The paper presents results of investigation of microstructure and micro-hardness for material of ZnO varistors applied to 110 kV surge arrester and surge arrester counter. The research combined two pairs of varistors, each consisted of one varistor subjected before to operation, while the other one was brand new unit and constituted a reference. All varistors were made of the same material by the reputable manufacture. The tests revealed a different degree of the material degradation for varistors subjected before to operation. This also refers to different degradation mechanism observed for the material of these varistors, if typical effects of degradation of aged ZnO varistors were considered as a reference. Physical state of spinel in the microstructure had a significant impact on the material degradation, however a considerable loosening of the microstructure associated with bismuth oxide was observed too. It was surprising, since the precipitates of the bismuth oxide phase most often showed very good binding to the ZnO matrix and high resistance to associated electrical, thermal and mechanical effects. The degradation effects in the ZnO matrix proved to be limited only.

This paper presents the results of testing samples of shield-centering elements from medium-voltage surge arresters. The elements were made of TSE glass textolite. The elements have been dismantled from different operated surge arresters, which were subjected to discharge currents (short-circuit currents) of different intensity and duration. The discharge currents led to degradation of the tested elements with various degrees of advancement. The degradation was investigated using microscopic methods and energy-dispersive X-ray spectroscopy (EDS). Changes in the content of elements of the surface of textolite materials – as the degradation progresses – were documented.
It was found that high discharge current flows resulted in melting of the organic binder, epoxy resin, especially its surface layer. Partial charring and even burning of the resin was noticeable. Furthermore, it was found that with increasing degradation on the surface of the TSE laminate, the carbon and oxygen content, which are part of the organic resin, decreases. Simultaneously the amount of silicon, calcium and aluminium, which are present in the glass fibres, increases. The charring effect of the resin and the formation of conductive paths result in a decrease in the performance of surge arresters and their subsequent failure.