Breath analysis has attracted human beings for centuries. It was one of the simplest methods to detect various diseases by using human smell sense only. Advances in technology enable to use more reliable and standardized methods, based on different gas sensing systems. Breath analysis requires the detection of volatile organic compounds (VOCs) of the concentrations below individual ppm (parts per million). Therefore, advanced detection methods have been proposed. Some of these methods use expensive and bulky equipment (e.g. optical sensors, mass spectrometry –MS), and require time-consuming analysis. Less accurate, but much cheaper, are resistive gas sensors. These sensors use porous materials and adsorptiondesorption processes, determining their physical parameters.We consider the problems of applying resistive gas sensors to breath analysis. Recent advances were underlined, showing that these economical gas sensors can be efficiently employed to analyse breath samples. General problems of applying resistive gas sensors are considered and illustrated with examples, predominantly related to commercial sensors and their long-term performance. A setup for collection of breath samples is considered and presented to point out the crucial parts and problematic issues.
This paper presents a portable exhaled breath analyser, developed to detect selected diseases. The set-up
employs resistive gas sensors: commercial MEMS sensors and prototype gas sensors made of WO3 gas
sensing layers doped with various metal ingredients. The set-up can modulate the gas sensors by applying
UV light to induce physical changes of the gas sensing layers. The sensors are placed in a tiny gas
chamber of a volume of about 22 ml. Breath samples can be either injected or blown into the gas chamber
when an additional pump is used to select the last breath phase. DC resistance and resistance fluctuations
of selected sensors using separate channels are recorded by an external data acquisition board. Low-noise
amplifiers with a selected gain were used together with a necessary bias circuit. The set-up monitors other
atmospheric parameters interacting with the responses of resistive gas sensors (humidity, temperature, atmospheric
pressure). The recorded data may be further analysed to determine optimal detection methods.
Raman spectrometers are devices which enable fast and non-contact identification of examined chemicals. These devices utilize the Raman phenomenon to identify unknown and often illicit chemicals (e.g. drugs, explosives) without the necessity of their preparation. Now, Raman devices can be portable and therefore can be more widely used to improve security at public places. Unfortunately, Raman spectra measurements is a challenge due to noise and interferences present outside the laboratories. The design of a portable Raman spectrometer developed at the Faculty of Electronics, Telecommunications and Informatics, Gdansk University of Technology is presented. The paper outlines sources of interferences present in Raman spectra measurements and signal processing techniques required to reduce their influence (e.g. background removal, spectra smoothing). Finally, the selected algorithms for automated chemicals classification are presented. The algorithms compare the measured Raman spectra with a reference spectra library to identify the sample. Detection efficiency of these algorithms is discussed and directions of further research are outlined.