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Abstract

This study mixes four different powders to produce Ti-6Cu-8Nb-xCr3C2 (x = 1, 3, and 5 mass%) alloys in three different proportions. The experimental results reveal that when 5 mass% Cr3C2 was added to the Ti-6Cu-8Nb alloys, the specimen possessed optimal mechanical properties after sintering at 1275°C for 1 h. The relative density reached 98.23%, hardness was enhanced to 67.8 HRA, and the transverse rupture strength (TRS) increased to 1821.2 MPa, respectively. The EBSD results show that the added Cr3C2 in situ decomposed into TiC and NbC during the sintering process, and the generated intermetallic compounds (Ti2Cu) were evenly dispersed in the Ti matrix. Furthermore, the reduced Cr atom acts as a β-phase stabilizing element and solid-solution in the Ti matrix. Consequently, the main strengthening mechanisms of the Ti-6Cu-8Nb-xCr3C2 alloys include dispersion strengthening, solid-solution strengthening, and precipitation hardening.
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Authors and Affiliations

Shih-Hsien Chang
1
ORCID: ORCID
Chen-Yu Weng
1
ORCID: ORCID
Kuo-Tsung Huang
2
ORCID: ORCID
Cheng Liang
1
ORCID: ORCID

  1. National Taipei University of Technology, Department of Materials and Mineral Resources Engineering, Taipei 10608, Taiwan, ROC
  2. National Kangshan Agricultural Industrial Senior High School, Department of Auto-Mechanics, Kaohsiung 82049, Taiwan, ROC
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Abstract

In this work, nanosized Ni (nNi) powders of 50 nm are mixed with Cr and Ni submicron-powders (600 nm) to fabricate ­Cr-50 mass% Ni alloys by vacuum hot pressing. In order to evaluate the influence of the nanosized Ni powders, different amounts of nanosized Ni powders are added to produce the Cr-(50-x) mass% Ni-x mass% nNi alloys (x = 0, 10, 20 , and 30). The hot pressing was maintained at 1275°C, 48 MPa for 1 h. The microstructure evaluation, mechanical, and electrical properties were performed. The results reveal that mechanical and electrical properties are enhanced when increasing the nNi addition. The Cr-20 mass% ­Ni-30 mass% nNi presents the highest relative density of 96.53% and the electrical conductivity of 2.18×104 Scm–1, moreover, the hardness and transverse rupture strength values increase to 76.1 HRA and 1217 MPa, respectively. Moreover, a more homogeneous microstructure and a decrease in the mean grain size to 3.15 μm are acquired. Significantly, this fabrication procedure (adding 30 mass% nanosized nickel powders) results in the optimal microstructure, electrical and mechanical properties of submicron-structured Cr-(50-x) mass% Ni-x mass% nNi alloys.
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Authors and Affiliations

Jhong-Ren Huang
1 2
ORCID: ORCID
Shih-Hsien Chang
3
ORCID: ORCID
Cheng-Liang Liao
3
ORCID: ORCID

  1. Tohoku University, Department of Metallurgy, Materials Science and Materials Processing, 6-6-04 Aramaki Aza Aoba, Aoba-ku, Sendai 980-8579, Japan
  2. National Taiwan University of Science and Technology, Department of Chemical Engineering, Taipei 10607, Taiwan, ROC
  3. National Taipei University of Technology, Department of Materials and Mineral Resources Engineering, Taipei 10608, Taiwan, ROC

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