The organic carbon (OC)-rich, black shale succession of the Middle Triassic Bravaisberget Formation in Spitsbergen contains scattered dolomite-ankerite cement in coarser-grained beds and intervals. This cement shows growth-related compositional trend from non-ferroan dolomite (0–5 mol % FeCO3) through ferroan dolomite (5–10 mol % FeCO3) to ankerite (10–20 mol % FeCO3, up to 1.7 mol % MnCO3) that is manifested by zoned nature of composite carbonate crystals. The d13C (-7.3‰ to -1.8‰ VPDB) and d18O (-9.4‰ to -6.0‰ VPDB) values are typical for burial cements originated from mixed inorganic and organic carbonate sources. The dolomite-ankerite cement formed over a range of diagenetic and burial environments, from early post-sulphidic to early catagenic. It reflects evolution of intraformational, compaction-derived marine fluids that was affected by dissolution of biogenic carbonate, clay mineral and iron oxide transformations, and thermal decomposition of organic carbon (decarboxylation of organic acids, kerogen breakdown). These processes operated during Late Triassic and post-Triassic burial history over a temperature range from approx. 40°C to more than 100°C, and contributed to the final stage of cementation of the primary pore space of siltstone and sandstone beds and intervals in the OC-rich succession.
The Passhatten Member (Anisian–Ladinian) is the most westward exposure of the Middle Triassic sedimentary sequence of Spitsbergen. The member has an average organic carbon of 2.21 wt %. The sediments were deposited in a shallow shelf environment under conditions of high biological productivity stimulated by a well−developed upwelling system and an enhanced nutrient supply from land areas. The high biological productivity caused a high supply of organic particles to the shelf bottom. Decomposition of organic matter initiated oxygen deficiency in the bottom waters; however, bottom water dynamics on the shallow shelf temporarily replenished the oxygen. Consequently, the Passhatten Mb section is bioturbated, even in thick black shale horizons and consists of alternately spaced lithological layers with variable organic carbon content. The organic matter is dominated by type II kerogen with a mixture of strongly altered marine and/or land derived organic matter. Calculated initial hydrogen index values suggest oil−prone organic matter similar to kerogen I and II types. The organic matter is in the upper intermediate stage of thermo−catalytic alteration, close to the cata− and metagenetic boundary. Maturity indicators including Rock−Eval, Maximum Temperature, Organic Matter Transformation Ratio, Residual Carbon content, as well as the volume of methane generated suggest mature to overmature organic matter. Methane potential retained in the black shales sequence is significant. Unexpelled gas is estimated at 395 mcf/ac−ft for the examined section.