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Abstract

The report demonstrates that plenty of methylated flavones of the plant, as the end product of the flavone biosynthesis pathway, are concentrated in the root bark, which largely remains in the waste that makes up 7% w/w of the commercial root and is discarded. The study of the waste extract showed that the last enriched with monomethylated flavones wogonin and oroxylin A, along with some polymethylated ones represent an end of the biosynthesis pathway of flavones in the plant. In addition to wogonin, 7 known methylated flavones were found for the first time in the root bark. Due to a high content of wogonin and oroxylin A in the extract, these flavones were concentrated using preparative liquid chromatography. As a result, the obtained complex of these two target flavones turned out to be 0.8% w/w of the waste. Such morphologically specific accumulation of methylated flavones at the root boundary raises the question of their role in plant life.
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Authors and Affiliations

Yury N. Elkin
1
Nadezhda I. Kulesh
1
Vyacheslav M. Shishmarev
2
Vladimir M. Kargin
3
Artem Y. Manyakhin
4

  1. Pacific Institute Bioorganic Chemistry FEB RAS, 690022, 159 Stoletiya ave., Vladivostok, Russia
  2. Institute of General and Experimental Biology, Siberian Division, Russian Academy of Science, Sakh’yanovoy Str., 6, Ulan-Ude 670047, Russia
  3. Dauria Stock Company, 687510, 14 Spokoininskaja st., Orlovsky stl, Zabaikalsky region, Russia
  4. Federal Scientific Center of the East Asia Terrestrial Biodiversity FEB RAS, 690022, 159 Stoletiya ave., Vladivostok, Russia
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Abstract

This study describes how microstructural constituents affected the hydrogen embrittlement resistance of high-strength pipeline steels. The American Petroleum Institute (API) X60, X70, and X80 pipeline steels demonstrated complicated microstructure comprising polygonal ferrite (PF), acicular ferrite, granular bainite (GB), bainitic ferrite (BF), and secondary phases, e.g., the martensite-austenite (MA) constituent, and the volume fraction of the microstructures was dependent on alloying elements and processing conditions. To evaluate the hydrogen embrittlement resistance, a slow strain rate test (SSRT) was performed after electrochemical hydrogen charging. The SSRT results indicated that the X80 steel with the highest volume fraction of the MA constituent demonstrated relatively high yield strength but exhibited the lowest hydrogen embrittlement resistance because the MA constituent acted as a reversible hydrogen trap site.
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Authors and Affiliations

Seung-Hyeok Shin
1
ORCID: ORCID
Dong-Kyu Oh
1
ORCID: ORCID
Sang-Gyu Kim
1
ORCID: ORCID
Byoungchul Hwang
1
ORCID: ORCID

  1. Seoul National University of Science and Technology, Depart ment of Materials Science and Engineering, 232 Gongneung-ro, Nowon-gu, Seoul 01811, Republic of Korea
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Abstract

The influence on the corrosion behaviour of Co-Mo nano-crystalline coatings of dissolved oxygen is studied in the Ringer’s solution and artificial saliva at 25°C. This was done by means of potentiodynamic tests and surface observations. It was shown that dissolved oxygen has no influence on passivity, oxidation of the coating and selective dissolution of cobalt. By contrast, dissolved oxygen affects corrosion. General corrosion was observed in the Ringer’s solution whereas pitting corrosion was found in artificial saliva.

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Authors and Affiliations

V. Vignal
H. Krawiec
M. Latkiewicz

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