Dynamic Mine disasters can be induced by the instability and failure of a composite structure of rock and coal layers during coal mining. Coal seam contains many native defects, severely affecting the instability and failure of the compound structure. In this study, the effects of coal persistent joint on the strength and failure characteristics of coal-rock composite samples were evaluated using PFC2D software. The results show that with the increase of included angle α between the loading direction and joint plane direction, the uniaxial compressive stress (UCS) and peak strain of composite samples first decrease and then gradually increase. The elastic moduli of composite samples do not change obviously with α. The peak strain at α of 45° is the lowest, and the UCS at α of 30° is the smallest. This is inconsistent with theoretical analysis of lowest UCS at α of 45°. This is because that the local stress concentration caused by the motion inconformity of composite samples may increase the average axial stress of upper wall in PFC2D software. Moreover, the coal persistent joint promotes the transformation from the unstable crack expansion to the macro-instability of composite samples, especially at α of 30° and 45°. The majority of failures for composite samples occur within the coal, and no obvious damage is observed in rock. Their failure modes are shear failure crossing or along the coal persistent joint. The failure of composite sample at α of 30° is a mixed failure, including the shear failure along the persistent joint in coal and tensile failure of rock induced by the propagation of coal persistent joint.
A ceria loaded carbon nanotubes (CeO2/CNTs) nanocomposites photocatalyst was prepared by chemical precipitation, and the preparation conditions were optimized using an orthogonal experiment method. HR-TEM, XRD, UV-Vis/DRS, TGA and XPS were used to characterize the photocatalyst. Nitrogen adsorption-desorption was employed to determine the BET specific surface area. The results indicated that the photocatalyst has no obvious impurities. CeO2 was dispersed on the carbon nanotubes with a good loading effect and high loading efficiency without agglomeration. The catalyst exhibits a strong ability to absorb light in the ultraviolet region and some ability to absorb light in the visible light region. The CeO2/CNTs nanocomposites photocatalyst was used to degrade azo dye Acid Orange 7 (40 mg/L). The optical decolorization rate was 66.58% after xenon lamp irradiation for 4 h, which is better than that of commercial CeO2 (43.13%). The results suggested that CeO2 loading on CNTs not only enhanced the optical decolorization rate but also accelerated the separation of CeO2/CNTs and water.