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Abstract

The article discusses issues related to the melting of grey and ductile cast iron in terms of metallurgical quality. The derivative and thermal analysis (DTA) was used to assess this quality. The article presents the results of research carried out in industrial conditions and analysed by the Itaca system. In the paper, the effect of the furnace type, the charge materials and the inoculation process on the parameters characterising the cast iron being melted was analysed. The most important of these are the minimum eutectic temperature (Te min), the liquidus temperature (T liquidus) and the nucleation rate. The results of the research and calculations are shown in graphs and as dependencies. Some of DTA results were compared to the microstructure analysis results. The article shows that the derivative and thermal analysis is a very effective tool in the assessment of the metallurgical quality of cast iron. It is a very good addition to chemical analysis. Based on the results of the research, it was concluded that a very high correlation exists between the rate of nucleation (DTA) and the number of graphite nuclei (microstructure analysis). Furthermore, it was also found that an improvement in nucleation could be achieved by ensuring a high value of carbon equivalent (CE) and, above all, by conducting the primary and secondary inoculation processes, respectively.
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Bibliography

[1] Stefanescu, D.M., Suarez, R. & Kim S.B, (2020). 90 years of thermal analysis as a control tool in the melting of cast iron. China Foundry. 17(2), 69-84. https://doi.org/10.1007/s41230-020-0039-x.
[2] Jura, S., Sakwa, J. & Borek, K. (1980). Application of thermal and differential analysis for determination of chemical composition parameters. Krzepnięcie Metali i Stopów. 3, 16-24. (in Polish).
[3] Jura, S., Sakwa, J. & Borek, K. (1980). Differential analysis of solidification and crystallization processes of gray cast iron. Krzepnięcie Metali i Stopów. 3, 25-35. (in Polish).
[4] Jura, Z. & Jura, S. (1990). Calorimetric curve and heat source in thermal and derivational analysis of cast iron solidification process. Krzepnięcie Metali i Stopów. 16, 126-139. (in Polish).
[5] Jura, Z. & Jura, S. (1996). The theory of the TDA method in the study of Al alloys. Krzepnięcie Metali i Stopów. 28, 57-88. (in Polish).
[6] Jura, S., Studnicki, A., Przybył, M. & Jura, Z. (2001). Application of the ATD method to assess the quality of ductile cast iron. Archiwum Odlewnictwa. 1(1), 93-102. (in Polish).
[7] Gawroński, J., Szajnar, J., Jura, Z. & Studnicki, A. (2004). Professor Stanisław Jura, creator of the theory and industrial applications of diagnostics and wear of metals and alloys. Archiwum Odlewnictwa. 4(SI 16), 1-74. (in Polish).
[8] Pietrowski, S. & Władysiak, R. (1996). TDA Inspection of piston silumins. Krzepnięcie Metali i Stopów. 28, 160-173. (in Polish).
[9] Pietrowski, S. & Gumienny, G. (2002). Methodology for preparing the quality assessment of ductile cast iron using the TDA method. Archiwum Odlewnictwa. 2(6). (in Polish).
[10] Pietrowski, S. & Gumienny, G. (2002). Evaluation of the quality of ductile cast iron EN-GJS-400-15 by the TDA method. Archiwum Odlewnictwa. 2(6), 257-268. (in Polish).
[11] Chisamera, M., Riposan, I., Stan, S., Stefan, E. & Costache, G. (2009). Thermal analysis control of in-mould and ladle inoculated grey cast irons. China Foundry. 6(2), 145-151.
[12] Erturka, S.O., Kumruoglub, L.C., Ozel, A. (2017). Determination of feederless casting limits by thermal analysis in cast iron. Acta Physica Polonica A. 131(3), 370-373. DOI: 10.12693/APhysPolA.131.370.
[13] Seidu, S.O. (2013). Thermal analysis of preconditioned ductile cast iron. International Journal of Current Engineering and Technology. 3(3), 813-818. ISSN 2277-4106.
[14] Cojocaru, A.M., Riposan, I. & Stan, S. (2019). Solidification influence in the control of inoculation effects in ductile cast irons by thermal analysis. Journal of Thermal Analysis and Calorimetry.138, 2131-2143. https://doi.org/10.1007/s10973-019-08808-2.
[15] Petrus, Ł., Bulanowski, A., Kołakowski, J., Brzeżański, M., Urbanowicz, M., Sobieraj, J., Matuszkiewicz, G., Szwalbe, L., Janerka, K. (2020). The influence of selected melting parameters on the physical and chemical properties of cast iron. Archives of Foundry Engineering. 20(1), 105-110. DOI: 10.24425/afe.2020.131290.
[16] Petrus, Ł., Bulanowski, A., Kołakowski, J., Sobieraj, J., Paruch, T., Urbanowicz, M., Brzeżański, M., Burdzy, D. & Janerka. K. (2021). Importance of TDA thermal analysis in an automated metallurgical process. Journal of Casting & Materials Engineering. 5(4), 89-93. https://doi.org/10.7494/ jcme.2021.5.4.89.
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Authors and Affiliations

J. Kołakowski
1
ORCID: ORCID
M. Brzeżański
1
ORCID: ORCID
D. Burdzy
1
ORCID: ORCID
J. Sobieraj
1
M. Urbanowicz
1
T. Paruch
1
K. Janerka
2
ORCID: ORCID

  1. “Śrem” Iron Foundry Sp. z o.o., ul. Staszica 1, 63-100 Śrem, Poland
  2. Department of Foundry Engineering, Silesian University of Technology, ul. Towarowa 7, 44-100 Gliwice, Poland
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Abstract

This paper presents the problems related to smelting gray and ductile cast iron. Special attention is paid to the metallurgical quality of cast iron. It depends on the type of furnace, charge materials and the special combination of charge, overheating and holding temperature, melting time, modification and spheroidization method. The evaluation of metallurgical quality has been performed by using derivativethermal analysis (DTA). During the smelting process and secondary metallurgy, the ITACA system was used allowing to obtain information on alloy characteristic temperatures (Tliquidus, TeMin, TeMax, Tsolidus), VPS value, recalescence value, IGQ coefficient, nucleation gauge, porosity etc. The results of investigations and calculations are displayed in the form of graphs and dependencies. It has been shown that the derivative-thermal analysis (DTA) is an effective complement of chemical analysis and it has been found that both the increase in temperature and metal holding time have a negative impact on the metallurgical quality of liquid metal. The metallurgical quality can be improved by using proper composition of charge materials and modifiers.

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Authors and Affiliations

Ł. Petrus
A. Bulanowski
J. Kołakowski
ORCID: ORCID
M. Brzeżański
ORCID: ORCID
M. Urbanowicz
J. Sobieraj
G. Matuszkiewicz
L. Szwalbe
K. Janerka
ORCID: ORCID
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Abstract

The paper presents the test results of molding compounds, sand casting molds and their analysis. The subject of testing was compound containing furan resins prepared according to the following recipe: matrix – regenerate 90% + fresh sand – 10%, furan resin – 1.10% by weight, hardener – 0.40% by weight. The impact of adhesive type and its quantity (Quan = 0.90, 1.1 and 1.5%) on the strength indexes of molding compound subject to densification was analyzed. The publication presents the test results: tensile strength Rm, compressive strength Rc and flexural strength Rg, as well as compound permeability as function of its density. The analysis also covers the impact of density level on mold strength and the distribution of density level along the mold height.

Based on the test results, it was found that the best method to obtain high strength molds made from compounds with chemical adhesives was to densify it by vibrating the system: match plate – molding flask – compound filling the mold. The effectiveness of this densification method depends on the amplitude and frequency of vibrations.

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Authors and Affiliations

Ł. Petrus
A. Bulanowski
J. Kołakowski
ORCID: ORCID
M. Urbanowicz
J. Sobieraj
M. Jelonek
M. Brzeżański
ORCID: ORCID
J.S. Zych
K. Janerka
ORCID: ORCID

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