Samples for the study were collected from, known from the literature, outcrop profiles in Zarzecze, Radymno, Dybawka, Tarnawce and Pikulice-Nehrybka, situated at the Carpathian border, in the vicinity of the Przemyśl town, close to the San River valley (SE Poland). They represent the Vistulian loess-palaeosol sequences. Carbonates occur mainly in the loesses representing OIS 2 and 3. Pollen analysis, carried out for two profiles (Tarnawce, Radymno), throws light on palaeoecological conditions of loess cover formation and transformation.Isotopic analysis of authigenic carbonates was carried out on carbonate cemented bodies dispersed throughout the loess in forms of nodule, rhizolith and rhizocretion and on bioclasts, mainly snail shells, ostracod valves, and sparse globules (probably the internal shells of the naked snails).In the successions studied, the upper Vistulian loess deposited in environment with poor vegetation, contains rhizo- liths and rhizocretions mainly, while in the middle and lower Vistulian loess with well developed soils, gley horizons, and intercalations of subaqueous sediments, remains of snail shells and ostracod valves prevail. The two main forms of carbonates differ markedly in isotopic composition from one another. These differences seem to be more important than those between samples of one form of carbonates along particular sections. That is the result of numerous factors affecting the fractionation of carbon and, in particular, oxygen stable isotopes in the environment of precipitation of authigenic calcite. The isotopic composition of carbonates cementing sediments is controlled mainly by biominerali- zation of organic matter and local climatic parameters which were rather slightly differentiated during the formation of the studied sediments. The d13C values for bioclasts vary in a broader range than for calcitic cements. Usually the snail shell carbonate is more enriched with heavier carbon isotope than that from ostracod valves, resulting from the isotopic equilibrium with precipitation and with surface waters, respectively. Basing on our study we can conclude that fluctuations of isotope composition of authigenic carbonates make it hard to apply as a paleoclimatic indicator. However, the general trend of d18O variation in analysed carbonate fractions from leoss-palaeosol sequences displays some connections with climatic fluctuations.

The Marhegda Bed is a carbonate-dominated Uthostratigraphic unit occurring locally at base of the Middle-Late Jurassic organic-rich sequence of the Agardhfjellet Formation in Spitsbergen, Svalbard. It has been interpreted to represent oolitic limestone facies deposited during an initial stage of Late Jurassic transgression. Petrographic, major element geochemical, and stable carbon and oxygen isotopic data presented in this paper indicate that this litho-stratigraphic unit is not a depositional limestone, but a diagenetic cementstone band originated in organic-rich sediment containing glauconite pellets and phosphatic ooids and grains. Two ep­isodes of carbonate diagenesis, including early precipitation of siderite and burial precipitation of ankerite, have contributed to the development of this cementstone. Extensive siderite precipi­tation occurred at sedimentary temperatures in nearsurface suboxic environment in which microbial reduction of ferric iron was the dominant diagenetic process. Precipitation of ankerite occurred at temperatures of about 80-100°C in burial diagenetic environment overwhelmed by thermal decarboxylation processes. Formation of ankerite was associated with advanced alteration of glauconite, dissolution of apatite and precipitation of kaolinite.