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Abstract

In this work, we have designed a new high entropy alloy containing lightweight elements, e.g., Al, Fe, Mn, Ti, Cu, Si by high energy ball milling and spark plasma sintering. The composition of Si was kept at 0.75 at% in this study. The results showed that the produced AlCuFeMnTiSi0.75 high entropy alloy was BCC structured. The evolution of BCC1 and BCC2 phases was observed with increasing the milling time up to 60 h. The spark plasma sintering treatment of milled compacts from 650-950°C showed the phase separation of BCC into BCC1 and BCC2. The density and strength of these developed high entropy alloys (95-98%, and 1000 HV) improved with milling time and were maximum at 850°C sintering temperature. The current work demonstrated desirable possibilities of Al-Si based high entropy alloys for substitution of traditional cast components at intermediate temperature applications.
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Bibliography

[1] J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, C.H. Tsau, S.Y. Chang, Adv. Eng. Mater. 6, 299 (2004).
[2] B.S. Murty, J.W. Yeh, S. Ranganathan, High-Entropy Alloys, 1st edn. Butterworth-Heinemann, Oxford 2014.
[3] B. Cantor, I.T.H. Chang, P. Knight, A.J.B. Vincent, Mater. Sci. Eng. A 375-377, 213 (2004).
[4] B. Cantor, Entropy 16, 4749 (2014). [5] W. Li, S. Cui, J. Han, C. Xu, Rare Met. 25, 133 (2006).
[6] A. Kumar, M. Gupta, Metals 6 (9), 199 (2016)
[7] K.M. Youssef, A.J. Zaddach, C. Niu, D.L. Irving, C.C. Koch, Mater. Res. Lett. 3, 95 (2014).
[8] K. Tseng, Y. Yang, C. Juan, T. Chin, C. Tsai, J. Yeh, Sci China Technol Sci. 61, 184 (2018).
[9] A. Sharma, D.U. Lim, J.P. Jung, Mater. Sci. Technol. 32 (8), 773 (2016).
[10] J.J. Chen, X. Zhou, W. Wang, B. Liu, Y. Lv, W. Yang, D. Xu, Y. Liu, J. Alloy. Compd. 760, 15 (2018).
[11] J.M. Torralba, P. Alvaredo, A.G. Junceda, Powder Met. 63, 227 (2020).
[12] B.D. Cullity, S.R. Stock, Elements of X-ray Diffraction, (3rd ed.), New York, Prentice Hall, 2001.
[13] M.J. Chae, A. Sharma, M.C. Oh, B. Ahn, Met. Mater. Int. 27, 629 (2021).
[14] A. Sharma, M.C. Oh, B. Ahn, Mater. Sci. Eng. A 797, 140066 (2020).
[15] J.M. Sanchez, I. Vicario, J. Albizuri, T. Guraya, E.M. Acuña, Sci Rep. 9, 6792 (2019).
[16] A. Kumar, P. Dekhne, A.K. Swarnakar, M. Chopkar, Mater. Res. Exp. 6, 026532 (2019).
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Authors and Affiliations

Minsu Kim
1
Ashutosh Sharma
1
ORCID: ORCID
Myoung Jin Chae
1
Hansung Lee
1
ORCID: ORCID
Byungmin Ahn
1
ORCID: ORCID

  1. Ajou University, Department of Materials Science and Engineering and Department of Energy Systems Research, 206 Worldcup-ro, Suwon-si, Gyeonggi, 16499, Korea
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Abstract

This study investigates single and multilayer TiAlN/CrN nanocomposite thin films developed using an RF magnetron sputtering system. The TiAlN and CrN layers showed a high degree of orientation, with the (200) peak being the strongest peak in both layers, and a multilayer structure was clearly observed. The surface roughness analysis using atomic force microscopy (AFM) and cross-sectional transmission electron microscopy (TEM) revealed that the TiAlN/CrN coatings had a smoother surface than the single-layer coatings and minimal intermixing between the two layers. Depth-sensing indentation measurements were used to measure the hardness and Young’s modulus of the coatings, demonstrating that TiAlN/CrN coating had the highest hardness (~16.38 GPa) and elastic modulus (~3.82 GPa) among all the coatings studied. This indicates that the TiAlN/CrN multilayer coating possesses superior mechanical properties due to its interface strength. Our findings suggest that these multilayer coatings have potential applications in tribological and decorative coatings.
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Authors and Affiliations

Viswanath G. Akkili
1
ORCID: ORCID
Hansung Lee
2
ORCID: ORCID
Suhyeon Kim
1
ORCID: ORCID
Jun-Hui Choi
3
Choong-Heui Chung
1
ORCID: ORCID
Joon Sik Park
1
Jae-Hyun Lee
3
ORCID: ORCID
Byungmin Ahn
3
ORCID: ORCID
Yoon-Kee Kim
4
Sangyeob Lee
4
ORCID: ORCID

  1. Hanbat National University,Department of Materials Science and Engineering, Daejeon, 34158, Korea
  2. Ajou University, Department of Energy Systems Research, Suwon, 16499, Korea
  3. Ajou University, Department of Energy Systems Research, Suwon, 16499, Korea; Ajou University, Department of Materials Science and Engineering, Suwon, 16499, Korea
  4. Hanbat National University, Department of Materials Science and Engineering, Daejeon, 34158, Korea

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