noticeable impact in the calculated surface mass balance. Our results indicate a decrease in the snow density by 22 kg m-3 over the study period. The density changes are shown to be correlated with the summer temperature changes. We show that this observed decrease in density does not have an appreciable effect on the calculated surface mass balance, as the corresponding changes are below the usual error range of the surface mass balance estimates. This relieves us from the need of detailed and time-consuming snow density measurements at every mass-balance campaign.
Different chromosomal forms of Deschampsia antarctica Desv. (Poaceae), including diploids (2n=26), hypotriploid (2n=36–38) and a genotype with an occasional occurrence of B chromosome (2n=26+0-1B) that originated from southern marginal populations (Argentine Islands region, maritime Antarctic) were studied using molecular cytogenetic, morphometric and biochemical methods. FISH analysis revealed variations in the number of rDNA sites between the diploid and hypotriploid plants. The genome size varied among plants with a different chromosome number and was on average 10.88 pg/2C for diploids and 16.46 pg/2C for hypotriploid. The mean values of leaf length of plants grown in vitro varied within a range of 5.23–9.56 cm. The total phenolic content ranged from 51.10 to 105.40 mg/g, and the total flavonoid content ranged from 1.22 to 4.67 mg/g. The amount of phenolic compounds did not differ significantly between the genotypes, while a variation in the flavonoid content was observed for L59 and DAR12. The diploids did not differ significantly among each other in terms of the number of rDNA loci, but differed slightly in their genome size. The individuals of DAR12 carrying B chromosome were similar to other diploids in terms of their genome size, but statistically differed in leaf length. The hypotriploid had both a greater number of rDNA sites and a larger genome size. No statistical correlations were observed between the genome size and leaf length or genome size and accumulation of phenolic and flavonoid compounds. The results of this study suggest that D. antarctica plants from the southern edge of the range are characterised by the heterogeneity of the studied parameters.
In polar regions, apart from tundra and glaciers, geothermally active areas with elevated temperatures are important elements of ecosystems. One such geothermally active region characterized by mosaic ecosystems and vast areas covered by recent lava fields is Iceland. The aim of our study was to explore the diversity of invertebrates inhabiting geothermally active lava fields in the Krafla area (Iceland). Eight bryophyte samples were collected from a warm surface, mainly from the steaming areas. We have found Nematoda, Rotifera, Tardigrada and Oribatida in the samples. Habitat analysis demonstrated there to be 12 bryophyte species (five liverworts and seven mosses). The diversity of bryophytes in a single sample ranged from one to six species. The most common bryophyte was Racomitrium lanuginosum (Hedw.) Brid. Four species of tardigrades were found, including one that was new. Pilatobius islandicus sp. nov. is described herein by morphological, morphometric and molecular approaches (COI, 28S rRNA, 18S rRNA). Oribatida mites were identified as two species (Malaconothrus monodactylus (Michael, 1888) and Camisia foveolata Hammer, 1955). The average density of invertebrates was 13.1 ind./g with a maximum of 40.8 ind./g calculated per dry material. The tardigrades found in our study belonged to herbivores, microbivores and omnivores, whereas the mites belonged to saprophages, which indicates complex trophic networks in geothermally active lava fields.
Climate change has been affecting plants over the last century and caused changes in life history features such as the flowering time. Herbarium specimens provide a snapshot of the past environmental conditions during their collection. The collection date in a herbarium specimen is a good proxy to determine the flowering period (phenology). In this study, phenological data from subarctic plant specimens collected over 100 years were gathered by using one of the largest herbarium databases in the World. The collection dates of 7146 herbarium specimens were analyzed and significant shifts in the phenology of subarctic plants were detected. In this study, most of the analyzed 142 species in a subarctic biogeographic region tended to flower earlier in the 1950–2018 period compared to the 1900–1949 as a possible result of the climate change. Flowering time shifted from 8 to 26 days in some species. Changes in flowering time may alter species interactions, community composition, and species distribution in a region. Therefore, results of this study may shed light on the possible shifts in phenology and plant responses under the climate change.
This article aims to analyse the influence of weather types on meteorological conditions in Petuniabukta (Svalbard) during July and August of 2016. The paper analyses the daily courses of air temperature and humidity at four measurement points located on the west bank of Petuniabukta near Adam Mickiewicz University Polar Station during two different types of weather conditions: (i) cloudy and windy, (ii) calm and clear. These weather types, distinguished on the basis of wind speed and cloudiness, allowed for the creation of composite maps of the synoptic situation (SLP and geopotential height of 500 hPa distribution) and its anomalies. In the study area, the air temperature range in windy and cloudy weather conditions was larger (-10°C to 15°C) than that in sunny and calm weather (0°C to 15°C), which contrasts the range of humidity values. The diurnal cycle of meteorological elements in sunny and calm days is strongly related to the sun elevation angle. In the above-mentioned weather types, the air temperature was higher by several degrees (median 5°C to 8°C) than on windy and cloudy days (median about 0°C to 6°C) at each measurement point. On days with sunny and calm weather, a smaller vertical temperature gradient of air is observed (for sunny and calm days 0.63°C and for windy weather 0.8°C).
Because of excellent properties, similar to natural bone minerals, and variety of possible biomedical applications, hydroxyapatite (HAp) is a valuable compound among the calcium phosphate salts. A number of synthesis routes for producing HAp powders have been reported. Despite this fact, it is important to develop new methods providing precise control over the reaction and having potential to scale-up. The main motivation for the current paper is a view of continuous synthesis methods toward medical application of produced hydroxyapatite, especially in the form of nanoparticles.
A novel absorbing pervaporation hybrid technique has been evaluated experimentally for the recovery of ammonia from the gas mixture in a recycle loop of synthesis plants. This process of hybridization brings together the combination of energy-efficient membrane gas separation based on poly(dimethylsiloxane) poly(diphenylsilsesquioxane) with a high selective sorption technique where a water solution with polyethylene glycol 400 (PEG-400) was used as the liquid absorbent. Process efficiency was studied using the pure and mixed gases. The influence of PEG-400 content in aqueous solutions on process selectivity and separation efficiency was studied. The ammonia recovery efficiency evaluation of an absorbing pervaporation technique was performed and compared with the conventional membrane gas separation. It was shown that the absorbing pervaporation technique outperforms the conventional membrane method in the whole range of productivity, producing the ammonia with a purity of 99.93 vol.% using the PEG 80 wt.% solution. The proposed method may be considered as an attractive solution in the optimization of the Haber process.
This paper analyses the real behaviour of the fluid in the channels of a three-end membrane module. The commonly accepted mathematical model of membrane separation of gas mixtures in such modules assumes a plug flow of fluid through the feed channel and perfect mixing in the permeate channel. This article discusses the admissibility of accepting such an assumption regarding the fluid behaviour in the permeate channel. Throughout analysis of the values of the Péclet number criterion, it has been demonstrated that in the industrial processes of membrane gas separation, the necessary conditions for the perfect mixing in the permeate channel are not met. Then, CFD simulations were performed in order to establish the real fluid behaviour in this channel. It was proved that in the permeate channel the fluid movement corresponds to the plug flow, with the concentration differences at both ends of the module being insignificant. In view of the observations made, the admissibility of concentration stability assumptions in the mathematical models for the permeate channel was discussed.
The aim of this article is to present a modern method of convective drying intensification caused by the external action of ultrasound. The purpose of this study is to discover the mechanism of ultrasonic interaction between the solid skeleton and the moisture in pores. This knowledge may help to explain the enhancement of drying mechanism affected by ultrasound, particularly with respect to biological products like fruits and vegetables. The experimental kinetics tests were conducted in a hybrid dryer equipped with a new ultrasonic generator. The drying kinetics curves determined on the basis of drying model developed by the author were validated with those by the ones obtained from experimental tests. The intensification of heat and mass transfer processes due to ultrasound induced heating effect and vibration effect are analysed. The obtained results allow to state that ultrasound makes drying processes more effective and enhance the drying efficiency of biological products without significant elevation of their temperature.
In this paper the influence of high power airborne ultrasound on drying biological material (Lobo apple) properties is considered. Apple samples were dried convectively at 75 ◦C and air flow of 2 m/s with and without ultrasound assist at 200W. During experiments, sun-drenched and not sun-drenched part of fruits were considered separately to show, how the maturity of the product influences dry material properties. Dried apple crisps in a size of small bars were subjected to compression tests during which acoustic emission (AE) was used. Analysis of AE and strength test results shows that correlations between received acoustic signals and sensory attributes (crispness, brittleness) of dried apples can be found. It was noted that ultrasound improved fruit brittleness in comparison with pure convective processes, where fruit maturity determines a kind of destruction and behaviour of dried apple crisps.
Comparative calculations with a mathematical model designed by the authors, which takes into consideration energy transfer from gas flowing through a given channel to gas which penetrates this channel from an adjacent channel, as well as a model which omits this phenomenon, respectively, were made for the process of separating gas mixtures carried out with an inert sweep gas in the fourend capillary membrane module. Calculations were made for the process of biogas separation using a PMSP polymer membrane, relative to helium as the sweep gas. It was demonstrated that omitting the energy transfer in the mathematical model might lead to obtaining results which indicate that the capacity of the process expressed by the value of feed flux subjected to separation is by several percent higher than in reality.
Carbon dioxide (CO2) is a compound responsible for the greenhouse effect. One of the methods of CO2 capture from the gas stream is adsorption process. In this paper, the adsorption equilibrium isotherms of CO2 on zeolite 13X were measured at different temperatures (293.15 K, 303.15 K, 313.15 K, 323.15 K, 333.15 K, 348.15 K, 373.15 K, 393.15 K) and under pressures up to 2 MPa. These data were obtained using an Intelligent Gravimetric Analyzer (IGA-002, Hiden Isochema, UK). Selected multitemperature adsorption isotherm equations, namely Toth, Langmuir–Freundlich, and, Langmuir were correlated with experimental data.
The aim of this work was to investigate the influence of distilled water flowrate in two different porousmembrane modules on the size of generated nitrogen nanobubbles. Modules had different diameter and number of membrane tubes inside the module. As bubbles are cut off from the membrane surface by a shear stress induced by the liquid flow, the change in the linear liquid velocity should result in a change of the generated bubble diameter. For both modules, higher flowrate of liquid induced generation of smaller bubbles, which was consistent with our expectations. This effect can help us in generation of bubbles of desired size.
This paper presents an experimental study on chicken egg white solution ultrafiltration, where membrane fouling has been the main point of concern. Separation process has been performed with a 150 kDa tubular ceramic TiO2/Al2O3 membrane. The operating parameters have been set as follows: transmembrane pressure 105–310 kPa, cross-flow velocity 2.73–4.55 m/s, pH 5 and constant temperature of 293 K. Resistance-in-series model has been used to calculate total resistance and its components. The experimental data have been described with four pore blocking models (complete blocking, intermediate blocking, standard blocking and cake filtration). The results obtained show that the dominant fouling mechanism is represented by cake filtration model.
Silica multichannel monoliths modified with zirconia, titania and alumina have been used as reactive cores of microreactors and studied in chemoselective reduction (MPV) of cyclohexanon/benzaldehyde with 2-butanol as a hydrogen donor. The attachment of metal oxides to the silica surface was confirmed by FT–IR spectroscopy, and dispersion of metal oxides was studied by UV–Vis spectroscopy. the catalytic activity of the lewis acid centres in both chemical processes decreased in the order zirconia > alumina > titania. This activity is in good agreement with dispersion and coordination of metal species. good stability of zirconia-grafted reactors was confirmed. high porosity of the monoliths and the presence of large meandering flow-through channels with a diameter of ca. 30 mm facilitate fluid transport and very effective mixing in the microreactors. The whole synthesis process is perfectly in line with trends of modern flow chemistry