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Abstract

Grain refining and modification are common foundry practice for improving properties of cast Al-Si alloys. In general, these types of treatments provide better fluidity, decreased porosity, higher yield strength and ductility. However, in practice, there are still some discrepancies on the reproducibility of the results from grain refining and effect of the refiner’s additions. Several factors include the fading effect of grain refinement and modifiers, inhomogeneous dendritic structure and non-uniform eutectic modification. In this study, standard ALCAN test was used by considering Taguchi’s experimental design techniques to evaluate grain refinement and modification efficiency. The effects of five casting parameters on the grain size have been investigated for A357 casting alloy. The results showed that the addition of the grain refiner was the most effective factor on the grain size. It was found that holding time, casting temperature, alloy type and modification with Sr were less effective over grain refinement.

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Authors and Affiliations

M. Çolak
D. Dışpınar
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Abstract

In this work, T-shaped mould design was used to generate hot spot and the effect of Sr and B on the hot tearing susceptibility of A356 was investigated. The die temperature was kept at 250o C and the pouring was carried out at 740o C. The amonut of Sr and B additions were 30 and 10 ppm, respectively. One of the most important defects that may exist in cast aluminium is the presence of bifilms. Bifilms can form by the surface turbulence of liquid metal. During such an action, two unbonded surfaces of oxides fold over each other which act as a crack. Therefore, this defect cause many problems in the cast part. In this work, it was found that bifilms have significant effect over the hot tearing of A356 alloy. When the alloy solidifies directionally, the structure consists of elongated dendritic structure. In the absence of equiaxed dendrites, the growing tips of the dendrites pushed the bifilms to open up and unravel. Thus, leading to enlarged surface of oxide to become more harmful. In this case, it was found that these bifilms initiate hot tearing.

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Authors and Affiliations

M. Uludağ
R. Çetin
D. Dışpınar
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Abstract

In the present study, the corrosion behaviour of A356 (Al-7Si-0.3Mg) alloy in 3.5% NaCl solution has been evaluated using

cyclic/potentiodynamic polarization tests. The alloy was provided in the unmodified form and it was then modified with AlTi5B1 for grain

refinement and with AlSr15 for Si modifications. These modifications yield to better mechanical properties. Tensile tests were performed.

In addition, bifilm index and SDAS values were calculated and microstructure of the samples was investigated. As a result of the corrosion

test, the Ecorr values for all conditions were determined approximately equal, and the samples were pitted rapidly. The degassing of the

melt decreased the bifilm index (i.e. higher melt quality) and thereby the corrosion resistance was increased. The lowest corrosion rate was

founded at degassing and as-received condition (3.9x10-3 mm/year). However, additive elements do not show the effect which degassing

process shows.

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Authors and Affiliations

M. Uludağ
M. Kocabaş
D. Dışpınar
R. Çetin
N. Cansever
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Abstract

The formation of oxide film on the surface of aluminium melts, i.e. bifilms, are known to be detrimental when they are incorporated into

the cast part. These defects causes premature fractures under stress, or aid porosity formation. In this work, Al-12 Si alloy was used to cast

a step mould under two conditions: as-received and degassed. In addition, 10 ppi filters were used in the mould in order to prevent bifilm

intrusion into the cast part. Reduced pressure test samples were collected for bifilm index measurements. Samples were machined into

standard bars for tensile testing. It was found that there was a good agreement with the bifilm index and mechanical properties.

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Authors and Affiliations

F. Yilmaz
M. Uludağ
M. Uyaner
D. Dişpinar
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Abstract

Light weight, low density with high mechanical properties and corrosion resistance, aluminum is the most important material and is commonly used for high performance applications such as aerospace, military and especially automotive industries. The researchers who participate in these industries are working hard to further decrease the weight of end products according to legal boundaries of greenhouse gases. A lot of research was undertaken to produce thin sectioned aluminum parts with improved mechanical properties. Several alloying element addition were investigated. Yet, nowadays aluminum has not met these expectations. Thus, composite materials, particularly metal matrix composites, have taken aluminum’s place due to the enhancement of mechanical properties of aluminum alloys by reinforcements. This paper deals with the overview of the reinforcements such as SiC, Al2O3 and graphene. Graphene has recently attracted many researcher due to its superior elastic modulus, high fatigue strength and low density. It is foreseen and predicted that graphene will replace and outperform carbon nanotubes (CNT) in near future.
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Authors and Affiliations

U. Aybarc
D. Dispinar
M.O. Seydibeyoglu
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Abstract

Recyclability is one of the great features of aluminium and its alloys. However, it has been typically considered that the secondary aluminium quality is low and bad. This is only because aluminium is so sensitive to turbulence. Uncontrolled transfer and handling of the liquid aluminium results in formation of double oxide defects known as bifilms. Bifilms are detrimental defects. They form porosity and deteriorate the properties. The detection and quantification of bifilms in liquid aluminium can be carried out by bifilm index measured in millimetres as an indication of melt cleanliness using Reduced Pressure Test (RPT). In this work, recycling efficiency and quality change of A356 alloy with various Ti additions have been investigated. The charge was recycled three times and change in bifilm index and bifilm number was evaluated. It was found that when high amount of Ti grain refiner was added, the melt quality was increased due to sedimentation of bifilms with Ti. When low amount of Ti is added, the melt quality was degraded.

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Authors and Affiliations

O. Gursoy
E. Erzi
K. Tur
D. Dispinar
ORCID: ORCID
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Abstract

The microstructure of Al-Si alloy has coarse silicon and this structure is known dangerous for mechanical properties due to its crack effect. Sr addition is preferred to modify the coarse silica during solidification. Additionally, bifilms (oxide structure) are known as a more dangerous defect which is frequently seen in light alloys. It is aimed at that negative effect of bifilms on the properties of the alloys tried to be removed by the degassing process and to regulate the microstructure of the alloy. In this study, the effect of degassing and Sr modification on the mechanical properties of AlSi12Fe alloy was investigated, extensively. Four different parameters (as-received, as-received + degassing, Sr addition, Sr addition + degassing) were studied under the same conditions environmentally. The microstructural analyses and mechanical tests were done on cast parts. All data obtained from the experimental study were analyzed statistically by using statistical analysis software. It was concluded from the results that Sr addition is very dangerous for AlSi12Fe alloy. It can be suggested that to reach high mechanical properties and low casting defects, the degassing process must be applied to all castings whereas Sr addition should not be preferred.

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Authors and Affiliations

M. Uludağ
M. Gurtaran
D. Dispinar
ORCID: ORCID
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Abstract

Aluminium alloys are one of the preferred materials especially for land and air transportation because of their high strength and lowdensity properties. Although production using casting method is economical yet it has some disadvantages. Shrinkage which is occurred due to the density difference between the solid and liquid metal is prevented by feeders which need to be calculated. Liquid metal should be transferred to the mould without any turbulence. As a result, sprues are needed to be designed precisely. On the other hand, aluminium alloys can also be shaped by forging at semi-solid temperatures. There are some advantages compared to the traditional forging methods of improving die life due to the lower tonnage values. In this study, semi-solid produced 7075 aluminium alloy die filling capabilities were investigated. To achieve semisolid structure strain induced melt activated method (SIMA) was used. The desired structure was achieved at 635 °C and 30 minutes of duration of heat treatment. After determining the optimum parameters, metallographic analysis, density calculations, porosity distribution and tensile tests were carried out. It was found that the reproducibility of SIMA produced 7075 alloy was quite low. A proper tensile test result was achieved only 7 of the total 15 tests and the mean value was 386 MPa. The main reason for this scattered in mechanical properties could be the chemical composition of the alloy and the rapid solidification of the liquid eutectic phases. It is important to define the best fitting process parameters and controlling them precisely will be the most important factors for future studies.
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Authors and Affiliations

E. Erzi
O. Gursoy
Ç.O.K. Yüksel
S. Kirtay
D. Dispinar
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Abstract

A356 is one of the widely used aluminium casting alloy that has been used in both sand and die casting processes. Large amounts of scrap

metal can be generated from the runner systems and feeders. In addition, chips are generated in the machined parts. The surface area with

regard to weight of chips is so high that it makes these scraps difficult to melt. Although there are several techniques evolved to remedy

this problem, yet the problem lies in the quality of the recycled raw material. Since recycling of these scrap is quite important due to the

advantages like energy saving and cost reduction in the final product, in this work, the recycling efficiency and casting quality were

investigated. Three types of charges were prepared for casting: %100 primary ingot, %100 scrap aluminium and fifty-fifty scrap

aluminium and primary ingot mixture were used. Melt quality was determined by calculating bifilm index by using reduced pressure test.

Tensile test samples were produced by casting both from sand and die moulds. Relationship between bifilm index and tensile strength were

determined as an indication of correlation of melt quality. It was found that untreated chips decrease the casting quality significantly.

Therefore, prior to charging the chips into the furnace for melting, a series of cleaning processes has to be used in order to achieve good

quality products.

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Authors and Affiliations

C. Yuksel
O. Tamer
E. Erzi
U. Aybarc
E. Cubuklusu
O. Topcuoglu
M. Cigdem
D. Dispinar
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Abstract

Porosity is one of the major problems in casting operations and there are several discussions in the literature about the porosity formation in aluminum castings. Bifilms are the defects that are introduced into the melt by turbulence. They can be detected with reduced pressure test and presented numerically by measuring bifilm index. The measure of bifilm index is the sum of total oxide length given in millimeters from the cross-section of reduced pressure test sample solidified under 0.01 MPa. In this work, low pressure die casting (LPDC) unit was built in an attempt to enhance the producibility rate. The unit consists of a pump housing that was placed inside the melt in the melting furnace where the pressure was applied instead of the whole melt surface. It was observed that the melt quality of A356 alloy was deteriorated over time which had led to higher porosity. This was attributed to the increased oxide thickness of the bifilm by the consumption of air in between the folded oxides. A relationship was found between bifilm index and pore formation.
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Bibliography

[1] Campbell, J. (2011). Complete Casting Handbook: Metal Casting Processes. Techniques and Design. Elsevier Science.
[2] Bonollo, F., Urban, J., Bonatto, B. & Botter, M. (2005). Gravity and low pressure die casting of aluminium alloys: a technical and economical benchmark. La Metallurgia Italiana. 6, 23-32.
[3] Dispinar, D. & J. Campbell, (2004). Critical assessment of reduced pressure test. Part 2: Quantification. International Journal of Cast Metals Research. 17(5), 287-294.
[4] Raiszadeh, R., & Griffiths, W.D. (2006). A method to study the history of a double oxide film defect in liquid aluminum alloys. Metallurgical and Materials Transactions B. 37(6), 865-871.
[5] Raiszadeh, R., & Griffiths, W.D. (2008). A semi-empirical mathematical model to estimate the duration of the atmosphere within a double oxide film defect in pure aluminum alloy. Metallurgical and Materials Transactions B. 39(2), 298-303.
[6] Raiszadeh, R., & Griffiths, W.D. (2011). The effect of holding liquid aluminum alloys on oxide film content. Metallurgical and Materials Transactions B. 42(1), 133-143.
[7] Aryafar, M., Raiszadeh, R., & Shalbafzadeh, A. (2010). Healing of double oxide film defects in A356 aluminium melt. Journal of materials science. 45(11), 3041-3051.
[8] Farhoodi, B., Raiszadeh, R., & Ghanaatian, M. H. (2014). Role of double oxide film defects in the formation of gas porosity in commercial purity and Sr-containing Al alloys. Journal of Materials Science & Technology. 30(2), 154-162.
[9] Amirinejhad, S., Raiszadeh, R., & Doostmohammadi, H. (2013). Study of double oxide film defect behaviour in liquid Al–Mg alloys. International Journal of Cast Metals Research. 26(6), 330-338.
[10] Bakhtiarani, F.N., & Raiszadeh, R. (2011). Healing of double-oxide film defects in commercial purity aluminum melt. Metallurgical and Materials Transactions B. 42(2), 331-340.
[11] Bagherpour-Torghabeh, H., Raiszadeh, R., & Doostmohammadi, H. (2017). Role of Mechanical Stirring of Al-Mg Melt in the Healing of Bifilm Defect. Metallurgical and Materials Transactions B. 48(6), 3174-3184.
[12] Nateghian, M., Raiszadeh, R., & Doostmohammadi, H. (2012). Behavior of Double-Oxide Film Defects in Al-0.05 wt pct Sr Alloy. Metallurgical and Materials Transactions B. 43(6), 1540-1549.
[13] Stefanescu, D.M. (2005). Computer simulation of shrinkage related defects in metal castings - a review. International Journal of Cast Metals Research. 18, 129-143.
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[22] Dispinar, D., Akhtar, S., Nordmark, A., Di Sabatino, M., & Arnberg, L. (2010). Degassing, hydrogen and porosity phenomena in A356. Materials Science and Engineering: A. 527(16-17), 3719-3725.
[23] Puga, H., Barbosa, J., Azevedo, T., Ribeiro, S. & Alves, J.L. (2016). Low pressure sand casting of ultrasonically degassed AlSi7Mg0. 3 alloy: Modelling and experimental validation of mould filling. Materials & Design. 94, 384-391.
[24] El-Sayed, M.A. & Essa, K. (2018). Effect of mould type and solidification time on bifilm defects and mechanical properties of Al–7si–0.3 mg alloy castings. Computational and Experimental Studies, 23.
[25] Gyarmati, G., Fegyverneki, G., Mende, T. & Tokár, M. (2019). Characterization of the double oxide film content of liquid aluminum alloys by computed tomography. Materials Characterization. 157, 109925. [26] Gyarmati, G., Fegyverneki, G., Tokár, M., & Mende, T. (2020). The Effects of Rotary Degassing Treatments on the Melt Quality of an Al–Si Casting Alloy. International Journal of Metalcasting. 1-11.
[27] Tiryakioğlu, M. (2020). The Effect of Hydrogen on Pore Formation in Aluminum Alloy Castings: Myth Versus Reality. Metals. 10(3), 368.
[28] Tiryakioğlu, M. (2019). Solubility of hydrogen in liquid aluminium: reanalysis of available data. International Journal of Cast Metals Research. 32(5-6), 315-318.
[29] Tiryakioğlu, M. (2020). A simple model to estimate hydrogen solubility in liquid aluminium alloys. International Journal of Cast Metals Research. 1-3.
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Authors and Affiliations

O. Gursoy
1
A. Nordmak
2
F. Syvertsen
2
M. Colak
3
K. Tur
4
D. Dispinar
5
ORCID: ORCID

  1. University of Padova, Italy
  2. SINTEF, Norway
  3. University of Bayburt, Turkey
  4. Atilim University, Turkey
  5. Istanbul Technical University, Turkey
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Abstract

In this work, 25 wheels were cast with three different grain refiners: Al5Ti1B, Al3Nb1B and MTS 1582. Samples were machined from the wheels to check the mechanical properties. It was found that Nb grain refinement had the lowest grain size (260 mm) and highest tensile properties (yield strength of 119-124 MPa and ultimate tensile strength of 190-209 MPa). Al5Ti1B and MTS 1582 revealed quite similar results (110 MPa yield and 198 MPa ultimate tensile strength). The fading of the grain refining effect of Al5TiB1 master alloy was observed in both Nb and Ti added castings whereas during the investigated time interval, the fading was not observed when MTS 1582 was used.
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Authors and Affiliations

F. Aydogan
1
K.C. Dizdar
2
ORCID: ORCID
H. Sahin
2
ORCID: ORCID
E. Mentese
1
D. Dispinar
2
ORCID: ORCID

  1. Doktas Wheels, Turkey
  2. Istanbul Technical University, Turkey
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Abstract

Production of the defect-free casting of aluminium alloys is the biggest challenge. Porosity is known to be the most important defect. Therefore, many cast parts are subjected to several non-destructive tests in order to check their acceptability. There are several standards, yet, the acceptance limit of porosity size and distribution may change according to the customer design and requirements. In this work, the aim was targeted to evaluate the effect of size, location, and distribution of pores on the tensile properties of cast A356 alloy. ANSYS software was used to perform stress analysis where the pore sizes were changed between 0.05 mm to 3 mm by 0.05 mm increments. Additionally, pore number was changed from 1 to 5 where they were placed at different locations in the test bar. Finally, bifilms were placed inside the pore at different sizes and orientations. The stress generated along the pores was recorded and compared with the fracture stress of the A356 alloy. It was found that as the bifilm size was getting smaller, their effect on tensile properties was lowered. On the other hand, as bifilms were larger, their orientation became the dominant factor in determining the fracture.
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Bibliography

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[31] Uludağ, M., Çetin, R., Dispinar, D. & Tiryakioğlu, M. (2017). Characterization of the Effect of Melt Treatments on Melt Quality in Al-7wt %Si-Mg Alloys. Metals. 7(5), 157. DOI: 10.3390/met7050157.
[32] Uludağ, M., Çetin, R., Dişpinar, D. & Tiryakioğlu, M. (2018). On the interpretation of melt quality assessment of A356 aluminum alloy by the reduced pressure test: the bifilm index and its physical meaning. International Journal of Metalcasting. 12, 853–860. DOI: 10.1007/s40962-018-0217-4.
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Authors and Affiliations

H. Sahin
1
ORCID: ORCID
M. Atik
1
F. Tezer
1
S. Temel
1
O. Aydin
1
O. Kesen
1
O. Gursoy
2
D. Dispinar
3
ORCID: ORCID

  1. Istanbul Technical University, Turkey
  2. University of Padova, Italy
  3. Foseco, Netherlands
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Abstract

The solubility of Fe in aluminium alloys is known to be a problem in the casting of aluminium alloys. Due to the formation of various intermetallic phases, the mechanical properties decrease. Therefore, it is important to determine the formation mechanisms of such intermetallic. In this work, A360 alloy was used, and Fe additions were made. The alloy was cast into the sand and die moulds that consisted of three different thicknesses. In this way, the effect of the cooling rate was investigated. The holding time was selected to be 5 hours and every hour, a sample was collected from the melt for microstructural analysis. Additionally, the melt quality change was also examined by means of using a reduced pressure test where the bifilm index was measured. It was found that the iron content was increased after 2 hours of holding and the melt quality was decreased. There was a correlation between the duration and bifilm index. The size of Al-Si-Mn-Fe phases was increased in parallel with the bifilm content regardless of the iron content.
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Authors and Affiliations

E.N. Bas
1
S. Alper
1
T. Tuncay
2
ORCID: ORCID
D. Dispinar
3
ORCID: ORCID
S. Kirtay
1
ORCID: ORCID

  1. Istanbul University-Cerrahpasa, Turkey
  2. Karabuk University, Turkey
  3. Foseco, Netherlands
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Abstract

Aluminum alloys are widely used in the industry thanks to its many advantages such as light weight and high strength. The use of this material in the market is increasing day by day with the developing technology. Due to the high energy inputs in the primary production, the use of secondary ingots by recycling from scrap material are more advantageous. However, the liquid metal quality is quite important in the use of secondary aluminum. It is believed that the quality of recycled aluminum is low, for this purpose, many liquid metal cleaning methods and test methods are used in the industry to assess the melt cleanliness level. In this study, it is aimed to examine the liquid metal quality in castings with varying temperature using K mold. A206 alloy was used, and the test parameters were selected as: (i) at 725 °C, 750 °C and 775 °C casting temperatures, (ii) different hydrogen levels. The hydrogen level was adjusted as low, medium and high with degassing, as-cast, and upgassing of the melt, respectively. The liquid metal quality of the cast samples was examined by the K mold technique. When the results were examined, it was determined that metal K values and the number of inclusions were high at the as-cast and up-gas liquid with increasing casting temperatures. It has been understood that the K mold technique is a practical method for the determination of liquid metal quality, if there is no reduced pressure test machine available at the foundry floor.
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Authors and Affiliations

A. Tigli
1 2
ORCID: ORCID
M. Tokatli
3
E. Uslu
3
ORCID: ORCID
M. Colak
3
D. Dispinar
1 4
ORCID: ORCID

  1. Istanbul Technical University, Turkey
  2. Sinop University, Turkey
  3. Bayburt University, Turkey
  4. Foseco, Netherlands
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Abstract

Casting is the most economical way of producing parts for many industries ranging from automotive, aerospace to construction towards small appliances in many shares. One of the challenges is the achievement of defect-free cast parts. There are many ways to do this which starts with calculation and design of proper runner system with correct size and number of feeders. The first rule suggests starting with clean melt. Yet, rejected parts can still be found. Although depending on the requirement from the parts, some defects can be tolerated, but in critical applications, it is crucial that no defect should exist that would deteriorate the performance of the part. Several methods exist on the foundry floor to detect these defects. Functional safety criteria, for example, are a must for today's automotive industry. These are not compromised under any circumstances. In this study, based on the D-FMEA (Design Failure Mode and Effect Analysis) study of a functional safety criterion against fuel leakage, one 1.4308 cast steel function block, which brazed-on fuel rail port in fuel injection unit, was investigated. Porosity, buckling, inclusion and detection for leak were carried out by non-destructive test (NDT) methods. It was found that the best practice was the CT-Scan (Computed Tomography) for such applications.
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Bibliography

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Authors and Affiliations

K.C. Dizdar
1
ORCID: ORCID
H. Sahin
1
ORCID: ORCID
M. Ardicli
2
D. Dispinar
3
ORCID: ORCID

  1. Istanbul Technical University, Turkey
  2. Bosch Powertrain Solutions, Bursa, Turkey
  3. Foseco Non-Ferrous Metal Treatment, Netherlands
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Abstract

Aluminum and its alloys are one of the most favored metal-based materials for engineering applications that require lightweight materials. On the other hand, composites are getting more preferable for different kinds of applications recently. Boron nitride nanotubes (BNNTs) are one of the excellent reinforcement materials for aluminum and its alloys. To enhance mechanical properties of aluminum, BNNTs can be added with different processes. BNNT reinforced aluminum matrix composites also demonstrate extraordinary radiation shielding properties. This study consists of BNNT reinforced aluminum matrix composite production performed by casting method. Since wetting of BNNT in liquid aluminum is an obstacle for casting, various casting techniques were performed to distribute homogeneously in liquid aluminum. Different methods were investigated in an aim to incorporate BNNT into liquid method as reinforcement. It was found that UTS was increased by 20% and elongation at fracture was increased by 170% when BNNT was preheated at 800°C for 30 minutes.
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Authors and Affiliations

B. Nemutlu
1
ORCID: ORCID
O. Kahraman
1
ORCID: ORCID
K. B. Demirel
1
ORCID: ORCID
I. Erkul
1
ORCID: ORCID
M. Cicek
1
ORCID: ORCID
H. Sahin
1
ORCID: ORCID
K.C. Dizdar
1
ORCID: ORCID
D. Dispinar
1
ORCID: ORCID

  1. Istanbul Technical University, Turkey

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