Inexpensive synthesis of electroceramic materials is required for efficient energy storage. Here the design of a scalable process, flame spray pyrolysis (FSP), for synthesis of size-controlled nanomaterials is investigated focusing on understanding the role of air entrainment (AE) during their aerosol synthesis with emphasis on battery materials. The AE into the enclosed FSP reactor is analysed quantitatively by computational fluid dynamics (CFD) and calculated temperatures are verified by Fourier transform infrared spectroscopy (FTIR). Various Li4Ti5O12 (LTO) particle compositions are made and characterized by N2 adsorption, electron microscopy and X-ray diffraction while the electrochemical performance of LTO is tested at various charging rates. Increasing AE decreases recirculation in the enclosing tube leading to lower reactor temperatures and particle concentrations by air dilution as well as shorter and narrower residence time distributions. As a result, particle growth by coagulation - coalescence decreases leading to smaller primary particles that are mostly pure LTO exhibiting high C-rate performance with more than 120 mAh/g galvanostatic specific charge at 40C, outperforming commercial LTO. The effect of AE on FSP-made particle characteristics is demonstrated also in combustion synthesis of LiFePO4 and ZrO2.
In the paper modeling of main inductances for mathematical models of induction motors is applied to study the effects caused by a rotor eccentricity and saturation effects. All three possible types of eccentricity: static, dynamic and mixed are modeled. The most important parameters describing rotor eccentricity include self and mutual inductances of the windings. The structural changes of the permeance function as a result of eccentricity appearance and the Fourier spectra of inductances in occurrence of saturation for each case are determined in the paper. The presented algorithm can be used for the diagnostically specialized models of induction motors.