In this paper cation arrangement in two samples of aluminoceladonite, emerald‑green and dark-green were studied by Mössbauer, Raman and X-ray photoelectron spectroscopies. The X-ray photoelectron spectroscopy (XPS) spectra obtained in the region of the Si2p, Al2p, Fe2p, K2p, and O1s core levels provided information, for the first time highlighting a route to identify the position of Si, Al, K, and Fe cations in a structure of layered silicates. The XPS analysis showed the presence of Al in tetrahedral and octahedral coordination while the K2p line indicated the possibility of K+ substitution by other cations in interlayer sites. Mössbauer spectroscopy provided information about crystal chemistry with respect to the local electronic and geometric environment around the Fe atom and to distortions of the polyhedra. It turned out that iron was located mostly in the cis-octahedra position wherein about 75% of iron appeared in the form of Fe ³⁺. The most preferred cation combinations around Fe corresponded to 3Fe ³⁺ ions and MgFe ²⁺Fe ³⁺/2MgFe ³⁺. Raman spectroscopy illustrated aluminium substitution in silicon and iron positions wherein the concentration of the aluminium determined the degree of structural distortion within the layered system. These isomorphic substitutions implied a typical band arrangement in the hydroxyl region, which has not been observed in celadonites so far.

Development of contemporary building industry and related search for new aesthetical and functional solutions of monumental buildings in the centers of large cities resulted in the interest in glass as a structural material. Attractiveness of glass as a building material may be derived from the fact, that it combines transparency and aesthetical look with other functional features. Application of glass results in modern look of building facades, improves the indoor comfort without limiting the availability of natural daylight. Wide implementation of the new high performance float flat glass manufacturing technology, in conjunction with increasing expectations of the construction industry relating to new glass functions, has led to significant developments in glass structures theory, cf. [1, 3, 4, 5, 9, 10]. Many years of scientific research conducted in European Union countries have been crowned with a report CEN/TC 250 N 1050 [2], compiled as a part of the work of European Committee for Standardization on the second edition of Eurocodes - an extension of the first edition by, among others, the recommendations for the above mentioned design of glass structures, in particular modern procedures for the design of glass building structures. The procedures proposed in the pre-code [2] are not widely known in Poland, and their implementation in the design codes should be verified at the country level. This task is undertaken in this paper.

In recent years significant progress has been made in structural application of glass elements in building industry. However, the issues related to computer modelling of glass panes, as well as analytical procedures allowing for taking into account the bonding action of PVB foil are not widely known in the engineering environment. In this paper results of numerical study of laminated glass plates are presented. The scope of the research covers over 40 cases of panes. Narrow (characterized by edge length ���� >2) and square (��/�� = 1) panes made of two or three layer laminated glass have been taken into account. The paper deals mainly with point supported glass. However, selected results for linearly supported plates have been included as well for comparison. For each considered case an advanced computational model have been developed within the environment of Abaqus software. Pointwise supports have been modelled using methods of various complexity. The obtained results have been compared with the results of standard calculations using Wölfel–Bennison and Galuppi– Royer–Carfagni hypotheses. The analytical procedures proposed by CEN have been applied as well. As a result, recommendations for static calculations of laminated glass panes have been formulated. The computational procedure based on the hypothesis presented by L. Galuppi and G. Royer-Carfagni should be considered the most universal. The remaining methods may be applied only in limited scope. In order to estimate maximum principal stress in the support zone an advanced computer model has to be used. The support may be modelled in an exact or simplified manner.