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Number of results: 250
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Abstract

Microstructures and mechanical properties of as-cast Al-6.5Mg-1.5Zn-0.5Fe alloys newly alloy-designed for the parts of automobile were investigated in detail. The aluminum (Al) sheets of 4 mm thickness, 30 mm width and 100 mm length were reduced to a thickness of 1mm by multi-pass rolling at ambient temperature and subsequently annealed for 1h at 200~500°C. The as-cast Al sheet was deformed without a formation of so large cracks even at huge rolling reduction of 75%. The recrystallization begun to occur at 250°C, it finished at 350°C. The as-rolled material showed tensile strength of 430 MPa and tensile elongation of 4.7%, however the specimen after annealing at 500°C showed the strength of 305 MPa and the elongation of 32%. The fraction of high angle grain boundaries above 15 degree increased greatly after annealing at high temperatures. These characteristics of the specimens after annealing were discussed in detail.

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Authors and Affiliations

Seong-Hee Lee
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Abstract

A cold roll-bonding process was applied to fabricate an AA1050/AA6061/AA1050 multi-layer sheet. Three Al sheets in which an AA6061 sheet is inserted inside two AA1050 sheets of 2 mm thickness, 40 mm width and 300 mm length were stacked up after surface treatment, and the material was then reduced to a thickness of 1.0 mm by multi-pass cold rolling. The AA1050/AA6061/ AA1050 laminate complex sheet fabricated by roll bonding was then hardened by a natural aging (T4) and an artificial aging (T6) treatments. The microstructures of the as-roll bonded and the age-hardened Al complex sheets were revealed by optical microscope and electron back scatter diffraction analysis, and the mechanical properties were investigated by tensile and hardness testing. The strength of the as-roll bonded complex sheet was found to increase by 2.6 times, compared to that value of the starting material. Both AA1050 and AA6061 showed a typical recrystallization structure in which the grains were equiaxed after heat treatment. However, the grain size was smaller in AA6061 than in AA1050.

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Authors and Affiliations

S.-H. Lee
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Abstract

The objective of the present study was to investigate the effects of Sn addition on the mechanical and corrosion properties of Mg-1Zn-1Zr-xSn (x = 1, 2, 3, 4, 5 wt.%) alloys prepared by powder-in-tube rolling (PTR) method. The PTR-treated Mg alloys reached 98.3% of theoretical density. The hardness of the alloy increased with Sn addition. Two main intermetallic phases, Mg2Sn and Zn2Zr3, were formed in the alloys. The Mg2Sn intermetallic particles were observed along the grain boundaries, while the Zn2Zr3 particles were distributed in the Mg matrix. The addition of 1 wt. % Sn caused the corrosion potential to shift toward a more positive value, and the resulting alloy exhibited low corrosion current density.

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Authors and Affiliations

A. Zakiyuddin
K. Lee
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Abstract

Recently, the rapid advancement of the IT industry has resulted in significant changes in audio-system configurations; particularly, the audio over internet protocol (AoIP) network-based audio-transmission technology has received favourable evaluations in this field. Applying the AoIP in a certain section of the multiple-cable zone is advantageous because the installation cost is lower than that for the existing systems, and the original sound is transmitted without any distortion. The existing AoIP-based technology, however, cannot control the audio-signal characteristics of every device and can only transmit multiple audio signals through a network. In this paper, the proposed Audio Network & Control Hierarchy Over peer-to-peer (Anchor) system enables all audio equipment to send and receive signals via a data network, and the receiving device can mix the signals of different IPs. Accordingly, it was possible to improve the system-application flexibility by simplifying the audio-system configuration. The research results confirmed that the received audio signals from different IPs were received, mixed, and output without errors. It is expected that Anchor will become a standard for audio-network protocols.

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Authors and Affiliations

Jaeho Lee
Hyoungjoon Jeon
Pyungho Choi
Soonchul Kwon
Seunghyun Lee
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Abstract

An ecoefficient, economical and sustainable valorization process for the synthesis of Co3O4 from waste lithium-ion battery (LIB) by leaching-solvent extract-scrubbing-precipitation stripping route has been developed. Through an optimization, the waste LIB cathode was leached using 2000 mole/m3 of H2SO4 and 5 Vol. % of the H2O2 at a pulp density of 100 kg/m3 under leaching time 60 minutes and temperature 75 °C. From the separated leach liquor, cobalt was purified by saponified Cyanex 272. From cobalt, loaded Cyanex 272 impurities were scrubbed and the CoC2O4·2H2O was recovered through precipitation stripping. Finally, the precipitate was calcined to synthesize Co3O4, which is a precursor for LIB cathode materials manufacturing. From TGA-DTA, followed by XRD analysis it was confirmed that at 200 °C the CoC2O4·2H2O can be converted to anhydrous CoC2O4 and at 350 °C the anhydrous can be converted to Co3O4 and at 1100 °C the Co3O4 can be converted to CoO. Through reported route waste LIB can back to LIB manufacturing process through a versatile and flexible industrial approach.
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Authors and Affiliations

B. Swain
J.-C. Lee
C.-G. Lee
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Abstract

We investigated the effect of pre-sintering process on the penetration behavior of Dy in a NdFeB sintered magnet which was grain boundary diffusion treated with Cu/Al mixed Dy source. The pre-sintering of a magnet was performed at 900oC in vacuum and then the pre-sintered body was dipped in the solutions of DyH2, DyH2 + Cu, and DyH2 + Al, respectively. The dipped pre-sintered body were then fully sintered 4 hours at 1060oC followed by a subsequent annealing. The pre-sintering apparently improved the diffusivity of Dy atoms. The penetration of Dy into the magnet extended almost to 2,000 μm from the surface, about four times deeper than that of the normally sintered and diffusion treated one, when the DyH2 + Al solution was used as a Dy source. However, the resulting increase of coercivity was about 4 kOe, somewhat lower than that of the normally treated one, mostly due to excessive oxide formation that hindered to make a continuous Nd-rich grain boundary phase and a core-shell type structure.

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Authors and Affiliations

M.W. Lee
J.K. Lee
T.S. Jang
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Abstract

The purpose of this study was to investigate the mechanical properties of beta type aged Ti-4Mo-4Cr-X (X = V, Sn, Zr) quaternary alloy for use as a cardiovascular stent. Titanium (Ti) alloys were fabricated using a vacuum arc remelting furnace process. To homogenize the specimens of each composition and remove the micro segregation, all cast specimens were subjected to homogenization at 850℃ for 4 h, which was 100℃ higher than the β-transus temperature of 750℃. The tensile strength and elongation of the aged Ti-4Mo-4Cr-X (X = V, Sn, Zr) alloys were increased as compared to the homogenized alloys. In addition, many α/β interface boundaries formed after aging treatment at 450°C, which acted as inhibitors of strain and caused an increase in tensile strength. The elongation of Ti-4Mo-4Cr-X alloys consisting of α + β phases after aging treatment was improved by greater than 30%. Results of a potentiodynamic polarization test showed that the lowest current density of Ti-4Mo-4Cr-4Sn with 1.05 × 10–8 A/cm2 was obtained. The present Ti-4Mo-4Cr-X alloys showed better corrosion characteristics as compared to the 316L stainless steel and L605 (Co-Cr alloy) cardiovascular stent alloys.

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Authors and Affiliations

Kwangmin Lee
ORCID: ORCID
Gunhee Lee
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Abstract

This study investigates the microstructures and the mechanical properties of equiatomic Ti20Mo20Ta20Nb20V20 and non-equiatomic Ti40Mo15Ta15Nb15V15 and Ti60Mo10Ta10Nb10V10 HEAs using X-ray diffraction (XRD) analysis, field emission scanning electron microscope (FE-SEM), and micro-Vickers hardness test. The specimens were fabricated using the vacuum arc remelting (VAR) process and homogenized at a temperature of 1300°C for 4 h in a vacuum atmosphere. The determined thermodynamic parameters, Ω ≥ 1.1, δ ≤ 6.6%, and VEC < 6.87, suggested that the HEAs consisted of BCC solid solutions. XRD patterns of all the HEAs displayed single BCC phases. The difference in the solidification rate led to the micro-segregation associated with the elements Ta and Mo enriched in the dendrite arms and the elements V and Ti in the inter-dendritic regions. The HEA specimens showed a decrease in hardness with higher concentration of Ti element because the intrinsic hardness of Ti is lower as compared to the intrinsic hardness of Nb and Mo.

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Authors and Affiliations

Seongi Lee
Kwangmin Lee
ORCID: ORCID
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Abstract

The present study investigated various thermodynamic parameters, microstructures and electrochemical behaviors of TiMoVCrZr and Ti-rich TiMoVCrZr high-entropy alloys (HEAs) prepared by vacuum arc remelting. The microstructures of the alloys were analyzed using X-ray diffraction (XRD) analysis, field emission scanning electron microscopy (FE-SEM), and potentiodynamic polarization tests. The determined thermodynamic values of the Ω-parameter and the atomic size difference (δ) for the HEAs were determined to be in the range of Ω ≥ 1.1, and δ ≤ 6.6% with valance electron configuration (VEC) ≤ 5.0, suggesting the HEAs were effective at forming solid solutions. XRD patterns of the equiatomic Ti20Mo20V20Cr20Zr20 HEA revealed four phases consisting of the body centered cubic1 (BCC1), BCC2, hexagonal close-packed (HCP), and intermetallic compound Cr2Zr phases. Three phases were observed in the XRD patterns of Ti-rich Ti40Mo15V15Cr15Zr15 (BCC, HCP, and Cr2Zr) and a single BCC phase was observed in Ti-rich Ti60Mo10V10Cr10Zr10 HEAs. The backscattered-electron (BSE) images on the equiatomic Ti20Mo20V20Cr20Zr20 HEA revealed BCC and HCP phases with Cr2Zr precipitates, suggesting precipitation from the HCP solid solution during the cooling. The micro-segregation of Ti-rich Ti60Mo10V10Cr10Zr10 HEAs appeared to decrease remarkably. The alloying elements in the HEAs were locally present and no phase changes occurred even after additional HIP treatment. The lowest current density obtained in the polarization potential test of Ti-rich Ti40Mo15V15Cr15Zr15 HEA was 7.12×10–4 mA/cm2 was obtained. The studied TiMoVCrZr HEAs showed improved corrosion characteristics as compared to currently available joint replacement material such as ASTM F75 alloy.

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Authors and Affiliations

Hocheol Song
Seongi Lee
Kwangmin Lee
ORCID: ORCID
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Abstract

Ag and Cu powders were mechanically alloyed using high-energy planetary milling to evaluate the sinter-bonding characteristics of a die-attach paste containing particles of these two representative conductive metals mixed at atomic scale. This resulted in the formation of completely alloyed Ag-40Cu particles of 9.5 µm average size after 3 h. The alloyed particles exhibited antioxidation properties during heating to 225°C in air; the combination of high pressure and long bonding time at 225°C enhanced the shear strength of the chip bonded using the particles. Consequently, the chips sinter-bonded at 225°C and 10 MPa for 10 min exhibited a sufficient strength of 15.3 MPa. However, an increase in bonding temperature to 250°C was detrimental to the strength, due to excessive oxidation of the alloyed particles. The mechanically alloyed phase in the particle began to decompose into nanoscale Ag and Cu phases above a bonding temperature of 225°C during heating.

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Authors and Affiliations

Woo Lim Choi
Jong-Hyun Lee

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