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Abstract

Sodium silicate is one of the most successful inorganic binder. Along with the broad application of sodium silicate for domestic and industrial purposes, the composition analysis, include modulus (m), ratio of SiO2:Na2O, Na2O%, SiO2%, and solid-containing content, is important for the products strength and service life. However, it is perplexing to operate, inefficient and low precision for traditional standard testing method of these parameters. In this study, an automatic measurement system of sodium silicate composition analysis, with the potential electrode for potentiometer titration, micro-controller, PCB, heater, stirrer, printer and micro peristaltic pump, was developed according to the determine method principle. The end-points of pH value in the two titrating steps, first was 4.3 and second was 6.0, were set in the micro-controller to control the reaction in the processing of the sodium silicate composition analysis. And all the potential signals of the pH electrode were transited in the special PCB for the micro-controller.
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Bibliography

[1] Rabbii, A. (2001). Sodium silicate glass as an inorganic binder in foundry industry. Iranian Polymer Journal. 10(4), 229-235.
[2] Stachowicz, M., Pałyga, Ł.& Kȩpowicz, D. (2020). Influence of automatic core shooting parameters in hot-box technology on the strength of sodium silicate olivine moulding sands. Archives of Foundry Engineering. 20(1), 67-72.
[3] Huafang, W., Wenbang, G. & Jijun, L. (2014). Improve the humidity resistance of sodium silicate sands by estermicrowave composite hardening. Metalurgija. 53(4), 455-458.
[4] Nowak, D. (2017). The impact of microwave penetration depth on the process of heating the moulding sand with sodium silicate. Archives of Foundry Engineering. 17(4), 115-118.
[5] M. Stachowicz, K. Granat, & D. Nowak. (2011). Application of microwaves for innovative hardening of environment-friendly water-glass moulding sands used in manufacture of cast-steel castings. Archives of Civil and Mechanical Engineering. XI(1), 209-219.
[6] Zhu, CX. (2007). Recent advances in waterglass sand technologies. China Foundry. 4(1), 13-17.
[7] Masuda Yuki, Tsubota Keiji, Ishii Kenichi, Imakoma Hironobu, Ohmura Naoto. (2009) Drying rate and surface temperature in solidification of glass particle layer with inorganic binder by microwave drying. Kagaku Kogaku Ronbunshu. 35(2). 229-231.
[8] Standardization Administration of the P.R.C. (2008). GB/T4209-2008, Sodium silicate for industry use[S]. Beijing, China Standard Press.
[9] Bourikas K., Kordulis C. & Lycourghiotis A. (2005). Differential potentiometric titration: Development of a methodology for determining the point of zero charge of metal (Hydr)oxides by one titration curve. Environmental Science & Technology. 39(11), 4100-4108.
[10] Fan ZT, Liu M, Wang HF, Long W, Hu XT. (2010). Chinese Patent No. 201010558029.3. Beijing, China National Intellectual Property Administration.
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Authors and Affiliations

Huafang Wang
1
ORCID: ORCID
Quanrun Wang
1
Wu Zhang
1
Xiang Gao
1
Jijun Lu
1
ORCID: ORCID

  1. School of Mechanical Engineering and Automation, Wuhan Textile University, Wuhan 430073, China
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Abstract

The sodium silicate sands hardened by microwave have the advantages of high strength, fast hardening speed and low residual strength with the lower addition of sodium silicate. However, the sodium ion in the sands will absorb moisture from the atmosphere, which would lead to lower storing strength, so the protection of a bonding bridge of sodium silicate between the sands is crucial. Methyl silicone oil is a cheap hydrophobic industrial raw material. The influence of the addition amount of methyl silicone oil modifier on compressive strength and moisture absorption of sodium silicate sands was studied in this work. The microscopic analysis of modified before and after sodium silicate sands has been carried on employing scanning electron microscopy(SEM) and energy spectrum analysis(EDS). The results showed that the strength of modified sodium silicate sands was significantly higher than that of unmodified sodium silicate sands, and the best addition of methyl silicone oil in the quantity of sodium silicate was 15%. It was also found that the bonding bridge of modified sodium silicate sands was the density and the adhesive film was smooth, and the methyl silicone oil was completely covered on the surface of the sodium silicate bonding bridge to protect it.
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Bibliography

[1] Stachowicz, M., Pałyga, Ł. & Kȩpowicz, D. (2020). Influence of automatic core shooting parameters in hot-box technology on the strength of sodium silicate olivine moulding sands. Archives of Foundry Engineering. 20(1), 67-72.
[2] Nowak, D.(2017).The impact of microwave penetration depth on the process of hardening the moulding sand with sodium silicate. Archives of Foundry Engineering. 17(4), 115-118.
[3] Gal, B., Granat, K. & Nowak, D. (2017). Effect of compaction degree on permittivity of water-glass containing moulding sand. Metalurgija. 56(1), 17-20.
[4] Kaźnica, N. & Zych, J. (2019). Indicator wso: a new parameter for characterization of protective coating efficiency against humidity. Journal of Materials Engineering and Performance. 28(7), 3960-3965.
[5] Bae, M.A., Lee, M.S. & Baek, J.H. (2020). The effect of the surface energy of water glass on the fluidity of sand. Journal of Korean Institute of Metals and Materials. 58(5), 319-325.
[6] Peng, Q.S., Wang, P.C., Huang, W., & Chen, H.B. (2020). The irradiation-induced grafting of nano-silica with methyl silicone oil. Polymer. 192(4), 122315.
[7] Stachowicz, M., Granat, K., & Payga. (2017). Influence of sand base preparation on properties of chromite moulding sands with sodium silicate hardened with selected methods. Archives of Metallurgy and Materials. 62(1), 379-383.
[8] Zhu, C. (2007). Recent advances in waterglass sand technologies. China Foundry. 4(1), 13-17.
[9] Huafang, W., Wenbang, G. & Jijun, L. (2014). Improve the humidity resistance of sodium silicate sands by ester-microwave composite hardening. Metalurgija. 53(4), 455-458.
[10] Masuda, Y., Tsubota, K., Ishii, K., Imakoma, H. & Ohmura, N. (2009). Drying rate and surface temperature in solidification of glass particle layer with inorganic binder by microwave drying. KAGAKU KOGAKU RONBUNSHU. 35(2), 229-231.
[11] Kosuge, K., Sunaga, M., Goda, R., Onodera, H. & Okane, T. (2018). Cure and collapse mechanism of inorganic mold using spherical artificial sand and water glass binder. Materials transactions. 59(11), 1784-1790.
[12] Zhang, Y.H., Liu, Z.Y., Liu, Z.C. & Yao, L.P. (2020). Mechanical properties of high-ductility cementitious composites with methyl silicone oil. Magazine of Concrete Research. 72(14), 747-756.
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Authors and Affiliations

Huafang Wang
1
ORCID: ORCID
Xiang Gao
1
Lei Yang
1
ORCID: ORCID
Wei He
1
Jijun Lu
1
ORCID: ORCID

  1. School of Mechanical Engineering and Automation, Wuhan Textile University, China

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