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Abstract

Recent advances in the construction of speed of sound meters made high-accuracy routine measurements possible in laboratories non-specialized in physical acoustics. Reliable values of the isentropic compressibility can be obtained from speeds of sound and densities of liquids using the Laplace formula. Strict thermodynamic relationships connect the isentropic compressibility of a medium and its density as a function of temperature and pressure with the heat capacity. These relationships result from the principles of thermodynamics and require no approximations or molecular models. In this study, the heat capacities of twelve liquids: hydrocarbons, acetonitrile, and ionic liquids were calculated from the speeds and densities taken from the literature sources. The agreement of the calculation results with the reference heat capacities, either critical values or measured calorimetrically, was satisfactory. The relative uncertainty of the calculated heat capacities was rather conservatively estimated for 5%. If the measurement procedures were optimized for heat capacity determination, better results would be attained, with the uncertainty probably smaller than 1%. Thus, the speed-and-density method is a potential alternative to classical calorimetry.
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Authors and Affiliations

Sylwia Szpaczek
1
Wojciech Marczak
1

  1. Faculty of Science and Technology, Jan Długosz University, Czestochowa, Poland
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Abstract

Blank handgun shots, party balloon bursts, and a pneumatic compressor with a small-diameter nozzle were used as sources of sound in the assessments of reverberation time, T. The two first sources were of impulse type, while the third one resembled a noise signal source. In this work, 532 values of T were experimentally obtained in four rooms of different volumes and compared. The T values for 1/3 octave frequency bands were found to be independent of the sound source. Reverberation times for the A-frequency-weighting filtered signals were close to one another for the shots and balloon bursts, while those obtained using the compressor nozzle were significantly shorter. The latter effect can be attributed to the relatively high share of high frequency waves in the sound generated by the nozzle. The results show that balloon bursts can be used as handgun shot substitutes in the assessments of reverberation times. While the nozzle noise is rather unsuitable for this purpose, it can be applied in the assessments of T for high frequency waves, up to the ultrasound range. Such acoustic climate information may be useful in designing spaces for high frequency sound-sensitive individuals, e.g. animal shelters.

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Authors and Affiliations

Piotr Szłapa
Marta Boroń
Jolanta Zachara
Wojciech Marczak

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