In this study, a research was conducted to recover metallic zinc and pig iron and to improve the purity and the recovery rate through a reduction process for zinc and iron in the byproducts that are generated after steelmaking dust treatment. As the result of the calcination, it was confirmed that Cl (6.06%) and K (3.37%) decreased to Cl (2.75%) and K (0.22%), respectively. For the zinc powder that was recovered with reaction temperature of 1100°C, reaction time of 4 hours, and argon gas of 1L/min as the optimal conditions. The measurement for the purity of zinc was 99.8% and the recovery rate was 92.14%. The melt reduction for recovering pig iron from the residue was reacted under reaction temperature of 1600°C, flux composition (CaO:SiO2) of 1:1, and reducing agent infusion ratio (residue: C) of 14:1, and the pig iron was measured to have a purity of 87.7% and a recovery rate of 91.81%.