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Abstract

The article presents the results of permeability measurements of a zirconium alcohol coating applied on moulds and cores. The introduction extensively discusses the reasons for the application of protective coatings, as well as their advantages and disadvantages. Also, the problems related to the application of protective coatings are presented i.e. limited permeability and thus the possibility of the presence of gas-originated defects in the casts. Next, the paper discusses the methods of measuring the permeability of protective coating proposed by Falęcki and Pacyniak. The study also presents an indirect permeability measurement method. For the investigations, zirconium alcohol coatings with the three conventional viscosities 10, 20 and 30s were used. The viscosity was determined by means of the Ford cup with the clearance of 4mm. The coatings were applied onto profiles of Φ 50 x 50 mm, made of moulding sand consisting of a sand matrix with the mean grain size of dL = 0,11, 17, 24, 31 and 34 mm and phenol-formaldehyde resin. The effect of the matrix grain size on the permeability of the sand with and without a coating was determined.

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Authors and Affiliations

Ł. Jamrozowicz
ORCID: ORCID
A. Siatko
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Abstract

This article presents measurements of the thickness of alcohol-based coatings on sand foundry cores and moulds. These coatings were applied using two methods, the dipping method and the painting method. For the purposes of the study, a zircon alcohol-based coating was prepared with three different levels of nominal viscosity; very thin at 10s, average at 20s, and thick at 30s. The coating was applied to a core made of quartz sand and furan resin. The cores were made of sand with three different grain sizes; dL = 0.22 mm – fine sand, dL = 0.33 mm medium sand, and dL = 0.47 mm coarse sand. In the study, the thickness of the coating obtained to the core was measured immediately after application as well as after drying. Additionally, the extent of penetration into the intergranular spaces of the core matrix was measured. On the basis of this study, the impact of the grain size of the core matrix on the thickness of the coating and its penetration into the core was assessed. The thickness of coatings obtained using different application methods was also assessed.

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Authors and Affiliations

Ł. Jamrozowicz
J. Kolczyk-Tylka
A. Siatko
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Abstract

The results of investigations of the rheological properties of typical ceramic slurries used in the investment casting technology – the lost

wax technology are presented in the paper. Flow curves in the wide range of shear velocity were made. Moreover, viscosity of ceramic

slurries depending on shearing stresses was specified. Tests were performed under conditions of three different temperatures 25, 30 and

35oC, which are typical and important in the viewpoint of making ceramic slurries in the investment casting technology.

In the light of the performed investigations can be said that the belonging in group of Newtonian or Non – Newtonian fluid is dependent

on content of solid phase (addition of aluminum oxide) in the whole composition of liquid ceramic slurries.

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Authors and Affiliations

J. Kolczyk
Ł. Jamrozowicz
N. Kaźnica
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Abstract

The investigation results of the kinetics of binding ceramic moulds, in dependence on the solid phase content in the liquid ceramic slurries being 67, 68 and 69% - respectively, made on the basis of the aqueous binding agents Ludox AM and SK. The ultrasonic method was used for assessing the kinetics of strengthening of the multilayer ceramic mould. Due to this method, it is possible to determine the ceramic mould strength at individual stages of its production. Currently self-supporting moulds, which must have the relevant strength during pouring with liquid metal, are mainly produced. A few various factors influence this mould strength. One of them is the ceramic slurry viscosity, which influences a thickness of individual layers deposited on the wax model in the investment casting technology. Depositing of layers causes increasing the total mould thickness. Therefore, it is important to determine the drying time of each deposited layer in order to prevent the mould cracking due to insufficient drying of layers and thus the weakening of the multilayer mould structure.

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Authors and Affiliations

J. Kolczyk
Ł. Jamrozowicz
J. Zych
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Abstract

Measurements of the hardening process course of the selected self-hardening moulding sands with the reclaimed material additions to the matrix, are presented in the hereby paper. Moulding sands were produced on the „Szczakowa” sand (of the Sibelco Company) as the matrix of the main fraction FG 0,40/0,32/0,20, while the reclaim was added to it in amounts of 20, 50 and 70%. Regeneration was performed with a horizontal mechanical regenerator capacity of 10 t/h. In addition, two moulding sands, one on the fresh sand matrix another on the reclaimed matrix, were prepared for comparison. Highly-fluid urea-furfuryl resin was used as a binder, while paratoluensulphonic acid as a hardener. During investigations the hardening process course was determined, it means the wave velocity change in time: cL = f(t). The hardening process kinetics was also assessed (dClx/dt = f(t)). Investigations were carried out on the research stand for ultrasound tests. In addition strength tests were performed.

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Authors and Affiliations

Ł. Jamrozowicz
J. Kolczyk
P. Wojtuń
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Abstract

Measurements of the hardening process of the selected self-setting sands are presented in the hereby paper. Moulding sands were prepared

on the matrix of „Szczakowa” sand of the Sibelco Company. Two resins: phenol-formaldehyde-furfuryl (FF/AF) and urea-formaldehydefurfuryl

(MF/AF) were used for making moulding sands. – Methylbenzene-sulphonic acid was applied as a hardener for the moulding sand

on FF/AF resin, while paratoluene-sulphonic acid for the moulding sand on MF/AF resin. Both hardeners were used in two concentrations:

low – the so-called ‘slow’ hardener and high - ‘fast’ hardener. During investigations, the courses of the hardening process were

determined, more accurately changes of the velocity of the ultrasound wave passage through the moulding sand cL = f(t) and changes of

the moulding sand hardening degree versus time, Sx = f(t). In addition, the kinetics of the hardening process was determined.

Measurements were performed on the research stand for ultrasound investigations.

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Authors and Affiliations

Ł. Jamrozowicz
J. Kolczyk
N. Kaźnica
Z. Pyziak
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Abstract

The results of investigations of humidity migration in near surface layers of sand mould during processes of penetration and drying of protective coatings are presented in the hereby paper. The process of the humidity exchanging between surroundings and moulding sands as porous materials, is widely described in the introduction. In addition, the humidity flow through porous materials, with dividing this process into stages in dependence of the humidity movement mechanism, is presented. Next the desorption process, it means the humidity removal from porous materials, was described. Elements of the drying process intensity as well as the water transport mechanisms at natural and artificial drying were explained. The innovative research stands for measuring resistance changes of porous media due to humidity migrations was applied in investigations. Aqueous zirconium coatings of two apparent viscosities 10s and 30s were used. Viscosity was determined by means of the Ford cup of a mesh clearance of 4mm. Coatings were deposited on cores made of the moulding sand containing sand matrix, of a mean grain size dL = 0.25 mm, and phenol-formaldehyde resin. Pairs of electrodes were placed in the core at depths: 2, 3, 4, 5, 8, 12 and 16 mm. Resistance measurements were performed in a continuous way. The course of the humidity migration process in the core surface layer after covering it by protective coating was determined during investigations. Investigations were performed in the room where the air temperature was: T = 22˚C but the air humidity was not controlled, as well as in the climatic chamber where the air temperature was: T = 35˚C and humidity: H = 45%. During the research, it was shown that the process of penetration (sorption) of moisture into the moulding sand is a gradual process and that the moisture penetrates at least 16 mm into the sand. In the case of the drying (desorption) process, moisture from the near-surface layers of the moulding sand dries out much faster than moisture that has penetrated deeper into the sand. Keywords: Core, Sand mould, Porous medium, Humidity migration, Protective coatings, Resistance measurement
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Bibliography

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Authors and Affiliations

Ł. Jamrozowicz
1
ORCID: ORCID
J. Zych
1
ORCID: ORCID

  1. AGH University of Science and Technology, Faculty of Foundry Engineering, Department of Moulding Materials, Mould Technology and Cast Non-Ferrous Metals, Al. Mickiewicza 30, 30-059 Kraków, Poland

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