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Abstract

Secondary or multiple remelted alloys are common materials used in foundries. For secondary (recycled) Al-Si-Cu alloys, the major problem is the increased iron presence. Iron is the most common impurity and with presence of other elements in alloy creates the intermetallic compounds, which may negatively affect the structure. The paper deals with effect of multiple remelting on the microstructure of the AlS9iCu3 alloy with increased iron content to about 1.4 wt. %. The evaluation of the microstructure is focused on the morphology of iron-base intermetallic phases in caste state, after the heat treatment (T5) and after natural aging. The occurrence of the sludge phases was also observed. From the obtained results can be concluded that the multiple remelting leads to change of chemical composition, changes in the final microstructure and also increases sludge phases formation. The use of heat treatment T5 led to a positive change of microstructure, while the effect of natural aging is beneficial only to the 3rd remelting.

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Authors and Affiliations

M. Matejka
D. Bolibruchová
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Abstract

This article focuses on the study of the influence of remelting and subsequent natural and artificial ageing on the structure of recycled AlSi9Cu3 alloy with increased iron content. The assessed changes in eutectic silicon and iron-based intermetallic phases were carried out using optical and scanning electron microscopy. The degradation of the eutectic silicon morphology due to remelting occurred only at the highest numbers of remelting. The effect of remelting the investigated alloy, which is accompanied by a gradual increase in wt. % Fe, began to manifest significantly through a change in the length of the ferric phases after the fourth remelting. As expected, the artificial ageing process has proven to be more effective than natural ageing. It has led to a change in the eutectic silicon morphology and has been beneficial in reducing the lengths of adverse ferric phases. The use of alloys with higher numbers of remelting, or with greater “contamination”, for the manufacture of shape-challenging castings is possible when using a suitable method of eliminating the negative factors of the remelting process. The results of our investigation show a suitable method of the above elimination the application of heat treatment T5 – via artificial ageing.

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Authors and Affiliations

M. Matejka
D. Bolibruchová
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Abstract

The paper deals with influence of multiple remelting on AlSi9Cu3 alloy with higher iron content on chosen mechanical properties. Multiple remelting may in various ways influence mechanical, foundry properties, gas saturation, shrinkage cavity, fluidity etc. of alloy. Higher presence of iron in Al-Si cast alloys is common problem mainly in secondary (recycled) aluminium alloys. In Al-Si alloy the iron is the most common impurity and with presence of other elements in alloy creates the intermetallic compounds, which decreases mechanical properties. Iron in the used alloy was increased to about 1.4 wt. %, so that the influence of increased iron content can be investigated. In the paper, the effect of multiple remelting is evaluated with respect to the resulting mechanical properties in cast state, after the heat treatment (T5) and after natural aging. From the obtained results it can be concluded that the multiple remelting leads to change of chemical composition and affect the mechanical properties.
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Authors and Affiliations

M. Matejka
D. Bolibruchová
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Abstract

High-pressure die casting results in a high quality surface and good mechanical properties of castings. Under the effect of pressure, integral and solid castings are achieved without a large number of foundry defects. The correct and proper setting of technological parameters plays a very important role in minimizing casting defects. The aim of the presented article is to determine the optimum maximum piston velocity for a casting in the high-pressure casting process with two height variants, depending on their internal quality. It is because the internal quality of particular castings is important in terms of proper functionality in operations where the biggest problem is the porosity of the casting. The main cause of porosity formation is the decreasing solubility of gases (most often hydrogen) during the melt solidification. Solubility represents the maximum amount of gas that can dissolve in a metal under equilibrium conditions of temperature and pressure. Macroporosity and microporosity were determined from the sections of the surfaces in the determined zones of the castings. Here, the results was that the macroporosity decreased with increasing piston velocity. Ideal microstructure was evaluated at a piston velocity of 3 m/s for both types of castings. On the other hand, the increase in tube size has shown that velocities of 3 m/s and higher, the tube is more prone to macroporosity formation. The highest hardness was achieved at the piston velocity of 2 m/s at both tube lengths.
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Authors and Affiliations

M. Matejka
1
ORCID: ORCID
D. Bolibruchová
1
ORCID: ORCID
R. Podprocká
2

  1. University of Zilina, Faculty of Mechanical Engineering, Department of Technological Engineering, Slovak Republic
  2. Rosenberg-Slovakia s.r.o., Slovak Republic
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Abstract

The technology of high-pressure die-casting (HPDC) of aluminum alloys is one of the most used and most economical technology for mass production of castings. High-pressure die-casting technology is characterized by the production of complex, thin-walled and dimensionally accurate castings. An important role is placed on the effective reduction of costs in the production process, wherein the combination with the technology of high-pressure die-casting is the possibility of recycling using returnable material. The experimental part of the paper focuses on the analysis of a gradual increase of the returnable material amount in combination with a commercial purity alloy for the production of high-pressure die-castings. The returnable material consisted of the so-called foundry waste (defective castings, venting and gating systems, etc.). The first step of the experimental castings evaluation consisted of numerical simulations, performed to determine the points of the casting, where porosity occurs. In the next step, the evaluation of areal porosity and microstructural analysis was performed on experimental castings with different amounts of returnable material in the batch. The evaluation of the area porosity showed only a small effect of the increased amount of the returnable material in the batch, where the worst results were obtained by the casting of the alloy with 90% but also with 55% of the returnable material in the batch. The microstructure analysis showed that the increase in returnable material in the batch was visibly manifested only by a change in the morphology of the eutectic Si.
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Bibliography

[1] Ragan, E. (2007). Die casting of metals. Prešov, Slovakia. (in Slovak).
[2] Eperješi, Ľ., Malik, J., Eperješi Š. & Fecko D. (2013) Influence of returning material on porosity of die castings. Manufacturing Technology. 13(1), 36-39. DOI: 10.21062/ujep/x.2013/a/1213-2489/MT/13/1/36.
[3] Gaustad, G., Olivetti, E. A. & Kirchain, R. (2012). Improving aluminum recycling: A survey of sorting and impurity removal technologies. Resources Conservation and Recycling. 58, 79-87.
[4] Matejka, M., Bolibruchová, D. & Kuriš, M. (2021). Crystallization of the structural components of multiple remelted AlSi9Cu3 alloy. Archives of Foundry Engineering. 21(2), 41-45. DOI: 10.24425/afe.2021.136096.
[5] Bruna, M., Remišová, A. & Sládek, A. (2019). Effect of filter thickness on reoxidation and mechanical properties of aluminium alloy AlSi7Mg0.3. Archives of Metallurgy and Materials. 3, 1100-1106. DOI: 10.24425/amm.2019.129500.
[6] Bryksi Stunova, B. & Bryksi, V. (2016). Analysis of defects in castings cast by rheocasting method SEED. Archives of Foundry Engineering. 16(3), 15-18. DOI: 10.1515/afe-2016-0041.
[7] Podprocká, R. & Bolibruchová, D. (2017). Iron intermetallic phases in the alloy based on Al-Si-Mg by applying manganese. Archives of Foundry Engineering. 17(3), 217-221. DOI: 10.24425/afe.2020.133321.
[8] Martinec, D., Pastircak, R. & Kantorikova, E. (2020). Using of technology semisolid squeeze casting by different initial states of material. Archives of Foundry Engineering. 20(1), 117-121. DOI: 10.24425/afe.2020.131292.
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Authors and Affiliations

M. Matejka
1
ORCID: ORCID
D. Bolibruchová
1
ORCID: ORCID
R. Podprocká
2

  1. University of Zilina, Faculty of Mechanical Engineering, Department of Technological Engineering, Univerzitna 1, 010 26 Zilina, Slovak Republic
  2. Rosenberg-Slovakia s.r.o., Kováčska 38, 044 25 Medzev, Slovak Republic
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Abstract

The article focuses on the analysis of the effect of Zr on the properties of the aluminium alloy AlSi9Cu1Mg. The effect of Zr was evaluated depending on the change in mechanical properties and heat resistance during a gradual addition of Zr with an increase of 0.05 wt. % Zr. Half of the cast experimental samples from each variant were heat treated by precipitation hardening T6 (hereinafter HT). The measured values in both states indicate an improvement of the mechanical properties, especially in the experimental variants with a content of Zr ≥ 0.20 wt. %. In the evaluation of Rm, the most significant improvement occurred in the experimental variant with an addition of Zr 0.25 wt. % after HT and E in the experimental variant with addition of Zr 0.20 wt. % after HT. Thus, a difference was found from the results of the authors defining the positive effect of Zr, in particular at 0.15 wt. %. When evaluating the microstructure of the AlSi9Cu1Mg alloy after Zr alloying, Zr phases are already eliminated with the addition of Zr 0.10 wt. %. Especially at higher levels of Zr ≥ 0.20 wt. %, long needle phases with slightly cleaved morphology are visible in the metal matrix. It can be stated that a negative manifestation of Zr alloying is expressed by an increase in gassing of experimental alloys, especially in variants with a content of Zr ≥ 0.15 wt. %. Experimental samples were cast into ceramic moulds. The development of an experimental alloy AlSi9Cu1Mg alloyed with Zr would allow the production of a more sophisticated material applicable to thin-walled Al castings capable of operating at higher temperature loads.

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Authors and Affiliations

M. Matejka
ORCID: ORCID
M. Kuriš
D. Bolibruchova
R. Pastirčák
ORCID: ORCID
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Abstract

Monitoring the solidification process is of great importance for understanding the quality of the melt, for controlling it, and for predicting the true properties of the alloy. Solidification is accompanied by the development of heat, the magnitude of which depends on the different phases occurring during solidification. Thermal analysis is now an important part of and tool for quality control, especially when using secondary aluminium alloys in the automotive industry. The effect of remelting on the change of crystallization of individual structural components of experimental AlSi9Cu3 alloy was determined by evaluation of cooling curves and their first derivatives. Structural analysis was evaluated using a scanning electron microscope. The effect of remelting was manifested especially in nucleation of phases rich in iron and copper. An increasing number of remelts had a negative effect after the fourth remelting, when harmful iron phases appeared in the structure in much larger dimensions.

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Authors and Affiliations

M. Matejka
ORCID: ORCID
D. Bolibruchova
Justyna Kasińska
ORCID: ORCID
M. Kuriš
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Abstract

At present, Al-Si-Cu based alloys (with a typical representative AlSi9Cu3 alloy) represent more than half of the castings used in various industries (automotive, aerospace and electrical engineering). These are most often sub-eutectic (exceptionally eutectic) alloys with a content of 6 to 13 wt. % Si and 1 to 5 wt. % Cu. The aim of the paper is to point out the importance of the evaluation of input raw materials that determines the overall properties of the casting and the costs invested in its production. A negative impact on performance can be expected when using an alloy made up of a high proportion of recycled material, despite its economic benefits. Experimental alloys were evaluated based on the results of crystallization process and a combination of scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), and deep etching. The effect of remelting and increasing the remelted returnable material in the batch was manifested especially in the crystallization of iron-rich phases. The negative effect of remelting on the structural components was manifested after the fourth remelting. Gradual increase of remelted returnable material in the batch causes harmful changes in the crystallization process.
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Bibliography

[1] Ciu, J. & Roven, H.J. (2010). Recycling of automotive aluminum. Transactions of Nonferrous Metals Society of China. 20, 2057-2063.
[2] Gaustad, G., Olivetti, E.A. & Kirchain, R. (2012). Improving aluminum recycling: A survey of sorting and impurity removal technologies. Resources Conservation and Recycling. 58, 79-87.
[3] Kasińska, J., Bolibruchová, D. & Matejka, M. (2020). The influence of remelting on the properties of AlSi9Cu3 alloy with higher iron content. Materials. 13, 575.
[4] Das, K.S. & Green, J.A.S. (2010). Aluminum Industry and Climate Change-Assessment and Responses. JOM: The Journal of The Minerals, Metals & Materials Society. 62, 27-31.
[5] Winczek, J., Gucwa, M., Mician, M. et al. (2019). The evaluation of the wear mechanism of high-carbon hardfacing layers. Archives of Metallurgy and Materials. 64 (3), 1111-1115
[6] Medlen, D. & Bolibruchová, D. (2012). The influence of remelting on the properties of AlSi6Cu4 alloy modified by antimony. Archives of Foundry Engineering. 12(1), 81-86.
[7] Martinec, D., Pastircak, R. & Kantorikova, E. (2020). Using of Technology Semisolid Squeeze Casting by Different Initial States of Material. Archives of Foundry Engineering. 20(1), 117-121.
[8] Campbell, J. (2011). Complete Casting Handbook: Metal Casting Processes, Metallurgy, Techniques and Design. Butterworth-Heinemann, Oxford, UK.
[9] Djurdjevic, M.B., Odanovic, Z. & Talijan, N. (2011). Characterization of the Solidification Path of AlSi5Cu (1-4 wt.%) Alloys Using Cooling Curve Analysis. JOM: The Journal of The Minerals, Metals & Materials Society. 63,11, 51-57.
[10] Lukač, I. (1981). Properties and structure of non-ferrous metals. ALFA Bratislava. (in Slovak).
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Authors and Affiliations

M. Matejka
1
ORCID: ORCID
D. Bolibruchová
1
ORCID: ORCID
M. Kuriš
1

  1. University of Zilina, Faculty of Mechanical Engineering, Department of Technological Engineering, Univerzitna 1, 010 26 Zilina, Slovak Republic
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Abstract

The article focused primarily on comparing the achieved mechanical results for AlSi7Mg0.3Cu0.5Zr and AlSi7Mg0.3Cu0.5Zr0.15Ti experimental alloys. Experimental variants with the addition of Zr ≥ 0.05 wt. % demonstrated the ability of Zr to precipitate in the form of Al3Zr or AlSiZr intermetallic phases. Zr precipitated in the form of long smooth needles with split ends. When evaluating the thermal analyses, the repeated peak was observed already with the initial addition of Zr in the range of approximately 630 °C. It was interesting to observe the increased interaction with other intermetallic phases. EDX analysis confirmed that the individual phases are based on Cu, Mg but also Fe. Similar phenomena were observed in experimental alloys with a constant addition of Zr and a gradual increase in Ti by 0.1 wt. %. A significant change occurred in the amount of precipitated Zr phases. A more significant increase in mechanical properties after heat treatment of AlSi7Mg0.3Cu0.5Zr experimental alloys was observed mainly above the Zr content ≥ 0.15 wt. % Zr. The improvement of yield and tensile strength over the AlSi7Mg0.3Cu0.5 reference alloy after heat treatment was minimal, not exceeding 1 %. A more significant improvement after heat treatment occurred in modulus of elongation with an increase by 6 %, and in hardness with an increase by 7 %. The most significant drop occurred in ductility where a decrease by 31 % was observed compared to the reference alloy. AlSi7Mg0.3Cu0.5Zr0.15Ti experimental alloys, characterized by varying Ti content, achieved a more significant improvement. The improvement in tensile strength over the AlSi7Mg0.3Cu0.5 reference alloy after heat treatment was minimal, not exceeding 1 %. A more significant improvement after heat treatment occurred in modulus of elongation with an increase by 12 %, in hardness with an increase by 12 % and the most significant improvement occurred in yield strengthwith a value of 18 %. The most significant decrease also occurred in ductility where, compared to the reference alloy, the ductility drop was by up to 67 %.
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Bibliography

[1] Vončina, M., Medved, J., Kores, S., Xie, P., Cziegler, A. & Schumacher, P. (2018). Effect of molybdenum an zirconium on aluminium casting alloys. Livarski Vestnik. 68-78.
[2] Medved, J. & Kores, M.V.S. (2018). Development of innovative Al-Si-Mn-Mg alloys with hight mechanical properties. The Minerals, Metals & Materials Society. 373-380. DOI 10.1007/978-3-319-72284-9_50.
[3] Pisarek, B.P., Rapiejko, C., Szymczak, T. & Payniak, T. (2017). Effect of Alloy Additions on the Structure and Mechanical Properties of the AlSi7Mg0.3 Alloy. Archives of Foundry Engineering. 17(1),137-142. ISSN: 1897-3310.
[4] Mahmudi, R., Sepehrband, P. & Ghasemi, H.M. (2006). Improve properties of A319 aluminium casting alloy modified with Zr. Materials Letters. 2606-2610. DOI: 10.1016/j.matlet.2006.01.046
[5] Sepehrband, P., Mahmudi, R., Khomamizadeh, F. (2004). Effect of Zr addition on the aging behavior of A319 aluminium cast alloy. Scripta Materialia. 253-257. DOI: 10.1016/j.scriptamat.2004.10.025
[6] Rakhmonov, J., Timelli, G. & Bonollo, F. (2017) Characterization of the solidification path and microstructure of secondary Al-7Si-3Cu-0,3Mg alloy with Zr, V and Ni additions. Material characterization. ISSN:1044-5803.
[7] Krajewski, W., Geer, A., Buraś, J., Piwowarski, G. & Krajewski, P. (2019). New developments of hight-zinc Al-Zn-Cu-Mn cast alloys. Materialstoday Proceedings. 306-311. DOI: 10.1016/j.matpr.2018.10.410.
[8] Hermandez-Sandoval, J., Samuel, A.M. & Vatierra, F.H. (2016). Thermal analysis for detection of Zr-rich phases in Al-Si-Cu-Mg 354-type alloys. Journal of metalcasting. ISSN 1939-5981.
[9] Bolibruchova, D., Kuriš, M., Matejka, M., Major Gabryś, K., Vicen, M., (2020) Effect of Ti on selected properties of AlSi7Mg0.3Cu0.5 alloy with constant addition of Zr. Archives of Metalurgy and Materials. 66(1), 65-72. DOI: 10.24425/amm.2021.134760.

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Authors and Affiliations

M. Kuriš
1
D. Bolibruchova
1
M. Matejka
1
ORCID: ORCID
E. Kantoríková
1
ORCID: ORCID

  1. University of Zilina, Faculty of Mechanical Engineering, Department of Technological Engineering, Univerzitna 1, 010 26 Zilina, Slovak Republic
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Abstract

Recycling of aluminium returnable material through its reuse is now an essential component of the production of aluminium alloy castings. The main goal is to find a suitable ratio of the primary alloy and the returnable material in the batch, thus determining the right compromise between the price and the quality of the casting. Experimental alloys were evaluated by thermal analysis, combination of structural analytical techniques and selected mechanical properties. The alloys were also subjected to tearing susceptibility testing. The increase in the returnable material amount resulted in changes in the alloy properties at the first increase in volume to 20%. After exceeding the balanced ratio (50:50), there was considerable degradation of the microstructure, failure to achieve the minimum values of some mechanical properties required by the standard, and the alloy showed increased susceptibility to tearing.

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Authors and Affiliations

M. Matejka
ORCID: ORCID
D. Bolibruchová
ORCID: ORCID
M. Chalupová
ORCID: ORCID
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Abstract

The current trend of continuous improvement of various components constantly pushes the development of new materials forward. The basic goal of research into new and better materials is to improve their properties compared to the original material. One of the essential properties of the newly developed aluminum alloys is their resistance to the formation of tearing. Tears appear during the solidification of the casting and break the integrity due to tension arising while cooling. Several factors influence the susceptibility to tearing, but they can be minimized and reduce the chance of their occurrence. As part of the experiment, the AlSi5Cu2Mg alloy was evaluated in four material variants, without additives (in the reference state), with the addition of transition elements Zr, Ti and their combination Zr + Ti. Susceptibility to the formation of teras was assessed using a qualitative method supplemented by microscopic analysis of the tear profile and determination of the dendritic coherence temperature. The evaluation shows that the addition of Zr increased the susceptibility to tear formation. On the contrary, the addition of Ti had a positive effect and reduced the susceptibility to the formation of tears. The effect of the addition of Zr and Ti in the AlSi5Cu2Mg alloy showed a similar values as without the addition of alloys (reference condition). Microstructural analysis of the tear profile pointed to the negative influence of phases rich in Zr. The subsequent evaluation of the dendritic coherence temperature of individual AlSi5Cu2Mg alloys did not show a correlation with the results of a quantitative evaluation of susceptibility to tears.
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Bibliography

[1] Bolibruchová, D. (2010). Foundry technology. Žilina: vydavateľstvo GEORG, ISBN 978-80-89401-14-7.
[2] Pastirčák, R., Bolibruchová, D., Sládek, A. (2015). Foundry theory. Žilina: EDIS-vydavateľské centrum ŽU, ISBN 978-80-554-1096-8.
[3] Wu, Q., (2012). Study of Hot Tearing in Cast and Wrought Aluminum Alloys. Dissertation thesis. Worchester: Faculty of the Worcester polytechnic institute, UK.
[4] Bruna, M. & Galčík, M. (2021). Casting Quality Improvement by Gating System Optimization. Archives of Foundry Engineering. 21(1). 132-136. DOI:10.24425/afe.2021.136089.
[5] Huang, H., Fu, P, Wang, Y., Peng, L. & Jiang, H. (2014). Effect of pouring and mold temperatures on hot tearing susceptibility of AZ91D and Mg–3Nd–0.2Zn–Zr Mg alloys. Transactions of Nonferrous Metals Society of China. 24(4), 922-929. DOI:10.1016/S1003-6326(14)63144-7.
[6] Campbell, J. (2015). Complete casting handbook: metal casting processes, metallurgy, techniques and design. Elsevier Science.
[7] Oh, S.H., A.H., Munkhdelger, Ch. & Kim, H.J. (2021). Effect of Cu content on hot tearing susceptibility in al-si-cu aluminum casting alloy. Journal of Korea Foundry Society. 41(5), 419-433.
[8] Bichler, L., Elsayed, A., Lee, K. & Ravindran, C. (2008). Influence of mold and pouring temperatures on hot tearing susceptibility of AZ91D magnesium alloy. International Journal of Metalcasting. 2, 43-54. DOI:10.1007/BF03355421.
[9] Hasan, A. & Suyitno, A. (2014). Effect pouring temperature on casting defect susceptibility of hot tearing in metal alloy Al-Si. Applied Mechanics and Materials. 758, 95-99. https://doi.org/10.4028/www.scientific.net/AMM.758.95.
[10] Djurdjevic, M.B. Sokolowski, J.H. & Odanovic Z. (2012). Determination of dendrite coherency point characteristics using first derivative curve versus temperature. Journal of Thermal Analysis and Calorimetry volume. 109(2), 875-882. https://doi.org/10.1007/s10973-012-2490-4.
[11] Gómez, I. V., Viteri, E. V. Montero, J., Djurdjevic, M. & Huber, G. (2018). The determination of dendrite coherency point characteristics using three new methods for aluminum alloys. Applied Sciences. 8(8), 1236, 1-14. https://doi.org/10.3390/app8081236.
[12] Bolibruchová, D., Širanec, L. & Matejka, M. (2022). Selected properties of a Zr-containing AlSi5Cu2Mg alloy intended for cylinder head castings. Materials. 15(14), 4798, 1-16. https://doi.org/10.3390/ma15144798
[13] Bolibruchová, D., Kuriš, M., Matejka, M. & Kasińska, J. (2022). Study of the influence of zirconium, titanium and strontium on the properties and microstructure of AlSi7Mg0.3Cu0.5 alloy. Materials. 15(10), 3709, 1-20. https://doi.org/10.3390/ma15103709.
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Authors and Affiliations

M. Matejka
1
ORCID: ORCID
D. Bolibruchová
1
ORCID: ORCID
E. Kantoríková
1
ORCID: ORCID

  1. University of Zilina, Faculty of Mechanical Engineering, Department of Technological Engineering, Slovak Republic
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Abstract

The article is focused on the synergic effect of constant content of Zr and higher content of Ti on mechanical properties Al-Si alloy. The Ti additions were in proportions of 0.1, 0.2 and 0.3 wt.% Ti. The casting process was carried out in ceramic molds, created for the investment casting technology. Half of the experimental samples were processed by precipitation curing T6. The measured results were compared with primary alloy AlSi7Mg0,3 and experimental alloy AlSi7Mg0.3Cu0.5Zr0.15. In variant with addition 0.1 wt. %, the tensile strength Rm increased by 1,5% but the elongation AM decreased to 40%. Variants with 0.2 and 0.3 wt. % addition of Ti achieved similar Rm but approximately 40% decrease in AM. However, it is interesting that yield strength Rp0.2 increased for all variants by approximately 14 to 20%. The results point out the possibility of developing a more sophisticated alloy for automotive industry.

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Authors and Affiliations

D. Bolibruchová
ORCID: ORCID
M. Kuriš
M. Matejka
ORCID: ORCID
K. Major-Gabryś
ORCID: ORCID
M. Vicen

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