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Abstract

The correlation-regression method, as one of the indirect sampling methods, is only sporadically used in geological and mining activities. Theoretically, it should be particularly useful for predicting the content of some chemical components in limestone and marl deposits due to the correlation between them. The results of simple and multiple correlation and regression analysis for 5 selected components (CaO, SiO2, Al2O3, MgO, and SO3), determined in samples from exploratory boreholes and blast holes carried out in the Barcin-Piechcin-Pakość deposit, are presented in the article. The determination coefficients were used as a measure of the correlation power and the quality of the regression models. A very strong linear correlation between CaO and SiO2 content and strong linear correlations between CaO and Al2O3 and SiO2 with Al2O3 have been found. The correlation relationships of the remaining pairs of oxides are weak or very weak and do not provide a basis for prediction of their content based on regression models binding them with the content of other components. The use of nonlinear models for these pairs of oxides results in only a slight improvement in the quality of regression, insignificant from a practical point of view. The application of multiple regression models, linking the content of the mentioned components (with the exception of CaO), leads to similar conclusions. Compared to the determination coefficients of a simple linear correlation, a strong increase in determination coefficients obtained in two cases was found to be artificial and caused by a correlation between the content of the selected components acting as independent variables. From the geological and mining point of view, the results of the analysis indicate the possibility of a fully reliable prediction of SiO2 content and the limited reliability of the Al2O3 content prediction when the CaO content is determined using simple linear regression models.
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Abstract

Air abrasion process is used for cleaning casting surface of prosthetic components, and to prepare the surface of these elements for the application of veneering items. Its side effect, however, is that abrasive particles are embedded in the treated surface, which can be up to 30% of the surface and it constitutes the side effect of this procedure. Such a significant participation of foreign material can not be indifferent to the properties of the surface. Embedded particles can be the place of stress concentration causing cracking of ceramics, and may deteriorate corrosion resistance by forming corrosive microlinks. In the latter cases, it would be advisable to remove elements embedded into the surface. The simplest method is chemical etching or electrochemical one. Nevertheless, these procedures should not significantly change the parameters of the surface. Among many possible reagents only a few fulfills all the above conditions. In addition, processing should not impair corrosion resistance of titanium, which is one of the most important factors determining its use as a prosthetic restoration in the mouth. The study presented results of corrosion resistance of titanium used to make prosthetic components by means of casting method, which were subjected to chemical processing designed to remove the embedded abrasive particles. The aim of the study was to investigate whether etching with selected reagents affects the corrosion resistance of titanium castings. For etching the following reagents were used: 30% HNO3 + 3% HF + H2O, HNO3+ HF+ glycerol (1:2:3), 4% HF in H2O2, 4% HF in H2O, with a control sandblasted sample, not subjected to etching. Tests demonstrated that the etching affected corrosion properties of test samples, in each case the reduction of the corrosion potential occurred - possibly due to the removal of particles of Al2O3 from the surface and activation of the surface. None of the samples underwent pitting corrosion as a result of polarization to 9 V. Values of the polarization resistance, and potentiodynamic characteristics indicated that the best corrosion resistance exhibited the samples after etching in a mixture of 4% solution of HF in H2O2. They showed very good passivation of the surface.
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