Stable isotopes 18O and 13C record of the Kapp Starostin Formation (Late Permian) is presented. The interdependence of δ18O nad δ13C isotope time series is applied for calculating paleotemperatures in the depositional basin of the Kapp Starostin Formation. The obtained results indicate overall cooling from c. 25°—10°C, and confirm some paleogeographical and paleoclimatical inferrences.
The Silurian Pelplin Formation is a part of a thick, mud-prone distal fill of the Caledonian foredeep, which stretches along the western margin of the East European Craton. The Pelplin Formation consists of organic carbon- rich mudstones that have recently been the target of intensive investigations, as they represent a potential source of shale gas. The Pelplin mudstones host numerous calcite concretions containing authigenic pyrite and barite. Mineralogical and petrographic examination (XRD, optical microscopy, cathodoluminoscopy, SEM-EDS) and stable isotope analyses (δ13Corg, δ13C and δ18O of carbonates, δ34S and δ18O of barite) were carried out in order to understand the diagenetic conditions that led to precipitation of this carbonate-sulfide-sulfate paragenesis and to see if the concretions can enhance the understanding of sedimentary settings in the Baltic and Lublin basins during the Silurian. Barite formed during early diagenesis before and during the concretionary growth due to a deceleration of sedimentation during increased primary productivity. The main stages of concretionary growth took place in yet uncompacted sediments shortly after their deposition in the sulfate reduction zone. This precompactional cementation led to preferential preservation of original sedimentary structures, faunal assemblages and early- diagenetic barite, which have been mostly lost in the surrounding mudstones during burial. These components allowed for the reconstruction of important paleoenvironmental conditions in the Baltic and Lublin basins, such as depth, proximity to the detrital orogenic source and marine primary productivity. Investigation of the concretions also enabled estimation of the magnitude of mechanical compaction of the mudstones and calculation of original sedimentation rates. Moreover, it showed that biogenic methane was produced at an early-diagenetic stage, whereas thermogenic hydrocarbons migrated through the Pelplin Formation during deep burial.
A rich collection of exceptionally preserved Lower Triassic fossil fish remains obtained during the Polish Spitsbergen Expedition of 2005 includes many isolated teeth believed to belong to a saurichthyid actinopterygian. Stable isotope analysis ( d 13 C and d 18 O) of putative Saurichthys teeth from the Hornsund area (South Spitsbergen) acting as a paleoenvironmental proxy has permitted trophic−level reconstruction and comparison with other Lower Triassic fish teeth from the same location. The broader range of d 13 C values obtained for durophagous teeth of the hybodont selachian, Lissodus , probably reflects its migratory behaviour and perhaps a greater feeding diversity. X−ray microcomputed tomography (XMT), a non−destructive technique, is used for the first time in order to elucidate de − tails of tooth histology, the results of which suggest that the method has considerable potential as a future analytical tool.
Modern hydrology of a typical Arctic fjord (Hornsund, SW Spitsbergen, Sval− bard) was investigated and compared with commonly used in paleoceanography proxies: benthic foraminiferal assemblages and their stable isotope (#2;18O and #2;13C) composition. The benthic foraminifera from Hornsund comprised 45 species and 28 genera. Their spatial variations follow the zonation pattern, resulting from the influence of Atlantic water at the fjord mouth and glacial meltwaters at the fjord head. At the mouth of the fjord, the total number of species and the contribution of agglutinating species were the highest. In the in− ner part of fjord, the foraminiferal faunas were poor in species and individuals, and aggluti− nating species were absent. “Living” (stained) foraminifera were found to be common throughout the short sediment cores (~10 cm long) studied. The stable isotope values of #2;18O and #2;13C were measured on tests of four species: Elphidium excavatum forma clavata, Cassidulina reniforme, Nonionellina labradorica and Cibicides lobatulus. The results con− firmed the importance of species−specific vital effects, particularly in the case of C. loba− tulus. The variability in the isotopic composition measured on different individuals within a single sample are comparable to isotopic composition of the same species test between sam− pling stations. The temperatures and bottom water salinities calculated from #2;18O values in different foraminifera tests mirrored those recorded for bottom waters in the central and outer fjords relatively well. However, in the case of the inner fjord, where winter−cooled bottom waters were present, the calculated values from #2;18O were systematically higher by about 2#3;C. The obtained results imply that particular caution must be taken in interpretation of fjord benthic foraminifera assemblages in high resolution studies and in selection of ma− terial for isotope analyses and their interpretation in cores from inner fjords or silled fjords, where winter−cooled waters may be present.