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Abstract

Presented study aimed to determine metals distribution on the quartz fiber filters surface coated with particulate matter by using high and low-volume samplers. The distribution pattern was tested using two different sub-sampling schemes. Each sub-sample was mineralized in the nitric acid in a microwave oven. An analysis was performed by means of atomic absorption spectroscopy with electrothermal atomization GF-AAS technique, and the determined elements were: As, Cd, Pb and Ni. A validation of the analytical procedure was carried out using NIES 28 Urban Aerosols standard reference material.

It was assumed that metal is distributed uniformly if its normalized concentrations on a single sub-sample is within ±15% of the mean concentration over the whole filter. The normalized concentrations values exceed this range, indicating a non-homogenous metals distribution. There were no statistically significant differences in metals concentrations between particular sub-samples in the function of its position along the filters diameter.

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Authors and Affiliations

Kamila Widziewicz
Wioletta Rogula-Kozłowska
Krzysztof Loska
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Abstract

The zinc and lead industry generates substantial quantities of waste. Among the many types of wastes, such as dust or liquid, a large proportion are solid waste such as slags. The purpose of the study was the qualitative and quantitative assessment of the short rotary kiln slags and slags deposited in a hazardous waste landfill originating from zinc and lead metallurgy. This assessment represents the primary step in evaluating materials such as slags concerning their potential for substantial applications, such as process for metal separation. Additionally, this evaluation forms the basis for a comprehensive environmental study. The concentrations of the four predominant metals – Fe>Pb>Zn>Cu – and accompanying elements – Na>Ca>K>Ni>Mn>Cr – were determined using atomic absorption spectroscopy (AAS) after aqua regia digestion. A large variation was found in the phase analysis of the studied materials based on SEM, XRD, X-ray microanalysis, and BCR sequential extraction. The BCR analysis revealed the occurrence of major metals in four different fractions: acid-soluble, reducible, oxidizable, and residual. Pb was mainly present in the acid-soluble fraction, while Fe, Cu, and Zn were present in the residual fraction.
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Authors and Affiliations

Milena Nocoń
1
Irena Korus
1
Krzysztof Loska
1

  1. Silesian University of Technology, Faculty of Environmental Engineering and Energy, Department of Water and Wastewater Engineering, Poland

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