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Number of results: 34
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Abstract

Growing emission requirements are forcing the foundry industry to seek new, more environmentally friendly solutions. One of the

solutions may be the technologies of preparing moulding and core sands using organic biodegradable materials

as binders. However, not only environmental requirements grow but also those related to the technological properties

of moulding sand. Advancing automation and mechanization of the foundry industry brings new challenges related to the moulding sands.

Low elasticity may cause defects during assembly of cores or moulds by the manipulators.

The paper presents the study of flexibility in the room temperature according to new method and resistance to thermal deformation of selfhardening

moulding sands with furfuryl resin, containing biodegradable material PCL. The task of the new additive is to reduce the

moulding sands harmfulness to the environment and increase its flexibility in the room temperature. The impact of the additive and the

effect of the amount of binder on the properties of mentioned moulding sands were analysed. Studies have shown that the use of 5% of

PCL does not change the nature of the thermal deformation curve, improves the bending strength of tested moulding mixtures and

increases their flexibility at room temperature.

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Authors and Affiliations

A. Grabarczyk
K. Major-Gabryś
St.M. Dobosz
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Abstract

The article shows the influence of environment requirements on changes in different foundry moulding sands technologies such as cold

box, self-hardening moulding sands and green sands. The aim of the article is to show the possibility of using the biodegradable materials

as binders (or parts of binders’ compositions) for foundry moulding and core sands. The authors concentrated on the possibility of

preparing new binders consisting of typical synthetic resins - commonly used in foundry practice - and biodegradable materials. According

to own research it is presumed that using biodegradable materials as a part of new binders’ compositions may cause not only lower toxicity

and better ability to reclaim, but may also accelerate the biodegradation rate of used binders. What’s more, using some kinds of

biodegradable materials may improve flexibility of moulding sands with polymeric binder. The conducted research was introductory and

took into account bending strength and thermal properties of furan moulding sands with biodegradable material (PCL). The research

proved that new biodegradable additive did not decrease the tested properties.

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Authors and Affiliations

St.M. Dobosz
A. Grabarczyk
K. Major-Gabryś
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Abstract

The paper presents the impact of biodegradable material - polycaprolactone (PCL) on selected properties of moulding sands. A self-hardening moulding sands with phenol-furfuryl resin, which is widely used in foundry practice, and an environmentally friendly self-hardening moulding sand with hydrated sodium silicate where chosen for testing. The purpose of the new additive in the case of synthetic resin moulding sands is to reduce their harmfulness to the environment and to increase their “elasticity” at ambient temperature. In the case of moulding sands with environmentally friendly hydrated sodium silicate binder, the task of the new additive is to increase the elasticity of the tested samples while preserving their ecological character. Studies have shown that the use of 5% PCL in moulding sand increases their flexibility at ambient temperature, both with organic and inorganic binders. The influence of the new additive on the deformation of the moulding sands at elevated temperatures has also been demonstrated.
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Authors and Affiliations

A. Grabarczyk
S.M. Dobosz
K. Major-Gabryś
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Abstract

This paper focuses on mechanical properties of self hardening moulding sands with furfuryl and alkyd binders. Elasticity as a new

parameter of moulding sands is investigated. With the use of presented testing equipment, it is possible to determine force kinetics and

deformation of moulding sand in real time. The need for this kind of study comes from the modern casting industry. New foundries can be

characterized with high intensity of production which is correlated with high level of mechanization and automatization of foundry

processes. The increasingly common use of manipulators in production of moulds and cores can lead to generation of new types of flaws,

caused by breakage in moulds and cores which could occur during mould assembly. Hence it is required that moulds and cores have high

resistance to those kinds of factors, attributing it with the phenomenon of elasticity. The article describes the theoretical basis of this

property, presents methods of measuring and continues earlier research.

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Authors and Affiliations

St.M. Dobosz
A. Grabarczyk
K. Major-Gabryś
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Abstract

Recently, some major changes have occurred in the structure of the European foundry industry, such as a rapid development in the production of castings from compacted graphite iron and light alloys at the expense of limiting the production of steel castings. This created a significant gap in the production of heavy steel castings (exceeding the weight of 30 Mg) for the metallurgical, cement and energy industries. The problem is proper moulding technology for such heavy castings, whose solidification and cooling time may take even several days, exposing the moulding material to a long-term thermal and mechanical load. Owing to their technological properties, sands with organic binders (synthetic resins) are the compositions used most often in industrial practice. Their main advantages include high strength, good collapsibility and knocking out properties, as well as easy mechanical reclamation. The main disadvantage of these sands is their harmful effect on the environment, manifesting itself at various stages of the casting process, especially during mould pouring. This is why new solutions are sought for sands based on organic binders to ensure their high technological properties but at the same time less harmfulness for the environment. This paper discusses the possibility of reducing the harmful effect of sands with furfuryl binders owing to the use of resins with reduced content of free furfuryl alcohol and hardeners with reduced sulphur content. The use of alkyd binder as an alternative to furfuryl binder has also been proposed and possible application of phenol-formaldehyde resins was considered.

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Authors and Affiliations

K. Major-Gabryś
ORCID: ORCID
M. Hosadyna-Kondracka
ORCID: ORCID
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Abstract

Due to the presence of harmful substances in resins those mould sands may be hazardous to the natural environment and workers. The general assessment of harmfulness of sands used for molds and cores encompasses 2 basic points: emission of hazardous substances during processes of preparing sands, pouring mold with liquid metals (high temperatures), cooling and shaking-out; possibility of washing out hazardous substances from used sands to the environment, during storage or economic use outside foundries. We present the results of research on the emission of BTEX compounds from mould sands with phenolic resins during pouring liquid metal of different temperature (cast iron and Al alloy). The research was conducted according to the original method prepared by the authors, which has been used for years in cooperation with various foundries (Poland, abroad).
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Authors and Affiliations

St.M. Dobosz
J. Jakubski
K. Major-Gabryś
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Abstract

The necessity of obtaining high quality castings forces both researchers and producers to undertake research in the field of moulding sands. The key is to obtain moulding and core sands which will ensure relevant technological parameters along with high environmental standards. The most important group in this research constitutes of moulding sands with hydrated sodium silicate. The aim of the article is to propose optimized parameters of hardening process of moulding sands with hydrated sodium silicate prepared in warm-box technology. This work focuses on mechanical and thermal deformation of moulding sands with hydrated sodium silicate and inorganic additives prepared in warm-box technology. Tested moulding sands were hardened in the temperature of 140oC for different time periods. Bending strength, thermal deformation and thermal degradation was tested. Chosen parameters were tested immediately after hardening and after 1h of cooling. Conducted research proved that it is possible to eliminate inorganic additives from moulding sands compositions. Moulding sands without additives have good enough strength properties and their economic and ecological character is improved.
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Authors and Affiliations

K.A. Major-Gabryś
S.M. Dobosz
A.P. Grabarczyk
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Abstract

The constantly developing and the broadly understood automation of production processes in foundry industry, creates both new working conditions - better working standards, faster and more accurate production - and new demands for previously used materials as well as opportunities to generate new foundry defects. Those high requirements create the need to develop further the existing elements of the casting production process. This work focuses on mechanical and thermal deformation of moulding sands prepared in hot-box technology. Moulding sands hardened in different time periods were tested immediately after hardening and after cooling. The obtained results showed that hardening time period in the range 30-120 sec does not influence the mechanical deformation of tested moulding sands significantly. Hot distortion tests proved that moulding sands prepared in hot-box technology can be characterized with stable thermal deformation up to the temperature of circa 320oC.

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Authors and Affiliations

A. Grabarczyk
K. Major-Gabryś
S.M. Dobosz
J. Jakubski
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Abstract

Modern techniques of castings production, including moulding sands production, require a strict technological regime and high quality

materials. In the case of self-hardening moulding sands with synthetic binders those requirements apply mainly to sand, which adds to

more than 98% of the whole moulding sand mixture. The factors that affect the quality of the moulding sands are both chemical (SiO2

,

Fe2O3 and carbonates content) and physical. Among these factors somewhat less attention is paid to the granulometric composition of the

sands. As a part of this study, the effect of sand quality on bending strength Rgu

and thermal deformation of self-hardening moulding sands

with furfural and alkyd resin was assessed. Moulding sands with furfural resin are known [1] to be the most susceptible to the sand quality.

A negative effect on its properties has, among others, high content of clay binder and so-called subgrains (fraction smaller than 0,1mm),

which can lead to neutralization of acidic hardeners (in the case of moulding sands with furfuryl resin) and also increase the specific

surface, what forces greater amount of binding agents. The research used 5 different quartz sands originating from different sources and

characterized with different grain composition and different clay binder content.

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Authors and Affiliations

St.M. Dobosz
A. Grabarczyk
J. Jakubski
K. Major-Gabryś
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Abstract

The paper presents possibility of using biodegradable materials as parts of moulding sands’ binders based on commonly used in foundry

practice resins. The authors focus on thermal destruction of binding materials and thermal deformation of moulding sands with tested

materials. All the research is conducted for the biodegradable material and two typical resins separately. The point of the article is to show

if tested materials are compatible from thermal destruction and thermal deformation points of view. It was proved that tested materials

characterized with similar thermal destruction but thermal deformation of moulding sands with those binders was different.

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Authors and Affiliations

St.M. Dobosz
J. Jakubski
K. Major-Gabryś
D. Drożyński
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Abstract

This paper presents a new perspective on the issue of reclamation of moulding and core sands. Taking as a premise that the reclamation process must remain on the surface of grains some not separated binding materials rests, it should be chosen the proper moulding sand’s composition that will be least harmful for the reclaim quality. There are two different moulding and core sands taken into examinations. The researches prove that a small correction of their compositions (hardener type) improves the quality of the received reclaims. Carried out in this article studies have shown that such an approach to the problem of reclamation of the moulding and core sands is needed and reasonable.

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Authors and Affiliations

S.M. Dobosz
K. Major-Gabryś
M. Hosadyna
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Abstract

Artificial neural networks are one of the modern methods of the production optimisation. An attempt to apply neural networks for controlling the quality of bentonite moulding sands is presented in this paper. This is the assessment method of sands suitability by means of detecting correlations between their individual parameters. The presented investigations were aimed at the selection of the neural network able to predict the active bentonite content in the moulding sand on the basis of this sand properties such as: permeability, compactibility and the compressive strength. Then, the data of selected parameters of new moulding sand were set to selected artificial neural network models. This was made to test the universality of the model in relation to other moulding sands. An application of the Statistica program allowed to select automatically the type of network proper for the representation of dependencies occurring in between the proposed moulding sand parameters. The most advantageous conditions were obtained for the uni-directional multi-layer perception (MLP) network. Knowledge of the neural network sensitivity to individual moulding sand parameters, allowed to eliminate not essential ones.
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Authors and Affiliations

St.M. Dobosz
J. Jakubski
K. Major-Gabryś
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Abstract

The constant growth of foundry modernization, mechanization and automation is followed with growing requirements for the quality and parameters of both moulding and core sands. Due to this changes it is necessary to widen the requirements for the parameters used for their quality evaluation by widening the testing of the moulding and core sands with the measurement of their resistance to mechanical deformation (further called elasticity). Following article covers measurements of this parameter in chosen moulding and core sands with different types of binders. It focuses on the differences in elasticity, bending strength and type of bond destruction (adhesive/cohesive) between different mixtures, and its connection to the applied bonding agent. Moulding and cores sands on which the most focus is placed on are primarily the self-hardening moulding sands with organic and inorganic binders, belonging to the group of universal applications (used as both moulding and core sands) and mixtures used in cold-box technology.

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Authors and Affiliations

St.M. Dobosz
A. Grabarczyk
K. Major-Gabryś
J. Kusiński
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Abstract

The ablation casting technology consists in pouring castings in single-use moulds made from the mixture of sand and watersoluble binder. After pouring the mould with liquid metal, while the casting is still solidifying, the mould destruction (washing out, erosion) takes place using a stream of cooling medium, which in this case is water. The following paper focuses on the selection of moulding sands with hydrated sodium silicate technologies for moulds devoted to the ablation casting of aluminum alloys. It has been proposed to use different types of moulding sands with a water-soluble binder, which is hydrated sodium silicate. The authors showed that the best kind of moulding sands for moulds for Al alloy casting will be moulding sands hardened with physical factors – through dehydration. The use of microwave hardened moulding sands and moulding sands made in hot-box technology has been proposed. The tests were carried out on moulding sands with different types of modified binder and various inorganic additives. The paper compares viscosity of different binders used in the research and thermal degradation of moulding sands with tested binders. The paper analyzes the influence of hardening time periods on bending strength of moulding sands with hydrated sodium silicate prepared in hot-box technology. The analysis of literature data and own research have shown that molding sand with hydrated sodium silicate hardened by dehydration is characterized by sufficient strength properties for the ablation foundry of Al alloys.

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Authors and Affiliations

K. Major-Gabryś
M. Hosadyna-Kondracka
A. Grabarczyk
J. Kamińska
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Abstract

The paper deals with the influence of manganese in AlSi7Mg0.3 alloy with higher iron content. Main aim is to eliminate harmful effect of intermetallic – iron based phases. Manganese in an alloy having an iron content of about 0.7 wt. % was graded at levels from 0.3 to 1.4 wt. %. In the paper, the effect of manganese is evaluated with respect to the resulting mechanical properties, also after the heat treatment (T6). Morphology of the excluded intermetallic phases and the character of the crystallisation of the alloy was also evaluated. From the obtained results it can be concluded that the increasing level of manganese in the alloy leads to an increase in the temperature of the β-Al5FeSi phase formation and therefore its elimination. Reducing the amount of β-Al5FeSi phase in the structure results in an improvement of the mechanical properties (observed at levels of 0.3 to 0.8 wt. % Mn). The highest addition of Mn (1.4 wt.%) leads to a decrease in the temperature corresponding to the formation of eutectic silicon, which has a positive influence on the structure, but at the same time the negative sludge particles were also present

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Authors and Affiliations

D. Bolibruchová
R. Podprocká
R. Pastirčák
K. Major-Gabryś
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Abstract

Main aim of submitted work is evaluation and experimental verification of inoculation effect on Al alloys hot-tear sensitivity. Submitted work consists of two parts. The first part introduces the reader to the hot tearing in general and provides theoretical analysis of hot tearing phenomenon. The second part describes strontium effect on hot tearing susceptibility, and gives the results on hot tearing for various aluminium alloys. During the test, the effect of alloy chemical composition on hot tearing susceptibility was also analyzed. Two different Al-based alloys were examined. Conclusions deals with effect of strontium on hot tearing susceptibility and confirms that main objective was achieved.

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Authors and Affiliations

D. Bolibruchová
M. Bruna
R. Pastirčák
K. Major-Gabryś
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Abstract

Due to the observed increase in the amount of waste in landfills, there has been an increase in the demand for products made of biomaterials and the composition of biomaterials with petroleum-derived materials. The problem of waste disposal/management also applies to waste from the casting production process with the use of disposable casting moulds made with the use of organic binders (resins), as well as residues from the process of regeneration of moulding sands. A perspective solution is to add a biodegradable component to the moulding/core sand. The authors proposed the use of polycaprolactone (PCL), a polymer from the group of aliphatic polyesters, as an additive to a casting resin commonly used in practice. As part of this study, the effect of PCL addition on the (bio) degradation of dust obtained after the process of mechanical regeneration of moulding sands with organic binders was determined. The (bio) degradation process was studied in the environment reflecting the actual environmental conditions. As part of the article, dust samples before and after the duration of the (bio) degradation process were tested for weight loss by thermogravimetry (TG) and for losses on ignition (LOI).
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Bibliography

[1] Bastian, K.C., Alleman, J.E. (1996). Environmental bioassay evaluation of foundry waste residuals. Joint Transportation Research Program Technical Report Series, Purdue University, Purdue e-Pubs.
[2] Brenner, V. (2003). Biodegradace persistentních xenobiotik. Biodegradace. VI, 2003, 45-47.
[3] Sobków, D., Barton, J., Czaja, K., Sudoł, M. & Mazoń, B. (2014). Research on the resistance of materials to environmental factors. CHEMIK. 68(4), 347–354. (in Polish).
[4] Stachurek I. (2010). Biomedical systems of polyethylene oxide biodegradable in the aquatic environment. PhD thesis, Politechnika Krakowska. (in Polish).
[5] Eastman, J. (2000). Protein-based binder update: performance put to the test. Modern Casting. 90, 32-34.
[6] Kramářová, D., Brandštetr, J., Rusín, K. & Henzlová, P. (2003). Biogenic polymeric materials as binders for foundry molds and cores. Slévárenství. 60(2-3), 71-73. (in Czech).
[7] Grabowska, B., Holtzer, M., Dańko, R., Górny, M., Bobrowski, A. & Olejnik, E. (2013). New bioco binders containing biopolymers for foundry industry. Metalurgija. 52(1), 47-50.
[8] Grabowska, B., Szucki, M., Suchy, J.Sz., Eichholz, S., Hodor, K. (2013). Thermal degradation behavior of cellulose-based material for gating systems in iron casting production. Polimery. 58(1), 39-44.
[9] Major-Gabryś, K. (2016). Environmentally Friendly Foundry Moulding and Core Sands. Katowice-Gliwice, Archives of Foundry Engineering, ISBN 978-83-63605-24-7 (in Polish)
[10] Major-Gabryś, K. (2019). Environmentally Friendly Foundry Molding and Core Sands. Journal of Materials Engineering and Performance. 28(7), 3905-3911.
[11] Holtzer, M. (2001). Management of waste and by-products in foundries. Kraków: University Scientific and Didactic Publishers, AGH, Poland. (in Polish).
[12] Skrzyński, M., Dańko, R. & Czapla, P. (2014). Regeneration of used moulding sand with furfuryl resin on a laboratory stand. Archives of Foundry Engineering. 14(spec.4), 111-114. (in Polish).
[13] Dańko, R., Łucarz, M. & Dańko, J. (2014). Mechanical and mechanical-thermal regeneration of the used core sand from the cold-box process. Archives of Foundry Engineering. 14(spec.4), 21-24. (in Polish).
[14] Rui, T., Liu, J. (2010). Study of modified furan resin binder system for large steel castings. In Proceedings of 69th World Foundry Congress, 16 - 20 October 2010. Hangzhou, China, World Foundry Organization (pp. 996 – 999).
[15] Dańko, R., Holtzer, M., Dańko, J. (2015). Characteristics of dust from mechanical reclamation of moulding sand with furan cold-setting resins – impact on environment. In Proceedings of the 2015 WFO International Forum on Moulding Materials and Casting Technologies, 25 – 28 September 2015. Changsha, China. WFO Moulding Materials Commission, Foundry Institution of Chinese Mechanical Engineering Society, Productivity Center of Foundry Industry of China (38-46).
[16] Iwamoto, A. & Tokiwa, Y. (1994). Enzymatic degradation of plastics containing polycaprolactone. Polymer Degradation and Stability. 45(2), 205-213.
[17] Eastmond, G.C. (2000). Poly(ε-caprolactone) blends. Advances in Polymer Science. 149, 59-222.
[18] Gutowska, A., Michniewicz, M., Ciechańska, D. & Szalczyńska, M. (2013). Methods of testing the biodegradability of biomass materials. CHEMIK. 67(10), 945-954. (in Polish).
[19] Major-Gabryś, K., Hosadyna-Kondracka, M., Skrzyński, M., Pastirčák, R. (2020). The quality of reclaim from moulding sand with furfuryl resin and PCL additive. The abstract paper at XXVI international conference of Polish, Czech and Slovak founders: 7-9.09.2020 r. Baranów Sandomierski, Poland.
[20] Major-Gabryś, K., Hosadyna-Kondracka, M. & Stachurek, I. (2020). Determination of mass loss in samples of post-regeneration dust from moulding sands with and without PCL subjected to biodegradation processes in a water environment. Journal of Applied Materials Engineering. 60(4), 121-129.
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Authors and Affiliations

K. Major-Gabryś
1
ORCID: ORCID
I. Stachurek
2
ORCID: ORCID
M. Hosadyna-Kondracka
2
ORCID: ORCID

  1. AGH University of Science and Technology, Faculty of Foundry Engineering, Mickiewicza 30, 30-059 Cracow, Poland
  2. ŁUKASIEWICZ Research Network - Foundry Research Institute, Zakopianska 73, 30-418 Cracow, Poland
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Abstract

Casting industry has been enriched with the processes of mechanization and automation in production. They offer both better working standards, faster and more accurate production, but also have begun to generate new opportunities for new foundry defects. This work discusses the disadvantages of processes that can occur, to a limited extend, in the technologies associated with mould assembly and during the initial stages of pouring. These defects will be described in detail in the further part of the paper and are mainly related to the quality of foundry cores, therefore the discussion of these issues will mainly concern core moulding sands. Four different types of moulding mixtures were used in the research, representing the most popular chemically bonded moulding sands used in foundry practise. The main focus of this article is the analysis of the influence of the binder type on mechanical and thermal deformation in moulding sands.

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Authors and Affiliations

A. Grabarczyk
K. Major-Gabryś
S.M. Dobosz
J. Jakubski
D. Bolibruchová
M. Bruna
R. Pastirčák
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Abstract

The essence of ablation casting technology consists in pouring castings in single-use moulds made from the mixture of sand and a watersoluble binder. After pouring the mould with liquid metal, while the casting is still solidifying, the mould destruction (washing out, erosion) takes place using a stream of cooling medium, which in this case is water. This paper focuses on the selection of moulding sands with hydrated sodium silicate for moulds used in the ablation casting. The research is based on the use of Cordis binder produced by the Hüttenes-Albertus Company. It is a new-generation inorganic binder based on hydrated sodium silicate. Its hardening takes place under the effect of high temperature. As part of the research, loose moulding mixtures based on the silica sand with different content of Cordis binder and special Anorgit additive were prepared. The reference material was sand mixture without the additive. The review of literature data and the results of own studies have shown that moulding sand with hydrated sodium silicate hardened by dehydration is characterized by sufficient strength properties to be used in the ablation casting process. Additionally, at the Foundry Research Institute in Krakow, preliminary semi-industrial tests were carried out on the use of Cordis sand technology in the manufacture of moulds for ablation casting. The possibility to use these sand mixtures has been confirmed in terms of both casting surface quality and sand reclamation.

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Authors and Affiliations

M. Hosadyna-Kondracka
K. Major-Gabryś
J. Kamińska
A. Grabarczyk
M. Angrecki

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