The theoretical estimation of sound absorption coefficient of a surface may give very different results. This will depend on the type of sound field assumed in the theoretical model used for the estimation of its sound absorption coefficient. Absorption coefficients for normal and diffuse sound fields are widely known, although they may be far from the absorption values given by an absorbing material when it is finally installed inside a room or enclosed space, where a sound field closer to a spherical wavefront is more likely to be found. This work presents a theoretical study, which is addressed at obtaining a mathematical expression to calculate the sound absorption coefficient for a variable range of incidence angles, called αs. The presented method uses a circular sound field incidence as an approximation to a spherical incidence. The estimation of this coefficient αs is based on obtaining the incident and reflected sound fields for a surface located facing a lineal source. The advantage of this calculation method over others lies on its capability to give results for circular, normal and random wave incidence depending on the range of incidence angles considered in the calculation.
The intercalation into interlayer spaces of montmorillonite (MMT), obtained from natural calcium bentonite, was investigated. Modification of MMT was performed by the poly(acrylic acid-co-maleic acid) sodium salt (co-MA/AA). Efficiency of modification of MMT by sodium salt co-MA/AA was assessed by the infrared spectroscopic methods (FTIR), X-ray diffraction method (XRD) and spectrophotometry UV-Vis. It was found, that MMT can be relatively simply modified with omitting the preliminary organofilisation – by introducing hydrogel chains of maleic acid-acrylic acid copolymer in a form of sodium salt into interlayer galleries. A successful intercalation by sodium salt of the above mentioned copolymer was confirmed by the powder X-ray diffraction (shifting the reflex(001) originated from the montmorillonite phase indicating an increase of interlayer distances) as well as by the infrared spectroscopy (occurring of vibrations characteristic for the introduced organic macromolecules). The performed modification causes an increase of the ion exchange ability which allows to assume that the developed hybrid composite: MMT-/maleic acid-acrylic acid copolymer (MMT-co- MA/AA) can find the application as a binding material in the moulding sands technology. In addition, modified montmorillonites indicate an increased ability for ion exchanges at higher temperatures (TG-DTG, UV-Vis). MMT modified by sodium salt of maleic acid-acrylic acid copolymer indicates a significant shifting of the loss of the ion exchange ability in the direction of the higher temperature range (500–700°C).
Studies on the quantity and distribution of organic carbon (DOC and РОС) in the water of the Admiralty Bay were conducted between 20 December 1978 and 15 February 1979. The С org. content ranged from 1.62 to 3.22 mg 1-1 for DOC and from 0.22 to 0.65 mg x 1-1 for РОС. Maximal DOC amounts were observed at the depth 25—50 m (on average about 2.50 mg x 1-1 ) and in chosen regions of surface waters of the Admiralty Bay, among others, in the vicinity of a large penguin colony. Mean content of DOC in waters of the Admiralty Bay (about 2.26 mg x 1-1 ) is lower as compared to mean DOC content in waters of the Bransfield Strait (about 4.12 mg x 1-1).
The environmental assessment of the surface water quality of the Western Bug River has been made using the system of classification quality of land surface water of Ukraine in accordance with the approved methodology, which allows comparing water quality of separate areas of water objects of different regions. The calculation of the environmental as-sessment of water quality has been carried according to three blocks: block of salt composition, block of trophic and sapro-bic (ecological and sanitary) indicators and block of indicators of content of specific toxic substances. The results are pre-sented in the form of a combined environmental assessment, based on the final conclusions of the three blocks and consists in calculating the integral ecological index. Comprehensive studies of changes in the water quality of the Western Bug Riv-er have been conducted within the territory of Ukraine for a long-term period. The water quality of the river on the final values of the integral indicators of the ecological condition corresponded mainly to 4nd category of the 3rd class – the wa-ter is “satisfactory” by condition and “little polluted” by degree of purity (except for points of observation that located within the Volyn region, where the water quality corresponded to 3rd category and the 2nd class. It is “good” by condition and “fairly clean” by the degree of purity). Visualization and part of the analysis are performed using GIS technologies in the software of the ArcGIS 10.3.