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Abstract

Agricultural residues rich in lignocellulosic biomass are low-cost and sustainable adsorbents widely used in water treatment. In the present research, thermodynamics, kinetics, and equilibrium of nickel(II) and lead(II) ion biosorption were studied using a corncob (Zea mays). The experiments were performed in a batch system evaluating the effect of tempera-ture and dose of adsorbent. Langmuir and Freundlich isotherms were used to study the equilibrium. Thermodynamic and kinetic parameters were determined using kinetic models (pseudo-first order, pseudo-second order, Elovich). Biosorbent characteristics were studied by Fourier-transform infrared spectroscopy, Scanning Electron Microscopy and Energy-dispersive X-ray spectroscopy. It was found that the hydroxyl, carboxyl, and phenolic groups are the major contributors to the removal process. Besides, Pb(II) ions form micro-complexes on the surface of the biomaterial while Ni(II) ions form bonds with active centers. It was found that the highest Ni(II) removal yields were achieved at 0.02 g of adsorbent and 70°C, while the highest Pb(II) removal yields were achieved at 0.003 g and 55°C. A maximum Ni(II) adsorption capacity of 3.52 mg∙g–1 (86%) and 13.32 mg∙g–1 (94.3%) for Pb(II) was obtained in 250 and 330 min, respectively. Pseudo-first or-der and pseudo-second order models best fit experimental data, and Langmuir and Freundlich models well describe the iso-therm of the process. Thermodynamic parameters (ΔH0, ΔG0, ΔS0) suggest that the adsorption process of both cations is exothermic, irreversible, and not spontaneous.
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Bibliography

ABDUL-HAMEED H.M., AL JUBOURY M.F. 2020. MgFe-doubled layers hydroxide intercalated with low cost local adsorbent using for removal of lead from aqueous solution. Journal of Water and Land Development. No. 45 (IV–VI) p. 10–18. DOI 10.24425/jwld.2020.133041.
BABAZADEH R., RAZMI J., PISHVAEE M.S, RABBANI M. 2017. A sustainable second-generation biodiesel supply chain net¬work design problem under risk. Omega. Vol. 66 p. 258–277. DOI 10.1016/J.OMEGA.2015.12.010.
BARDESTANI R., ROY C., KALIAGUINE S. 2019. The effect of biochar mild air oxidation on the optimization of lead(II) adsorption from wastewater. Journal of Environmental Mana¬gement. Vol. 240 p. 404–420. DOI 10.1016/j.jenvman.2019.03.110.
BUREVSKA K., MEMEDI H., LISICHKOV K., KUVENDZIEV S., MARINKOVSKI M., RUSESKA G., GROZDANOV A. 2017. Biosorption of nickel ions from aqueous solutions by natural and modified peanut husks: Equilibrium and kinetics. Water and Environment Journal. Promoting Sustainable Solutions. Vol. 32. Iss. 2 p. 276–284. DOI 10.1111/wej.12325.
CHEN Y., WANG H., ZHAO W., HUANG S. 2018. Four different kinds of peels as adsorbents for the removal of Cd (II) from aqueous solution: Kinetics, isotherm and mechanism. Journal of the Taiwan Institute of Chemical Engineers. Vol. 88. p. 146–151. DOI 10.1016/j.jtice.2018.03.046.
CHERIK D., LOUHAB K. 2018. A kinetics, isotherms, and thermo¬dynamic study of Diclofenac adsorption using activated carbon prepared from olive stones. Journal of Dispersion Science and Technology. Vol. 39. No. 6 p. 814–825. DOI 10.1080/01932691.2017.1395346.
DAI Y., SUN ., WANG W., LU L., LIU M., LI J., ... ZHANG Y. 2018. Utilizations of agricultural waste as adsorbent for the removal of contaminants: A review. Chemosphere. Vol. 211 p. 235–253. DOI 10.1016/j.chemosphere.2018.06.179.
DOBROSZ-GÓMEZ I., GÓMEZ M., SANTA C. 2018. Optimización del proceso de adsorción de Cr(VI) sobre carbón activado de origen bituminoso [Optimization of the Cr(VI) adsorption process on activated carbon of bituminous origin]. Información Tecnológica. Vol. 29. No. 6 p. 43–56. DOI 10.4067/ S0718-07642018000600043.
GAŁCZYŃSKA M., MAŃKOWSKA N., MILKE J., BUŚKO M. 2019. Possibilities and limitations of using Lemna minor, Hydro-charis morsus-ranae and Ceratophyllum demersum in removing metals with contaminated water. Journal of Water and Land Development. No. 40 p. 161–173. DOI 10.2478/jwld-2019-0018.
HAROON H., ASHFAQ T., GARDAZI S.M.H., SHERAZI T.A., ALI M., RASHID N., BILAL M. 2016. Equilibrium kinetic and thermo-dynamic studies of Cr(VI) adsorption onto a novel adsorbent of Eucalyptus camaldulensis waste: Batch and column reactors. Korean Journal of Chemical Engineering. Vol. 33 No. 10 p. 2898–2907. DOI 10.1007/s11814-016-0160-0.
HERNÁNDEZ RODIGUEZ M., YPERMAN J., CARLEER R., MAGGEN J., DADDI D., GRYGLEWICZ G., VAN DER BRUGGEN B., FALCÓN HERNÁNDEZ J., OTERO CALVIS A. 2018. Adsorption of Ni(II) on spent coffee and coffee husk based activated carbon. Journal of Environmental Chemical Engineering. Vol. 6. No. 1 p. 1161–1170. DOI 10.1016/j.jece.2017.12.045.
IBISI N.E., ASOLUKA C.A. 2018. Use of agro-waste (Musa paradisiaca peels) as a sustainable biosorbent for toxic metal ions removal from contaminated water. Chemistry International. Vol. 4. No. 1 p. 52–59.
JOHARI K., SAMAN N., SONG S.T., CHIN C.S., KONG H., MAT H. 2016. Adsorption enhancement of elemental mercury by various surface modified coconut husk as eco-friendly low-cost adsorbents. International Biodeterioration and Biodegra-dation Vol. 109 p. 45–52. DOI 10.1016/j.ibiod.2016.01.004.
KAPLAN INCE O., INCE M., YONTEN V., GOKSU A. 2017. A food waste utilization study for removing lead(II) from drinks. Food Chemistry. Vol. 214 p. 637–643. DOI 10.1016/ j.foodchem.2016.07.117.
LIU Z., DENG X., WANG M., CHEN J., ZHANG A., GU Z., ZHAO C. 2009. BSA-modified polyethersulfone membrane: Prepara-tion, characterization and biocompatibility. Journal of Biomaterials Science, Polymer Edition. DOI 10.1163/156856209X412227.
MANIRETHAN V., GUPTA N., BALAKRISHNAN R.M., RAVAL K. 2019. Batch and continuous studies on the removal of heavy metals from aqueous solution using biosynthesised melanin-coated PVDF membranes. Environmental Science and Pollution Research. Vol. 27 p. 24723–24737. DOI 10.1007/ s11356-019-06310-8.
MANJULADEVI M., ANITHA R., MANONMANI S. 2018. Kinetic study on adsorption of Cr(VI), Ni(II), Cd(II) and Pb(II) ions from aqueous solutions using activated carbon prepared from Cucumis melo peel. Applied Water Science. Vol. 8 No. 1 p. 36. DOI 10.1007/s13201-018-0674-1.
NASEEM K., HUMA R., SHAHBAZ A., JAMAL J., ZIA UR REHMAN M., SHARIF A., …, FAROOQI Z.H. 2019. Extraction of heavy metals from aqueous medium by husk biomass: Adsorption isotherm, kinetic and thermodynamic study. Zeitschrift für Physikalische Chemie. Vol. 233 Iss. 2 p. 201–223. DOI 10.1515/zpch-2018-1182.
OUHIMMOU M., RÖNNQVIST M., LAPOINTE L.-A. 2019. Assessment of sustainable integration of new products into value chain through a generic decision support model: An application to the forest value chain. Omega. Vol. 99, 102173. DOI 10.1016/J.OMEGA.2019.102173.
PRADHAN P., ARORA A., MAHAJANI S.M. 2018. Pilot scale evaluation of fuel pellets production from garden waste biomass. Energy for Sustainable Development. Vol. 43 p. 1–14. DOI 10.1016/j.esd.2017.11.005.
RAVAL N.P, SHAH P.U., SHAH N.K. 2016. Adsorptive removal of nickel(II) ions from aqueous environment: A review. Journal of Environmental Management. Vol. 179 p. 1–20. DOI 10.1016/j.jenvman.2016.04.045.
SHEN Z., ZHANG Y., MCMILLAN O., JIN F, AL-TABBAA A. 2017. Characteristics and mechanisms of nickel adsorption on biochars produced from wheat straw pellets and rice husk. Environmental Science and Pollution Research International. Vol. 24. No. 14 p. 12809–12819.
SINGH S., SHUKLA S. 2017. Theoretical studies on adsorption of Ni(II) from aqueous solution using Citrus limetta peels. Environmental Progress & Sustainable Energy. Vol. 36. No. 3 p. 864–872.
SIREGAR A., SULISTYO I., PRAYOGO N.A. 2020. Heavy metal contamination in water, sediments and Planiliza subviridis tissue in the Donan River, Indonesia. Journal of Water and Land Development. Vol. 45 (IV–VI) p. 157–164. DOI 10.24425/jwld.2020.133057.
TEJADA-TOVAR C., GONZALEZ-DELGADO A., VILLABONA-ORTIZ A. 2019a. Characterization of residual biomasses and its application for the removal of lead ions from aqueous solution. Applied Sciences. Vol. 9. No. 21, 4486. DOI 10.3390/app9214486.
TEJADA-TOVAR C., VILLABONA-ORTÍZ A., GONZÁLEZ-DELGADO Á.D., GRANADOS-CONDE C., JIMÉNEZ-VILLADIEGO M. 2019b. Kinetics of mercury and nickel adsorption using chemically pretreated cocoa (Theobroma cacao) husk. Transactions of the ASABE. Vol. 62. No. 2 p. 461–466. DOI 10.13031/trans.13133.
VALENCIA J.A.R., GONZÁLEZ J.P., JIMENEZ-PITRE I., MOLINA-BOLÍVAR G. 2019. Physico-chemical treatment of waste water contaminated with heavy metals in the industry of metallic coatings. Journal of Water and Land Development. Vol. 43 p. 171–176. DOI 10.2478/jwld-2019-0075.
YI Y., LV J., LIU Y., WU G. 2017. Synthesis and application of modified litchi peel for removal of hexavalent chromium from aqueous solutions. Journal of Molecular Liquids. Vol. 225 p. 28–33. DOI 10.1016/j.molliq.2016.10.140.
YIN W., ZHAO C., XU J., ZHANG J., GUO Z., SHAO Y. 2019. Removal of Cd(II) and Ni(II) from aqueous solutions using activated carbon developed from powder-hydrolyzed-feathers and Trapa natans husks. Colloids and Surfaces A: Physico-chemical and Engineering Aspects. Vol. 560 p. 426–433. DOI 10.1016/j.colsurfa.2018.10.031.

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Authors and Affiliations

Candelaria Tejada-Tovar
1
ORCID: ORCID
Ángel Villabona-Ortíz
1
ORCID: ORCID
Angel Dario Gonzalez-Delgado
1
ORCID: ORCID

  1. University of Cartagena, Avenida del Consulado Calle 30 No. 48-152, Cartagena, Bolívar, Colombia

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