Validation results of a theoretical model that describes the formation of bromate during ozonation of bromide-containing natural waters are presented. An axial dispersion model integrating the nonideal mixing, mass-transfer and a kinetic model that links ozone decomposition reactions from the Tomiyasu, Fukutomi and Gordon ozone decay model with direct and indirect bromide oxidation reactions, oxidation of natural organicmatter and reactions of dissolved organics and aqueous bromine was verified. Themodel was successfully validated with results obtained both at a laboratory and a full scale. Its applicability to different water supply systems was approved.
The paper presents the results of experimental-simulation tests of expansion-shrinkage phenomena occurring in cast iron castings. The tests were based on the standard test for inspecting the tendency of steel-carbon alloys to create compacted discontinuities of the pipe shrinkage type. The cast alloy was a high-silicone ductile iron of GJS - 600 - 10 grade. The validation regarding correctness of prognoses of the shrinkage defects was applied mostly to the simulation code (system) NovaFlow & Solid CV (NFS CV). The obtained results were referred to the results obtained using the Procast system (macro- and micromodel). The analysis of sensitivity of the modules responsible for predicting the shrinkage discontinuities on selected pre-processing parameters was performed, focusing mostly on critical fractions concerning the feeding flows (mass and capillary) and variation of initial temperature of the alloy in the mould and heat transfer coefficient (HTC) on the casting - chill interface.
The main objective of this study was to analyse the psychometric properties of the Polish adaptation of the Kenny Music Performance Anxiety Inventory – Revised (K -MPAI -R, Kenny, 2009) modified as the Kenny Performance Anxiety Inventory (K -PAI) for a general population of individuals with experience in public performance in fields other than music. Another aim was to test the factor structure of K -PAI on a Polish sample. We analysed the relationship between the scores on K -PAI and general anxiety, depression, attentional control, the scores on the Behavioural Inhibition Scale (BIS) and the Behavioural Activation Scale (BAS) and reward susceptibility. Participants (N = 586) completed the questionnaires in a wider online study. The scores on K -PAI revealed a moderate to strong positive association with different measures of anxiety, trait -anxiety in particular, and negative associations with attentional control and susceptibility to reward. K -PAI scores were strongly associated with depression, but displayed no relationship with the BAS or any of its sub -dimensions. These results generally replicated those obtained on the K -MPAI -R with Australian and Peruvian musicians, indicating the cross -cultural validity of the K -MPAI -R and K -PAI. It is suggested that performance anxiety develops on the basis of the biological predispositions and early negative experiences in performance contexts.
The presented paper describes the results of an experiment determining the instantaneous values of velocity vector components of the air stream at selected spots of the boundary layer formed at the sidewalls of the mine heading in the ŁP type steel arch support. The experiment was carried out in a mine heading in an active hard coal mine. A 3-axis thermoanemometric probe was used to obtain three-dimensional distributions of the velocity and turbulent values, such as turbulence intensity and turbulent kinetic energy of the flowing ventilation air stream. The analysis of the measurement results was aided by a numerical solution of the discussed case of flow. The research results presented in this paper provide a basis for extensive studies of the description of velocity distribution and other turbulent quantities within the near-sidewall structures of a mine heading. The objective of these tasks is to improve the accuracy and reliability of numerical calculations relating to air flow in mine headings.
The paper refers to previous publications of the author, focused on criteria of casting feeding, including the thermal criterion proposed by Niyama. On the basis of this criterion, present in the post-processing of practically all the simulation codes, danger of casting compactness (in the sense of soundness) in form of a microporosity, caused by the shrinkage phenomena, is predicted. The vast majority of publications in this field concerns shrinkage and feeding phenomena in the cast steel castings – these are the alloys, in which parallel expansion phenomenon does not occur as in the cast irons (graphite crystallization). The paper, basing on the simulation-experimental studies, presents problems of usability of a classic, definition-based approach to the Niyama criterion for the cast iron castings, especially of greater massiveness, for prediction of presence of zones of dispersed porosity, with relation to predictions of the shrinkage type defects. The graphite expansion and its influence on shrinkage compensation during solidification of eutectic is also discussed.
The paper concerns the problem of discontinuity in high pressure die castings (HPDC). The compactness of their structure is not perfect, as it is sometimes believed. The discontinuities present in these castings are the porosity as follow: shrinkage and gas (hydrogen and gas-air occlusions) origin. The mixed gas and shrinkage nature of porosity makes it difficult to identify and indicate the dominant source. The selected parameters of metallurgical quality of AlSi9Cu3 alloy before and after refining and the gravity castings samples (as DI - density index method), were tested and evaluated. This alloy was served to cast the test casting by HPDC method. The penetrating testing (PT) and metallographic study of both kinds of castings were realized. The application of the NF&S simulation system allowed virtually to indicate the porosity zones at risk of a particular type in gravity and high-pressure-die-castings. The comparing of these results with the experiment allowed to conclude about NF&S models validation. The validity of hypotheses concerning the mechanisms of formation and development of porosity in HPDC casting were also analyzed.
The impact of casting conditions on microstructure a and mechanical properties was described, especially for cast products from AlSi9Cu3 alloy. Particular attention was paid to the parameters of dendritic structure: DAS 1 and DAS 2. Selected mechanical properties (by static tension test) of test castings made using basic technologies of casting: GSC - gravity sand casting, GDC - gravity die-casting and HPDC - high-pressure die-casting, are presented for cast-on test bars and cast separately. Casts were made of the same alloy AlSi9Cu3. Fractures and the zone near the fracture (after static tension test) was subjected to VT - visual tests, PT - penetration tests and metallographic tests. The condition of porosity (fracture zone) was also assessed. The analysis of virtual results was performed using the NovaFlow & Solid system together with the database and they were compared to experimental tests. This way of validation was applied in order to assess the correlation between the local rate of cooling and the size of DAS for GSC, GDC and HPDC technologies. Finally, the correlation between the parameters of structure and mechanical properties with regard to the impact of porosity was signalized.