The article contains considerations on the historical evolution of globalization in the context of the rivalry between two basic concepts of economic system: pro-state option and pro-market option. The author assumes that globalization is a permanent feature of human aspirations. In the beginning of modern era it was interlocked with the alternating dominance of pro-market and pro-state tendencies, and it continues to appear in the same form until present times. The liberal economic thought has expressed these opposition in the state versus market formula. Over the last five centuries there have been five stages of alternating dominance of pro-market and pro-state forces, connected with globalization. First was the mercantilism with the significant role of state, and its antithesis was the XIX-century free-competition capitalism. Two last stages – the neo-liberalism dating from 1980 to 2008 and its antithesis from 2009 to 2019 – have been presented in detail. The previous stages are shown only as historical background. The analysis is preceded by the outline of a theoretical model of globalization connected with the alternating dominance of pro-state and pro-market tendencies, which can be seen as value added to the legacy of economic thought devoted to the relationship between market and state.
Polish Academy of Sciences, Institute of Chemical Engineering, 44-100 Gliwice, Bałtycka 5, Poland A review concerning main processes of hydrogenation of carbon oxides towards synthesis of methanol, mixture of methanol and higher aliphatic alcohols and one-step synthesis of dimethyl ether as well as methanol steam reforming is given. Low-temperature methanol catalysts and lowtemperature modified methanol catalysts containing copper as primary component and zinc as secondary one are described.
Hydrogen is the fuel of the future, therefore many hydrogen production methods are developed. At present, fuel cells are of great interest due to their energy efficiency and environmental benefits. A brief review of effective formation methods of hydrogen was conducted. It seems that hydrogen from steam reforming of methanol process is the best fuel source to be applied in fuel cells. In this process Cu-based complex catalysts proved to be the best. In presented work kinetic equations from available literature and catalysts are reported. However, hydrogen produced even in the presence of the most selective catalysts in this process is not pure enough for fuel cells and should be purified from CO. Currently, catalysts for hydrogen production are not sufficiently active in oxidation of carbon monoxide. A simple and effective method to lower CO level and obtain clean H2 is the preferential oxidation of monoxide carbon (CO-PROX). Over new CO-PROX catalysts the level of carbon monoxide can be lowered to a sufficient level of 10 ppm.