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Abstract

The present study is aimed to access the growth rates, biomass productivity and nutrient removal in different concentrations of microalgae Botryococcus sp. beads using kitchen wastewater as a media. Verhulst logistic kinetic model was used to measure the optimal concentrations of microalgae Botryococcus sp. in kitchen wastewater in terms of cell growth rate kinetics and biomass productivity. The study verified that the maximum productivity was recorded with 1×106 cell/ml of the initial concentration of Botryococcus sp. with 42.64 mg/l/day and the highest removal of tp and ammonia was obtained (78.14% and 60.53% respectively). The highest specific growth rate of biomass at 0.2896 μmax/d compare to other concentrations, while the lowest occurred at concentrations of 105 cells/ml at 0.0412 μmax/d. The present study shows the different concentrations of Botryococcus sp. in alginate beads culturing in kitchen wastewater influence the cells growth of biomass and nutrient uptake with optimum concentration (106 cells/ml) of Botryococcus sp. which is suggested for wastewater treatment purposes. The result of scanning electron microscopy (sem) shows differences in morphology in terms of surface; smoother and cleaner (before the experiment), cracks and rough surface with black/white spots (after the experiment). These findings seemly can be applied efficiently in kitchen wastewater treatment as well as a production medium for microalgae biomass.
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Authors and Affiliations

N.A.R. Shaari
1
N.M. Apandi
1 2
ORCID: ORCID
N.M. Sunar
3
ORCID: ORCID
R. Nagarajah
1
K. Cheong
1
S.S.M. Ahia
1
Khairul Anwar Abdul Halim
4
ORCID: ORCID
M. Gacek
5
ORCID: ORCID
Wan Mastura Wan Ibrahim
4
ORCID: ORCID

  1. Universiti Tun Hussein Onn Malaysia Faculty Of Engineering Technology, Department of Civil Engineering Technology, Pagoh Education Hub, 84600, Pagoh, Muar, Johor, Malaysia
  2. Universiti Tun Hussein Onn Malaysia, Susta Inable Engineering Technology Research Centre (Setechrc), Faculty of Civil Engineering Technology, Pagoh Educat Ion Hub, 84600, Pagoh, Muar, Johor, Malaysia
  3. Universiti Tun Hussein Onn Malaysia, Research Centre for Soft Soil (Recess), Institute of Integrat Edengineering, 86400 Batu Pahat , Johor, Malaysia
  4. Universiti Malaysia Perlis (Unimap), Centre of Excellence Geopolymer & Green Technology (Cegeogtech), 01000 Perlis, Malaysia
  5. Czestochowa University of Technology, Faculty of Production Engineering And Materials Technology. Department of Physics, 19 Armii Krajowej Av., 42-200 Czestochowa , Poland
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Abstract

The use of organically modified clays as nano-reinforcement in polymer matrices is widely investigated owing to their remarkable reinforcement at low filler loading. In this body of work, the nanocomposites were prepared by melt blending nanoclay with polyamide 11 (PA 11) utilising a twin-screw extruder in order to maximise the dispersion of clay particles within the matrix during compounding. The main aim of the work was to study the reinforcing effect of nanoclay within PA 11 using two micromechanical model namely Halpin-Tsai and Mori-Tanaka composite theories. These theories were used to predict the effective tensile modulus of PA 11 nanocomposites and the results were compared to the experimental data. In addition, the Halpin-Tsai model was used to predict the storage modulus and heat distortion temperature (HDT) of PA 11 nanocomposites. It was found that the tensile modulus for nanocomposites with a high clay aspect ratio exhibits up to 10% higher when compared to the nanocomposites with lower clay aspect ratio. Thus, it is believed that the combination of clay aspect ratio and modulus contributes to the super reinforcing effect of nanoclay within the PA 11 matrix.
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Authors and Affiliations

Khairul Anwar Abdul Halim
1 2
ORCID: ORCID
James E. Kennedy
3
ORCID: ORCID
Mohd Arif Anuar Mohd Salleh
1 2
ORCID: ORCID
Azlin Fazlina Osman
1 2
ORCID: ORCID
Mohd Firdaus Omar
1 2
ORCID: ORCID
N.M. Sunar
4
ORCID: ORCID

  1. Universiti Malaysia Perlis, Centre of Excellence Geopolymer and Green Technology (CEGeoGTech), 01000 Perlis, Malaysia
  2. Universiti Malaysia Perlis, Faculty of Chemical Engineering and Technology, Kompleks Pusat Pengajian Jejawi 3, Kawasan Perindustrian Jejawi, 02600, Arau, Perlis, Malaysia
  3. Athlone Institute of Technology, Dublin Road, Co. Westmeath , Ireland
  4. Universiti Tun Hussein Onn Malaysia, Research Centre for Soft Soil (RECESS), Institute of Integrate d Engineering, 86400 Parit Raja, Johor, Malaysia

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