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Abstract

The amorphous Mg-based alloys may be used as metallic biomaterials for resorbable orthopedic implants. The Mg-Zn-Ca metallic glasses demonstrate variable in time degradation rate in simulated body fluid. In this work the Mg66Zn30Ca4 alloy was chosen as a substrate for coatings. This paper reports on the surface modification of a Mg66Zn30Ca4 metallic glass by plasma electrolytic oxidation (PEO). The structure characterization of uncoated Mg66Zn30Ca4 alloy was performed by using TEMand XRD method. The immersion tests of coated and uncoated Mg66Zn30Ca4 alloy were carried out in Ringer’s solutionat 37°C. The volume of released hydrogen by immersion tests was determined. The coatings structure and chemical composition after immersion tests by SEM/EDS were studied. Based on SEM images of surface structure samples, immersion tests results and hydrogen evolution measurement was proposed the course of corrosion process in Ringer’s solution for Mg-based metallic glasses with PEO coating. Results of immersion tests in Ringer’s solution allowed to determine the amount of evolved hydrogen in a function of time for Mg66Zn30Ca4 metallic glass and sample with PEO coating. In comparison to the non-coated Mg66Zn30Ca4 alloy, the sample with PEO layer showed a significantly decreased hydrogen evolution volume.

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Authors and Affiliations

K. Cesarz-Andraczke
A. Kazek-Kęsik
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Abstract

Scientists and medics are still searching for new metallic materials that can be used in medicine, e.g., as material for implants. The following article proposes materials based on titanium with vital elements prepared by combined powder metallurgy and arc melting methods. Four compositions of Ti-28Ta-9Nb, Ti-28Ta-19Nb, Ti-28Ta-9Zr and Ti-28Ta-19Zr (wt.%) have been prepared. The tested material was thoroughly analyzed by X-ray diffraction and scanning electron microscopy. Qualitative phase analysis using X-ray diffraction showed the presence of two phases, α' and β titanium. In addition, a microhardness test was conducted, and the material was characterized in terms of corrosion properties. It was found that the corrosion resistance decreases with an increase of the β phase presence.
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Authors and Affiliations

I. Matuła
1
ORCID: ORCID
G. Dercz
1
ORCID: ORCID
K. Prusik
1
ORCID: ORCID
M. Szklarska
1
ORCID: ORCID
A. Kazek-Kęsik
2
ORCID: ORCID
W. Simka
2
ORCID: ORCID
E. Sudoł
3

  1. University of Silesia in Katowice, Institute of Materials Engineering, 75 Pułku Piechoty Str., 1 A, 41-500 Chorzów, Poland
  2. Silesian University of Technology, Faculty of Chemistry, 6 B. Krzywoustego Str., 44-100 Gliwice, Poland
  3. Graduate, Institute of Materials Engineering, University of Silesia in Katowice, 75 Pułku Piechoty Street 1 A, 41-500 Chorzów, Poland
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Abstract

This work investigated two titanium-based alloys with a constant tantalum content and variable contents of alloy additives – niobium and zirconium. The Ti-30Ta-10Zr-20Nb (wt.%) and Ti-30Ta-20Zr-10Nb (wt.%) alloys were obtained using a combination of powder metallurgy and arc melting methods. The influence of alloying additives on the structure and properties of the Ti-Ta-Nb-Zr system was studied using, among others: X-ray diffraction and scanning electron microscopy. The X-ray diffraction confirmed the single-β-phase structure of both alloys. In addition, the microscopic analysis revealed that a higher amount of zirconium favoured the formation of larger grains. However, the microhardness analysis indicated that the alloy with the higher niobium content had the higher microhardness. Importantly, the in vitro corrosion study revealed that the addition of niobium promoted the better corrosion resistance of the investigated alloy.
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Authors and Affiliations

G. Dercz
1
ORCID: ORCID
I. Matuła
1
ORCID: ORCID
K. Prusik
1
ORCID: ORCID
J. Zając
1
M. Szklarska
1
ORCID: ORCID
A. Kazek-Kęsik
2
ORCID: ORCID
W. Simka
2
ORCID: ORCID

  1. Institute of Materials Engineering, University of Silesia in Katowice, 75 Pułku Piechoty Street 1 A, 41-500 Chorzów, Poland
  2. Faculty of Chemistry, Silesian University of Technology, B. Krzywoustego Street 6, 44-100 Gliwice, Poland

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