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Abstract

Fatigue crack growth for 2024-T3 Alclad aluminium alloy sheet being subjected to two load programs: a constant stress amplitude cyclic tension (R=O. l) (CA) and a variable amplitude tension with either a single or multiple overloads (OVL) periodically repeated is analysed in the paper. The latter load program corresponds to a simple flight simulation spectrum of wing structure of civil aircraft. The investigation was developed in order to learn about interaction between the applied load and formation of fatigue striations. Experimental results of surface crack growth rate provided by optical observations were compared with the rate determined on the basis of microfracture analysis. Good correspondence found under CA loading between the surface growth rate and the growth rate in the sheet depth means that the direction of specimen's cutting does not change essentially the crack growth behaviour. In the case of second loading (OVL) this factor influences the crack growth behaviour. Microfracture analysis revealed either retardation and acceleration of crack growth rate under OL V loading. This behaviour of growth rate results from a plastic zone formed in the front of crack tip and a crack closure effect.
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Authors and Affiliations

Dorota Kocańda
Stanisław Kocańda
Janusz Torzewski
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Abstract

The aim of the presented research was to test different carbon supports, such as graphene oxide (GO), graphene oxide modified with ammonia (N-GO), and reduced graphene oxide (rGO) for catalysts used in a low-temperature fuel cell, specifically a proton exchange membrane fuel cell (PEMFC). Modification of the carbon supports should lead to different catalytic activity in the fuel cell. Reduction of GO leads to partial removal of oxygen groups from GO, forming rGO. Modification of GO with ammonia results in an enrichment of GO structure with nitrogen. A thorough analysis of the used supports was carried out, using various analytical techniques, such as FTIR spectroscopy and thermogravimetric (TGA) analysis. Palladium and platinum catalysts deposited on these supports were produced and used for the oxygen reduction reaction (ORR). Catalytic activity tests of the prepared catalysts were carried out in a home-made direct formic acid fuel cell (DFAFC). The tests showed that the enrichment of the GO structure with nitrogen caused an increase in the catalytic activity, especially for the palladium catalyst. However, reduction of GO resulted in catalysts with higher activity and the highest catalytic activity was demonstrated by Pt/rGO, because platinum is the most catalytically active metal for ORR. The obtained results may be significant for low-temperature fuel cell technology, because they show that a simple modification of a carbon support may lead to a significant increase of the catalyst activity. This could be useful especially in lowering the cost of fuel cells, which is an important factor, because thousands of fuel cells running on hydrogen are already in use in commercial vehicles, forklifts, and backup power units worldwide. Another method used for lowering the price of current fuel cells can involve developing new clean and cheap production methods of the fuel, i.e. hydrogen. One of them employs catalytic processes, where carbon materials can be also used as a support and it is necessary to know how they can influence catalytic activity.

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Authors and Affiliations

Zuzanna Bojarska
Marta Mazurkiewicz-Pawlicka
Łukasz Makowski

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