Nifedipine, a pyridine derivative was investigated as corrosion inhibitor for API 5L X-52 steel in 2 M HCl solution by potentiodynamic polarization, electrochemical impedance spectroscopy and quantum chemical calculations. Statistical tools were used to compare results of the experimental methods. The results showed that nifedipine is capable of inhibiting the corrosion of API 5L X-52 steel in 2 M HCl solution. Potentiodynamic polarization results reveal that nifedipine functions as a mixed-type inhibitor and presents an inhibition efficiency of about 78% at 500 ppm. Impedance data reveal an increasing charge transfer resistance with increasing inhibitor concentration and also shows comparable inhibition efficiency of about 89-94% at 500 ppm. Thermodynamic parameters imply that nifedipine is adsorbed on the steel surface by a physiochemical process and obeys Langmuir adsorption isotherm. The calculated molecular properties namely the highest occupied molecular orbital energy, lowest unoccupied molecular orbital energy, chemical hardness, energy gap, dipole moment, electronegativity and global nucleophilicity index all show a positive relationship to the observed corrosion inhibition efficiency.
Localization systems are an important component of Active and Assisted Living (AAL) platforms supporting persons with cognitive impairments. The paper presents a positioning system being a part of the platform developed within the IONIS European project. The system’s main function is providing the platform with data on user mobility and localization, which would be used to analyze his/her behavior and detect dementia wandering symptoms. An additional function of the system is localization of items, which are frequently misplaced by dementia sufferers.
The paper includes a brief description of system’s architecture, design of anchor nodes and tags and exchange of data between devices. both localization algorithms for user and item positioning are also presented. Exemplary results illustrating the system’s capabilities are also included.
Experiments have been carried out on the influence exerted by Aroclor 1254 upon the photosynthetic production of organic 14C by an assemblage of marine Antarctic diatoms (Thalassiosira sp. 48%, Nitzschia sp. 21%, Chaetoceros sp. 15% and Corethron iriophilum 10%). Samples of various numbers of cells per cm3 of water have been used. Incorporation of 14C02 by the diatoms proved to be proportional to the increased number of cells in the sample only at the lowest levels of concentration in per cm3. Further increase of the level of 14C in diatoms has not been found as number of cells in the sample kept growing. Calculation of brutto photosynthesis has indicated that low concentration of Aroclor 1254 (0,01 to 1 ppm) may stimulate the photosynthetic incorporation of carbon, yet the photosynthetic release of carbon from cells within the photorespiratory process is stimulated to a higher degree. High concentration of Aroclor (1 to 50 ppm) inhibit the brutto assimilation, yet the release of carbon during the photorespiratory process is inhibited to a higher degree. A hypothesis is being considered implying that the relation between the intensity of photosynthesis and intensity of photorespiration may vary according to the rate of concentration of Aroclor.
This paper describes a “distributed method” of introducing the humanitarian engineering principles and concepts to the curriculum of telecommunications at a maritime university. That is by modifying appropriately the syllabi of the telecommunications subjects taught. The propositions made in this area are illustrated by the concrete examples taken from the current Polish Qualifications Framework for the higher education system in Poland. And, for clarity and consistency of presentation, fundamentals and principles as well as a basic terminology and features of this Framework are also highlighted here shortly. Moreover, it has been shown that the approach presented in this paper is more useful compared to a method based on organization of some special courses for students on the humanitarian engineering, in particular when this regards a maritime university.
In recent years, two developments revolutionized the molecular genetics. The first one is an enormously improved technique of the DNA sequencing. It is now possible to obtain in couple of hours and on the low cost, the full sequence of the human genome. The second one is the invention of the CRISPR-Cas technique, which allows the precise manipulations of genomes of living organisms. This technique was already successfully applied to “repair” human genes responsible for hereditary diseases. To some astonishment, applications of genetic engineering to humans does not bring protests of general public, while similar manipulations pf plants genomes are considered an dangerous. In Poland and in some other countries, parliaments introduced an extremely restrictive laws, which in practice makes cultivation of GM plants outside laboratories impossible. This is caused by the ignorance of the general public and by opposition of catholic church which considers genetic modifications of all organisms as contradictory with Gods will. The most common modification of plants is an introduction into their genomes of the single gene from the bacterium Bacillus thuringensis, what make the plant resistant to harmful insects. According to WHO, neither the manipulation mentioned above, nor manipulations of the other kind, do not pose any danger to humans.