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Abstract

The use of organically modified clays as nano-reinforcement in polymer matrices is widely investigated owing to their remarkable reinforcement at low filler loading. In this body of work, the nanocomposites were prepared by melt blending nanoclay with polyamide 11 (PA 11) utilising a twin-screw extruder in order to maximise the dispersion of clay particles within the matrix during compounding. The main aim of the work was to study the reinforcing effect of nanoclay within PA 11 using two micromechanical model namely Halpin-Tsai and Mori-Tanaka composite theories. These theories were used to predict the effective tensile modulus of PA 11 nanocomposites and the results were compared to the experimental data. In addition, the Halpin-Tsai model was used to predict the storage modulus and heat distortion temperature (HDT) of PA 11 nanocomposites. It was found that the tensile modulus for nanocomposites with a high clay aspect ratio exhibits up to 10% higher when compared to the nanocomposites with lower clay aspect ratio. Thus, it is believed that the combination of clay aspect ratio and modulus contributes to the super reinforcing effect of nanoclay within the PA 11 matrix.
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Authors and Affiliations

Khairul Anwar Abdul Halim
1 2
ORCID: ORCID
James E. Kennedy
3
ORCID: ORCID
Mohd Arif Anuar Mohd Salleh
1 2
ORCID: ORCID
Azlin Fazlina Osman
1 2
ORCID: ORCID
Mohd Firdaus Omar
1 2
ORCID: ORCID
N.M. Sunar
4
ORCID: ORCID

  1. Universiti Malaysia Perlis, Centre of Excellence Geopolymer and Green Technology (CEGeoGTech), 01000 Perlis, Malaysia
  2. Universiti Malaysia Perlis, Faculty of Chemical Engineering and Technology, Kompleks Pusat Pengajian Jejawi 3, Kawasan Perindustrian Jejawi, 02600, Arau, Perlis, Malaysia
  3. Athlone Institute of Technology, Dublin Road, Co. Westmeath , Ireland
  4. Universiti Tun Hussein Onn Malaysia, Research Centre for Soft Soil (RECESS), Institute of Integrate d Engineering, 86400 Parit Raja, Johor, Malaysia

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