The molecular dynamics of the well-known nematic liquid crystal 4-n-pentyl-4′-cyanobiphenyl geometrically restricted in Anopore and Synpor porous membranes with various pore structure and treated by different surfactants (namely decanoic acid and lecithin) is compared. In the Anopore membrane the chosen surfactants induce the homeotropic orientation of the molecules on the walls of the cylindrical pores and observed corresponding relaxation processes (librational modes) are practically the same. The dielectric measurements of lecithin treated Synpor membranes reveals the reorientation of the molecules from planar to homeotropic on the complex multilayer structure present in their volume. The dielectric strengths of the observed two molecular processes (δ-process and librational mode) are inversed in the ratio compared to the untreated membranes. The observed differences in molecular dynamics results from the orientation of the liquid crystal molecules in untreated and treated membranes and the structure of the membranes themselves.
The purpose of the work was to determine the infuence of the bulk density ρz of granules, processing parameters and the density of ski inserts ρw made of expanded polystyrene (EPS) on their damping properties. For this aim liners for ski helmets with 3 different bulk densities were made. Sintering time and sintering pressure were also changed. The percentage damping factor η was determined on the basis of the results obtained in the rebound resilience test. Based on the analysis of the obtained data, it was found that increasing the density of EPS pads ρw increases their damping properties and at the same time contributes to a decrease in elasticity, increase in hardness and brittleness of EPS products.