Liquid AI -Si alloys are usually given special treatments before they are cast to obtain finer or modified matrix and eutectic structures, leading to improved proper ties. For many years, sodium additions to hypoeutectic and eutectic AI -Si melts have been recognized as the most effective method of modifying the eutectic morphology, although most of the group IA or IIA elements have significant effects on the eutectic s tructure. Unfortunately, many of these approaches also have associated several founding difficulties, such as fading, forming dross in presence of certain alloying elements, reduced fluidity, etc. ln recent years, antimony additions to AI -Si castings have attracted considerable attention as an alternative method of refining the eutectic structure. Such additions eliminate many of the difficulties listed above and provide permanent (i.e. non -fading) refining ability. In this paper, the authors summarize work on antimony treatment of Al -Si based alloys.
Porosity is one of the major defects in aluminum castings, which results is a decrease of a mechanical properties. Porosity in aluminum alloys is caused by solidification shrinkage and gas segregation. The final amount of porosity in aluminium castings is mostly influenced by several factors, as amount of hydrogen in molten aluminium alloy, cooling rate, melt temperature, mold material, or solidification interval. This article deals with effect of chemical composition on porosity in Al-Si aluminum alloys. For experiment was used Pure aluminum and four alloys: AlSi6Cu4, AlSi7Mg0, 3, AlSi9Cu1, AlSi10MgCu1.
Aluminium is one of the main soil components. Usually it is a part of non-toxic aluminosilicates but in low pH values its mobility is higher and - especially in monomeric form is toxic for plants. Selenium is an essential element necessary for animals and humans. Its compounds have anticancer and anti mutagenic character. However, its high uptake from environment, e.g. with food or water could lead to various diseases including embryonic deformity, decreased hatchling survival and death to aquatic organisms. Soil contamination with aluminium leads to disturbances in plant growth as a result of low calcium and magnesium uptake. High concentrations of selenium lead to its accumulation in plant tissues what is the beginning of selenium fate in food chain. In this work a cultivated layer of soils located near five industry plants in the town of Opole (southern Poland) were investigated. Aluminium and selenium content in soils is an effect of two factors: its natural occurrence in rocks (natural content) and human activity - especially chemicals from agriculture, industrial and transport pollutants. Aluminium was determined in the range of 3440 to 14804 mg/kg d.w. Obtained results of selenium concentration covered the range from 27.1 to 958.1 μg/kg d.w. These results are slightly higher than concentrations noted in natural or non-polluted soils, but still low. These amounts of selenium could have more positive than negative effects. Aluminium and selenium concentrations were discussed concurrently with base soils parameters, such as pH, EC and granulometric fractions composition.
The paper presents results of bend tests at elevated temperatures of aluminium alloy EN AC-44200 (AlSi12) based composite materials reinforced with aluminium oxide particles. The examined materials were manufactured by squeeze casting. Preforms made of Al2O3 particles, with volumetric fraction 10, 20, 30 and 40 vol.% of particles joined with sodium silicate bridges were used as reinforcement. The preforms were characterised by open porosity ensuring proper infiltration with the EN AC-44200 (AlSi12) liquid alloy. The largest bending strength was found for the materials containing 40 vol.% of reinforcing ceramic particles, tested at ambient temperature. At increased test temperature, bending strength Rg of composites decreased in average by 30 to 50 MPa per 100°C of temperature increase. Temperature increase did not significantly affect cracking of the materials. Cracks propagated mainly along the interfaces particle/matrix, with no effect of the particles falling-out from fracture surfaces. Direction of cracking can be affected by a small number of agglomerations of particles or of non-reacted binder. In the composites, the particles strongly restrict plastic deformation of the alloy, which leads to creation of brittle fractures. At elevated temperatures, however mainly at 200 and 300°C, larger numbers of broken, fragmented particles was observed in the vicinity of cracks. Fragmentation of particles occurred mainly at tensioned side of the bended specimens, in the materials with smaller fraction of Al2O3 reinforcement, i.e. 10 and 20 vol.%.
Main aim of submitted work is evaluation and experimental verification of inoculation effect on Al alloys hot-tear sensitivity. Submitted work consists of two parts. The first part introduces the reader to the hot tearing in general and provides theoretical analysis of hot tearing phenomenon. The second part describes strontium effect on hot tearing susceptibility, and gives the results on hot tearing for various aluminium alloys. During the test, the effect of alloy chemical composition on hot tearing susceptibility was also analyzed. Two different Al-based alloys were examined. Conclusions deals with effect of strontium on hot tearing susceptibility and confirms that main objective was achieved.
The presented work discusses the influence of material of foundry mould on the effect of modification of AlSi11 alloy. For this purpose castings were produced in moulds made of four various materials. Castings of the first type were cast in a metal die, the second ones in the conventional mould of bentonite-bound sand, those of the third type in the sand mould with oil binder, the last ones in a shell mould where phenol-formaldehyde resin was applied as a binder. All the castings were made of AlSi11 alloy modified with strontium. For a purpose of comparison also castings made of the non-modified alloy were produced. The castings were examined with regard to their microstructures. The performed investigations point out that the addition of strontium master alloy results in refining of the alloy structure, particularly of the α-phase, causes some morphological changes in the alloy and the refinement of eutectics. The advantageous influence of modifier on the structure of the examined silumin was observed particularly in the case of alloy cast either in the conventional oil-bound sand mould or in the shell mould. The non-modified alloy cast into a metal die exhibits a structure similar to those of modified alloy solidifying in the other moulds. The improvement in both tensile strength and unit elongation suggests that the modification was carried out correctly. The best mechanical properties were found for the alloy cast in a metal die, both with and without modification treatment.
The paper deals with the impact of technological parameters on the heat transfer coefficient and microstructure in AlSi12 alloy using squeeze casting technology. The casting with crystallization under pressure was used, specifically direct squeeze casting method. The goal was to affect crystallization by pressure with a value 100 and 150 MPa. The pressure applied to the melt causes a significant increase of the coefficient of heat transfer between the melt and the mold. There is an increase in heat flow by approximately 50% and the heat transfer coefficient of up to 100-fold, depending on the casting conditions. The change in cooling rate influences the morphology of the silicon particles and intermetallic phases. A change of excluded needles to a rod-shaped geometry with significantly shorter length occurs when used gravity casting method. By using the pressure of 150 MPa during the crystallization process, in the structure can be observed an irregular silica particles, but the size does not exceed 25 microns.
Pouring of liquid aluminium is typically accompanied by disturbance of the free surface. During these disturbances, the free surface oxide films can be entrained in the bulk of liquid, also pockets of air can be accidentally trapped in this oxide films. The resultant scattering of porosity in castings seems nearly always to originate from the pockets of entrained air in oxide films. Latest version of ProCast software allows to identify the amount of oxides formed at the free surface and where they are most likely to end-up in casts. During a filling calculation, ProCast can calculate different indicators which allow to better quantify the filling pattern. The fluid front tracking indicator “ Free surface time exposure” has the units [cm2*s]. At each point of the free surface, the free surface area is multiplied by the time. This value is cumulated with the value of the previous timestep. In addition, this value is transported with the free surface and with the fluid flow.Experiments to validate this new functions were executed.
The influence of aluminium (added in quantity from about 0.6% to about 2.8%) on both the alloy matrix and the shape of graphite precipitates in cast iron treated with a fixed amounts of cerium mischmetal (0.11%) and ferrosilicon (1.29%) is discussed in the paper. The metallographic examinations were carried out for specimens cut out of the separately cast rods of 20 mm diameter. It was found that the addition of aluminium in the amounts from about 0.6% to about 1.1% to the cast iron containing about 3% of carbon, about 3.7% of silicon (after graphitizing modification), and 0.1% of manganese leads to the occurrence of the ferrite-pearlite matrix containing cementite precipitates in the case of the treatment of the alloy with cerium mischmetal . The increase in the quantity of aluminium up to about 1.9% or up to about 2.8% results either in purely ferrite matrix in this first case or in ferrite matrix containing small amounts of pearlite in the latter one. Nodular graphite precipitates occurred only in cast iron containing 1.9% or 2.8% of aluminium, and the greater aluminium content resulted in the higher degree of graphite spheroidization. The noticeable amount of vermicular graphite precipitates accompanied the nodular graphite.
This paper presents a study of the effect of the modification and cooling rate on the grain count α(Al) in the Al-5Cu alloy. Research was performed on castings with walls thickness between 3 mm and 25 mm. Cooling curves were recorded to determine the cooling rate and the degree of undercooling at the beginning of solidification. It has been shown that cooling rate increases exponentially as the wall thickness of casting decreases. Moreover it has been demonstrated that the cooling rate of castings changes within a wide range (21ºC/s - 1ºC/s) when the wall thickness changes from 3 up to 25 mm. Metallographic examinations revealed primary grains (primary α(Al) grains). The paper show that the relationship between the grain count and the degree of undercooling (for non-modified and modified alloys) can be represented by the equation N = Nv = np·exp(-b/ΔTα), based on the Weibull's distribution of the size of nucleation sites.
The results of examinations of the influence of titanium-boron inoculant on the solidification, the microstructure, and the mechanical properties of AlZn20 alloy are presented. The examinations were carried out for specimens cast both of the non-modified and the inoculated alloy. There were assessed changes in the alloy overcooling during the first stage of solidification due to the nuclei-forming influence of the inoculant. The results of quantitative metallographic measurements concerning the refinement of the grain structure of casting produced in sand moulds are presented. The cooling rate sensitivity of the alloy was proved by revealing changes in morphology of the α-phase primary crystals. Differences in mechanical properties resulting from the applied casting method and optional inoculation were evaluated.
The article contains basic information associated with the impact of the FSW process parameters on the forming of a weld while friction welding of aluminium casting alloys. Research was conducted using specially made samples containing a rod of casting alloy mounted in the wrought alloy in the selected area of FSW tool acting. Research has thrown light on the process of joining materials of significantly dissimilar physical properties, such as casting alloys and wrought alloys. Metallographic testing of a weld area has revealed the big impact of welding conditions, especially tool rotational speed, on the degree of metal stirring, grain refinement and shape factor of a weld. As the result of research it has been stated that at the high tool rotational speed, the metals stirring in a weld is significantly greater than in case of welding at low rotational speeds, however this fails to influence the strength of a weld. Plastic strain occurring while welding causes very high refinement of particles in the tested area and changing of their shape towards particles being more equiaxial. In the properly selected welding conditions it is possible to obtain joints of correct and repeatable structure, however in the case of the accumulation of cavities in the casting alloy the FSW process not always eliminates them.
It is really hard to determine the phenomena occurring during aluminum refining process using argon blowing through the liquid metal in industrial conditions. The solution of such problem is physical modelling. This kind of modelling gives possibility to determine the level of dispersion of the refining gas in liquid metal. Especially in steel metallurgy RTD (Residence Time Distribution) analysis and visualization process with some colour tracer, which can give extra information about time of mixing are very popularly used. Because the modelling research (especially visualization) is pictorial, the research was conducted to check if it is possible to estimate quantitatively impeller working effectiveness basing on determination of the RTD curves. The examined object was model of URO-200 batch refining reactor. The RTD curves was registered and discussed for three different impellers and four different variants of processing parameters (rotary impeller speed: 300-500 rpm, and gas flow rate: 15-20 l·min–1). Additionally, the process of mixing of the inert gas with water as a modelling agent was enabled to be observed due to introduction of colour tracer (KMnO4). Results obtained from both measuring methods were graphically presented, compared and shortly discussed.
The work determined the influence of aluminium in the amount from about 1% to about 7% on the graphite precipitates in cast iron with relatively high silicon content (3.4% to 3.90%) and low manganese content (about 0.1%). The cast iron was spheroidized with cerium mixture and graphitized with ferrosilicon. The performed treatment resulted in occurring of compact graphite precipitates, mainly nodular and vermicular, of various size. The following parameters were determined: the area percentage occupied by graphite, perimeters of graphite precipitates per unit area, and the number of graphite precipitates per unit area. The examinations were performed by means of computer image analyser, taking into account four classes of shape factor. It was found that as the aluminium content in cast iron increases from about 1.1% to about 3.4%, the number of graphite precipitates rises from about 700 to about 1000 per square mm. For higher Al content (4.2% to 6.8%) this number falls within the range of 1300 – 1500 precipitates/mm2 . The degree of cast iron spheroidization increases with an increase in aluminium content within the examined range, though when Al content exceeds about 2.8%, the area occupied by graphite decreases. The average size of graphite precipitates is equal to 11-15 μm in cast iron containing aluminium in the quantity from about 1.1% to about 3.4%, and for higher Al content it decreases to about 6 μm.
The work determined the influence of aluminium in the amount from about 0.6% to about 8% on graphitization of cast iron with relatively high silicon content (3.4%-3.9%) and low manganese content (about 0.1%). The cast iron was spheroidized with cerium mixture and graphitized with ferrosilicon. It was found that the degree of graphitization increases with an increase in aluminium content in cast iron up to 2.8%, then decreases. Nodular and vermicular graphite precipitates were found after the applied treatment in cast iron containing aluminium in the amount from about 1.9% to about 8%. The Fe3AlCx carbides, increasing brittleness and deteriorating the machinability of cast iron, were not found in cast iron containing up to about 6.8% Al. These carbides were revealed only in cast iron containing about 8% Al.
The influence of aluminium added in amounts of about 1.6%, 2.1%, or 2.8% on the effectiveness of cast iron spheroidization with magnesium was determined. The cast iron was melted and treated with FeSiMg7 master alloy under industrial conditions. The metallographic examinations were performed for the separately cast rods of 20 mm diameter. They included the assessment of the shape of graphite precipitates and of the matrix structure. The results allowed to state that the despheroidizing influence of aluminium (introduced in the above mentioned quantities) is the stronger, the higher is the aluminium content in the alloy. The results of examinations carried out by means of a computer image analyser enabled the quantitative assessment of the considered aluminium addition influence. It was found that the despheroidizing influence of aluminium (up to about 2.8%) yields the crystallization of either the deformed nodular graphite precipitates or vermicular graphite precipitates. None of the examined specimens, however, contained the flake graphite precipitates. The results of examinations confirmed the already known opinion that aluminium widens the range of ferrite crystallization.
Water and bottom sediment samples collected from a few fish-breeding ponds/reservoirs were subjected to tests. The aim of this paper was to determine the total content of aluminium and its fractions in the samples tested to estimate the potential risk to fish caused by the toxic forms of aluminium. The monomeric inorganic aluminium in waters was determined using the ion exchange and extraction-colorimetric method with oxychinoline according to Barnes's-Driscoll's procedure. The bottoms were fractionated using a three-step sequential extraction procedure and the microwave mineralisation. The total content of aluminium in waters and extracts was determined using the spectrophotometric method with eriochromocyanine R, and comparatively using the ICP OES technique. The results were subjected to statistical analysis. The level of concentration of labile Al in the waters about 26-34 μg/dm3 and content of exchangeable Al 5-34 mg/g range in bottom sediments are possibly hazardous to aquatic organisms.
In the aluminium alloy family, Al-Zn materials with non-standard chemical composition containing Mg and Cu are a new group of alloys, mainly owing to their high strength properties. Proper choice of alloying elements, and of the method of molten metal treatment and casting enable further shaping of the properties. One of the modern methods to produce materials with submicron structure is a method of Rapid Solidification. The ribbon cast in a melt spinning device is an intermediate product for further plastic working. Using the technique of Rapid Solidification it is not possible to directly produce a solid structural material of the required shape and length. Therefore, the ribbon of an ultrafine grain or nanometric structure must be subjected to the operations of fragmentation, compaction, consolidation and hot extrusion. In this article the authors focussed their attention on the technological aspect of the above mentioned process and described successive stages of the fabrication of an AlZn9Mg2.5Cu1.8 alloy of ultrafine grain structure designated for further plastic working, which enables making extruded rods or elements shaped by the die forging technology. Studies described in the article were performed under variable parameters determined experimentally in the course of the alloy manufacturing process, including casting by RS and subsequent fragmentation.
The research described in this contribution is focused on fractographic analysis of the fracture area of newly developed eutectic silumin type AlSi9NiCuMg0.5 (AA 4032), which was developed and patented by a team of staff of the Faculty of Mechanical Engineering. The paper presents determination of the cause of casting cracks in operating conditions. Fractographic analysis of the fracture area, identification of the structure of the casting, identification of structural components on the surface of the fracture surface and chemical analysis of the material in the area of refraction were performed within the experiment. Al-Si alloys with high specific strength, low density, and good castability are widely used in pressure-molded components for the automotive and aerospace industries. The results shown that the inter-media phases Fe-Al and Fe-Si in aluminium alloys lead to breakage across the entire casting section and a crack that crossed the entire cross section, which was confirmed by EDS analysis.
The paper presents research on the effects of soft annealing parameters on a change of the impact strength KC and Brinell hardness (HB) of the EN AC-AlSi11 alloy. The research has been performed according to the trivalent testing plan for two input parameters – temperature in the range between 280°C and 370°C and time in the range between 2 and 8 hours. The application of such heat treatment improves the plasticity of the investigated alloy. The improvement of the impact strength KC by 71% and the decrease of the hardness HB by 20% was achieved for the soft annealing treatment conducted at a temperature 370°C for 8 hours, compared to the alloy without the heat treatment. A change of the form of eutectic silicon precipitations which underwent refinement, coagulation and partial rounding, had a direct effect on the hardness HB and impact strength KC. The results obtained were used to prepare space plots enabling the temperature and time for soft annealing treatment to be selected with reference to the obtained impact strength KC and hardness HB of the alloy with the heat treatment.
The paper deals with the impact of technological parameters on the mechanical properties and microstructure in AlSi12 alloy using squeeze casting technology. The casting with crystallization under pressure was used, specifically direct squeeze casting method. The goal was to affect crystallization by pressure with a value 100 and 150 MPa. From the experiments we can conclude that operating pressure of 100 MPa is sufficient to influence the structural characteristics of the alloy AlSi12. The change in cooling rate influences the morphology of the silicon particles and intermetallic phases. A change of excluded needles to a rod-shaped geometries with significantly shorter length occurs when used gravity casting method. At a pressure of 100 MPa was increased of tensile strength on average of 20%. At a pressure of 150 MPa was increased of tensile strength on average of 30%. During the experiment it was also observed, that increasing difference between the casting temperature and the mold temperature leads to increase of mechanical properties.
The paper presents relationships between the degree of structure fineness and feeding quality of the Al – 20 wt.% Zn (Al-20 Zn) alloy cast into a mould made from sand containing silica quartz as a matrix and bentonite as a binder, and its damping coefficient of the ultrasound wave at frequency of 1 MHz. The structure of the examined alloy was grain refined by the addition of the refining Al-3 wt.% Ti – 0.15 wt.%C (TiCAl) master alloy. The macrostructure analysis of the initial alloy without the addition of Ti and the alloy doped with 50-100 ppm Ti as well as results of damping experiments showed that the structure of the modified alloy is significantly refined. At the same time, its damping coefficient decreases by about 20-25%; however, it still belongs to the so called high-damping alloys. Additionally, it was found that despite of using high purity metals Al and Zn (minimum 99,99% purity), differences in the damping coefficient for samples cut from upper and bottom parts of the vertically cast rolls were observed. These differences are connected with the insufficient feeding process leading to shrinkage porosity as well as gases present in metal charges which are responsible for bubbles of gas-porosity.
At thermal junctions of aluminium alloy castings and at points where risering proves to be difficult there appear internal or external shrinkages, which are both functionally and aesthetically inadmissible. Applying the Probat Fluss Mikro 100 agent, which is based on nano-oxides of aluminium, results in the appearance of a large amount of fine microscopic pores, which compensate for the shrinking of metal. Experimental tests with gravity die casting of AlSi8Cu3 and AlSi10Mg alloys have confirmed that the effect of the agent can be of advantage in foundry practice, leading to the production of castings without local concentrations of defects and without the appearance of shrinkages and macroscopic gas pores. Also, beneficial effect on the mechanical properties of the metal has been observed.
The paper is devoted to grain-refinement of the medium-aluminium zinc based alloys (MAl-Zn). The system examined was sand cast Zn10 wt. %. Al binary alloy (Zn-10Al) doped with commercial Al-3 wt. % Ti – 0.15 wt. % C grain refiner (Al-3Ti-0.15C GR). Basing on the measured attenuation coefficient of ultrasonic wave it was stated that together with significantly increased structure fineness damping decreases only by about 10 – 20%. The following examinations should establish the influence of the mentioned grain-refinement on strength and ductility of MAl-Zn cast alloys.