The results of researches of sorption processes of surface layers of components of sand moulds covered by protective coatings are

presented in the hereby paper. Investigations comprised various types of sand grains of moulding sands with furan resin: silica sand,

reclaimed sand and calcined in temperature of 700oC silica sand. Two kinds of alcoholic protective coatings were used – zirconium and

zirconium – graphite. Tests were performed under condition of a constant temperature within the range 30 – 35oC and high relative air

humidity 75 - 80%. To analyze the role of sand grains in sorption processes quantitavie moisture sorption with use of gravimetric method

and ultrasonic method were used in measurements. The tendency to moisture sorption of surface layers of sand moulds according to the

different kinds of sand grains was specified. The effectiveness of protective action of coatings from moisture sorption was analyzed as

well.

Knowledge of the role of sand grains from the viewpoint of capacity for moisture sorption is important due to the surface casting defects

occurrence. In particular, that are defects of a gaseous origin caused by too high moisture content of moulds, especially in surface layers.

A large number of defects of castings made in sand moulds is caused by gases. There are several sources of gases: gases emitted from moulds, cores or protective coatings during pouring and casting solidification; water in moulding sands; moisture adsorbed from surroundings due to atmospheric conditions changes. In investigations of gas volumetric emissions of moulding sands amounts of gases emitted from moulding sand were determined - up to now - in dependence of the applied binders, sand grains, protective coatings or alloys used for moulds pouring. The results of investigating gas volumetric emissions of thin-walled sand cores poured with liquid metal are presented in the hereby paper. They correspond to the surface layer in the mould work part, which is decisive for the surface quality of the obtained castings. In addition, cores were stored under conditions of a high air humidity, where due to large differences in humidity, the moisture - from surroundings - was adsorbed into the surface layer of the sand mould. Due to that, it was possible to asses the influence of the adsorbed moisture on the gas volumetric emission from moulds and cores surface layers by means of the new method of investigating the gas emission kinetics from thin moulding sand layers heated by liquid metal. The results of investigations of kinetics of the gas emission from moulding sands with furan and alkyd resins as well as with hydrated sodium silicate (water glass) are presented. Kinetics of gases emissions from these kinds of moulding sands poured with Al-Si alloy were compared.

The results of investigations of the rheological properties of typical ceramic slurries used in the investment casting technology – the lost

wax technology are presented in the paper. Flow curves in the wide range of shear velocity were made. Moreover, viscosity of ceramic

slurries depending on shearing stresses was specified. Tests were performed under conditions of three different temperatures 25, 30 and

35oC, which are typical and important in the viewpoint of making ceramic slurries in the investment casting technology.

In the light of the performed investigations can be said that the belonging in group of Newtonian or Non – Newtonian fluid is dependent

on content of solid phase (addition of aluminum oxide) in the whole composition of liquid ceramic slurries.

The graphite form in cast iron is the structure parameter deciding on its all physical and mechanical properties. Three basic forms of graphite: flake, vermicular (compact) and nodular (spheroidal) are singled out in standard cast iron grades, without a heat treatment. Standards of individual grades of cast iron the most often allow only the homogeneous graphite form, sometimes with addition of 5÷10% of the other form. The interesting and - in the authors opinion - future-oriented material can constitute cast iron in which various forms of graphite are present, e.g. in comparative amounts: spherical and vermicular cast irons. Cast iron within which graphite occurs in two or three forms was named „Vari-Morph” (VM) cast iron, i.e. the one in which spherical and vermicular or vermicular and flake graphite occur in a wide range of proportions. The results of investigations of these new cast iron grades and their properties are presented in the hereby paper.

Gas emission from casting moulds, cores and coatings applied for sand and permanent moulds is one of the fundamental reasons of casting defects occurrence. In the previous studies, gas emission was measured in two ways: normalized, in which the evolving gas volume was measured during heating of the moulding sand sample in a sealed flask, or by measuring the amount of gas from sand core (sample) which is produced during the pouring of liquid metal. After the pouring process the sand mould is heated very unequally, the most heated areas are layers adjacent to the liquid metal. The emission of gas is significantly larger from the surface layer than from the remaining ones. New, original method of measuring kinetics of gas emission from very thin layers of sand moulds heated by liquid metal developed by the authors is presented in the hereby paper. Description of this new method and the investigation results of kinetics of gas emission from moulding sand with furan and alkyd resin are shown. Liquid grey cast iron and Al-Si alloy were used as a heat source in the sand moulds. Comparison of the kinetics of gas emission of these two kinds of moulding sands filled with two different alloys was made. The momentary metal temperature in sand mould was assigned to the kinetics of gas emission, what creates a full view of the possibility of formation of casting defects of the gaseous origin. Moulding sand with alkyd resin is characterized by larger gas emission; however gases are emitted slower than in the case of moulding sands with furan resin. This new investigation method has a high repeatability and is the only one which gives a full view of phenomenon’s in the surface layer which determines quality of the casings. The obtained results are presented on several graphs and analyzed in detail. They have a great application value and can be used in the production of iron as well as light metal alloy castings.

Measurements of the hardening process of the selected self-setting sands are presented in the hereby paper. Moulding sands were prepared

on the matrix of „Szczakowa” sand of the Sibelco Company. Two resins: phenol-formaldehyde-furfuryl (FF/AF) and urea-formaldehydefurfuryl

(MF/AF) were used for making moulding sands. – Methylbenzene-sulphonic acid was applied as a hardener for the moulding sand

on FF/AF resin, while paratoluene-sulphonic acid for the moulding sand on MF/AF resin. Both hardeners were used in two concentrations:

low – the so-called ‘slow’ hardener and high - ‘fast’ hardener. During investigations, the courses of the hardening process were

determined, more accurately changes of the velocity of the ultrasound wave passage through the moulding sand cL = f(t) and changes of

the moulding sand hardening degree versus time, Sx = f(t). In addition, the kinetics of the hardening process was determined.

Measurements were performed on the research stand for ultrasound investigations.