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Abstract

The aim of this study is to demonstrate the possibility of using moulds made from the environmentally friendly sands with hydrated sodium silicate in modified ablation casting. The ablation casting technology is primarily intended for castings with diversified wall thickness and complex shapes made in sand moulds. The article presents the effect of binder content and hardening time on the bending strength Rg u of moulding sands with binders based on hydrated sodium silicate hardened by microwave technology. The aim of the research was to develop an optimal sand composition that would provide the strength necessary to make a mould capable of withstanding the modified ablation casting process. At the same time, the sand composition should guarantee the susceptibility of the mould to the destructive action of the ablation medium, which in this case is water. Tests have shown that microwave hardening provides satisfactory moulds’ strength properties even at a low binder content in the sand mixture.

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Authors and Affiliations

S. Puzio
J. Kamińska
K. Major-Gabryś
M. Angrecki
M. Hosadyna-Kondracka
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Abstract

Bentonites and clays are included in the group of drilling fluids materials. The raw materials are mainly clay minerals, which are divided into several groups, like montmorillonite, kaolinite, illite, biotite, muscovite, nontronite, anorthoclase, microcline, sanidine or rutile, differing in chemical composition and crystal lattice structure. Clay minerals have a layered structure forming sheet units. The layers merge into sheets that build up to form the structure of the mineral.

The aim of the studies carried out in the ŁUKASIEWICZ Research Network - Foundry Research Institute is to explore the possibility of using minerals coming from Polish deposits.

The article outlines the basic properties of hybrid bentonites, which are a mixture of bentonite clay called beidellite, originating from overburden deposits of the Turoszów Mine, and foundry bentonite from one of the Slovak deposits. As part of the physico-chemical tests of minerals, measurements included in the PN-85/H-11003 standard, i.e. montmorillonite content, water content and swelling index, were carried out. Additionally, the loss on ignition and pH chemical reaction were determined. Based on the thermal analysis of raw materials, carried out in the temperature range from 0 to 1000oC, changes occurring in these materials during heating, i.e. thermal stability in contact with liquid metal, were determined.

Examinations of the sand mixture based on pure clay and bentonite and of the sand mixture based on hybrid bentonites enabled tracing changes in permeability, compressive strength and tensile strength in the transformation zone as well as compactability referred to the clay content in sand mixture. Selected technological and strength parameters of synthetic sands are crucial for the foundry, because they significantly affect the quality of the finished casting.

Based on the analysis of the results, the optimal composition of hybrid bentonite was selected.

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Authors and Affiliations

J. Kamińska
ORCID: ORCID
S. Puzio
ORCID: ORCID
M. Angrecki
ORCID: ORCID
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Abstract

Increasing demands are imposed on foundries to enforce the manufacture of castings characterized by tight dimensional tolerances, high surface finish and total absence of casting defects. To face these challenges, castings are increasingly made in loose self-hardening sands with furfuryl resin, commonly known as furan sands. In the group of self-hardening sands with synthetic resins, loose self-hardening sands with furfuryl resin enjoy the greatest popularity. The sand mixtures based on furan resins are usually subjected to mechanical reclamation. The consumption of binder and hardener and thus the cost of the sand depend on the quality of reclaim, and mainly on the dust removal degree.

The planned tightening of the environmental protection regulations in the EU countries, including limiting the content of free furfuryl alcohol in resins and reducing the emission of furfuryl alcohol, formaldehyde and BTEX compounds at workplaces, necessitated the development of a new generation of eco-friendly furfuryl resins that have recently appeared on the market.

The main aim of this article was to determine the effect of reclaim content on the sand parameters, such as bending strength, tensile strength, bench life, gas-forming tendency and loss on ignition. Tests were carried out with reclaim content in the sand mixture varying from 50 to 90%. The reclaim obtained by dry mechanical reclamation was supplied by one of the domestic foundries.

The results showed that the highest mechanical properties were obtained in sands containing 60% of the reclaim.

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Authors and Affiliations

J. Kamińska
ORCID: ORCID
S. Puzio
ORCID: ORCID
M. Angrecki
ORCID: ORCID
A. Łoś
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Abstract

The aim of the research was to determine the effect of the primary quality of reclaim from dry mechanical reclamation on the strength properties and service life of moulding sands based on this reclaim. Another aim was to establish the effect of the quality of reclaim, sulphur content - in particular, on the surface quality and thickness of the deformed surface layer in ductile iron castings. The research has revealed differences in the strength parameters and service life (mouldability) of sands based on the tested reclaims, depending on the type of the furfuryl resin used, including resins whose synthesis was done as part of the Żywfur project. Examinations of the structure of the surface layer of test castings poured in moulds made of loose self-hardening sands containing the addition of reclaim have confirmed the occurrence of degenerated spheroidal graphite in this part of the casting. It should be noted here that when massive castings with a long solidification time are made, the graphite degeneration effect can be more visible and the layer with the changed structure can increase in thickness. The research has clearly shown that it is necessary to control the parameters of the reclaim, including sulphur content which is transferred from the hardener and accumulates on the grains. This phenomenon has a negative impact not only on the sand strength and technological properties but also on the surface layer of castings.
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Bibliography

[1] Lewandowski, J.L. (1997). Materials for foundry moulds. Kraków: WN Akapit. ISBN: 83-7108-21-2 (in Polish).
[2] Kamińska, J., Puzio, S., Angrecki, M., Stachowicz, M. & Łoś, A. (2019). Preliminary tests of innovative eco-friendly furfuryl resins and foundry sand mixtures based on these resins. Journal of Ecological Engineering. 20(9), 285-292, DOI: 10.12911/22998993/112510.
[3] Acharya, S.G., Vadher, J.A. & Kanjariya, P.V. (2016). Identification and quantification of gases releasing from furan no bake binder. Archives of Foundry Engineering. 16(3), 5-10. DOI: 10.1515/afe-2016-0039.
[4] Chate, G.R., Patel, GC M., Deshpande, A.S. & Parappagoudar, M.B. (2018). Modeling and optimization of furan moulding sand system using design of experiments and particle swarm optimization. Journal of Process Mechanical Engineering. 232(5), 1-20. DOI: 10.1177/0954408917728636.
[5] Sappinen, T., Orkas, J. & Konqvist, T. (2018). Thermal Reclamation of Foundry Sands Using Repurposed Sand Dryer Equipment. Archives of Foundry Engineering. 18(4), 99-102. DOI: 10.24425/afe.2018.125176.
[6] Kamińska, J., Puzio, S., Angrecki, M. & Łoś, A. (2020). Effect of reclaim addition on the mechanical and technological properties of moulding sands based on pro-ecological furfuryl resin. Archives of Metallurgy and Materials. 65(4), 1425-1429. DOI: 10.24425/amm.2020.133709.
[7] Yan-lei, L., Guo-hua, W., Wen-cai, L., An-tao, C., Liang, Z. & Ying-xin Wang, W. (2017). Effect of reclaimed sand additions on mechanical properties and fracture behavior of furan no-bake resin sand. China Foundry. 14(2), 128-137. DOI: 10.1007/s41230-017-6024-3.
[8] Holtzer, M., Dańko, R., Kmita, A., Drożyński, D., Kubecki, M., Skrzyński, M. & Roczniak, A. (2020). Environmental impact of the reclaimed sand addition to moulding sand with furan and phenol-formaldehyde resin—A comparison, Materials. 13(19), 4395; DOI: https://doi.org/10.3390/ma13194395.
[9] Holtzer, M., Dańko, R. & Kmita, A. (2016). Influence of a reclaimed sand addition to moulding sand with furan resin on its impact on the environment. Water Air and Soil Pollution. 227(16), 1-12. DOI: 10.1007/s11270-015-2707-9.
[10] Hosadyna, M. (2012). The effect of sulphur contained in self-hardening moulding sands on the structure of surface layer in ductile iron castings. Doctoral dissertation, Kraków. (in Polish).
[11] Holtzer, M., Zych, J. & Retel, K. (1996). The effect of mould-liquid cast iron interaction on the surface quality of castings. Przegląd Odlewnictwa. 6(1996), 129-134. (in Polish).
[12] Riposan, I., Chisamera, M., Stan, S., Skaland, T. (2008). Surface graphite degeneration in ductile iron castings for resin molds. Tsinghua Science and Technology. 13(2), 157-163.
[13] Linke, T., Sluis, J.R. (1993). The influence of coatings on the graphite structure in the rim-zone of ductile iron castings. 60th World Foundry Congress, The Netherlands
[14] Hosadyna, M., Dobosz, St.M. & Jelinek, P. (2009). The diffusion of sulphur from moulding sand to cast and methods of its elimination. Archives of Foundry Engineering. 9(4), 73-76.
[15] Sheladiya, M.V., Acharya, S.G., Mehta, K., Acharya, G.D. (2019). Evaluate sulphur diffusion at mould-metal interface in no-bake mould system. Archives of Foundry Engineering. 19(1), 63-70. DOI: 10.24425/afe.2018.125193.
[16] Anca, D., Stan, I., Chisamera, M., Riposan, I. & Stan, S. (2021). Experimental study regarding the possibility of blocking the diffusion of sulfur at casting-mold interface in ductile iron castings. Coatings. 11(673), 1-10. DOI: https://doi.org/10.3390/coatings11060673.
[17] Dańko, J., Dańko, R. & Łucarz, M. (2007). Processes and devices for the matrix regeneration of spent molding sands. Kraków: WN Akapit. ISBN: 978-83-89541-88-8 (in Polish).
[18] Holtzer, M., Bobrowski, A., Drożyński, D., Isendorf, B., Mazur, (2012). Influence of the reclaim on the properties of moulding sands with furfuryl resin applied for moulds for manganese steel castings. Archives of Foundry Engineering. 12(1), 57-62.
[19] Dańko, R., Górny, M., Holtzer, M., Żymankowska-Kumon, S. (2014). Effect of the quality of furan moulding sand on the skin layer of ductile iron castings. ISIJ International. 54(6), 1288-1293. DOI: https://doi.org/10.2355/isijinternational.54.1288.
[20] Pałyga, Ł., Stachowicz, M., Granat, K. (2015). Evaluation of 2D and 3D surface roughness of die castings from alloy AlSi9Cu3. Archives of Foundry Engineering. 15(1), 75-80.

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Authors and Affiliations

J. Kamińska
1
ORCID: ORCID
M. Angrecki
1
ORCID: ORCID
S. Puzio
1
ORCID: ORCID
M. Stachowicz
2
ORCID: ORCID

  1. Łukasiewicz Research Network – Krakow Institute of Technology, Poland
  2. Wroclaw University of Technology, Faculty of Mechanical Engineering, Poland
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Abstract

The possibilities of using an inorganic phosphate binder for the ablation casting technology are discussed in this paper. This kind of binder was selected for the process due to its inorganic character and water-solubility. Test castings were made in the sand mixture containing this binder. Each time during the pouring liquid alloy into the molds and solidification process of castings, the temperature in the mold was examined. Then the properties of the obtained castings were compared to the properties of the castings solidifying at ambient temperature in similar sand and metal molds. Post-process materials were also examined - quartz matrix and water. It has been demonstrated that ablation casting technology promotes refining of the microstructure, and thus upgrades the mechanical properties of castings (Rm was raised about approx. 20%). Properties of these castings are comparable to the castings poured in metal moulds. However, the post-process water does not meet the requirements of ecology, which significantly reduces the possibility of its cheap disposal.
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Bibliography


[1] Puzio, S., Kamińska, J., Angrecki, M. & Major-Gabryś, K. (2020). The Influence of Inorganic Binder Type on Properties of Self-Hardening Moulding Sands Intended for the Ablation Casting Process. Journal of Applied Materials Engineering. 60(4), 99-108.
[2] United States Patent No. US 7,159,642 B2.
[3] Dudek, P., Fajkiel, A., Reguła, T. & Bochenek, J. (2014). Research on the ablation casting technology of aluminum alloys. Prace Instytutu Odlewnictwa, LIV(2). (in Polish).
[4] Ananthanarayanan, L., Samuel, F. & Gruzelski, J. (1992). Thermal analysis studies of the effect of cooling rate on the microstructure of 319 aluminium alloy. AFS Trans., 100, 383-391.
[5] Thompson, S., Cockcroft, S. & Wells, M. (2004). Advanced high metals casting development solidification of aluminium alloy A356. Materials Science and Technology, 20, 194-200.
[6] Jordon, L.W.J.B. (2011). Monotonic and cyclic characterization of five different casting process on a common magnesium alloy. Inte Natl, Manuf. Sci. Eng. Conf. MSE. Proceeding ASME.
[7] Jorstad, J. & Rasmussen, W. (1997). Aluminium science and technology. American Foundry Society. (368), 204-205.
[8] Weiss, D., Grassi, J., Schultz, B. & Rohagti, P. (2011). Ablation of hybrid metal matrix composites. Transactions of American Foundry Society. (119), 35-42.
[9] Taghipourian, M., Mohammadalihab, M., Boutorabic, S. & Mirdamadic, S. (2016). The effect of waterjet beginning time on the microstructure and mechanical properties of A356 aluminium alloy during the ablation casting process. Journal of Materials Processing Technology. 238, 89-95. DOI: https://doi.org/10.1016/j.jmatprotec.2016.05.004
[10] Rooy, E., Van Linden, J. (2015). ASM Metals Handbook, Properties and Selection: Nonferrous Alloys and Special-Purpose Materials. 2, 3330-3345.
[11] Bohlooli, V., Shabani Mahalli, M. & Boutorabi, S. (2013). Effect of ablation casting on microstructure and casting properties of A356 aluminium casting alloy. Acta Metallurgica Sininca (English letters). 26(1), 85-91.
[12] Grassi, J., Campbell, J. (2010). Ablation casting. A Technical paper, pp. 1-9.
[13] Jordon, L. (2011). Characterization of five different casting process on a common magnesium alloy. Inte Natl, Manuf. Sci. Eng. Conf. MSEC. Proceeding ASME.
[14] Wang, L., Lett, R. (2011). Microstructure characterization of magnesium control ARM castings. Shape Casting, pp. 215-222.
[15] Yadav , S., Gupta, N. (2017). Ablation casting process – an emerging process for non ferrous alloys. International Journal of Engineering, Technology, Science and Research. 4(4).
[16] Acura. (2015). Ablation Casting. Retrieved from: https://www.acura.com/performance/modals/ablation-casting
[17] Honda. (2015). New technical details next generation nsx revealed at SAE 2015 World Congress. Retrieved from: https://honda.did.pl/pl/samochody/nasza-firma/aktualnosci/450-nowe-szczegoly-techniczne-dot-kolejnej-generacji-modelu-nsx-ujawnione-na-sae-2015-world-congr.html
[18] Technology, F.M. (2015). Ablation-cast parts debut on new acura NSX. Retrieved from: https://www.foundrymag.com/meltpour/ablation-cast-parts-debut-new-acura-nsx
[19] Holtzer, M. (2002). Development directions of molding and core sand with inorganic binders in terms of reducing the negative impact on the environment. Archives of Foundry. 2(3), 50-56. (in Polish).
[20] Major-Gabryś K. (2016). Environmentally friendly foundry molding and core sand. Kraków: Archives of Foundry Engineering. (in Polish)
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Authors and Affiliations

S. Puzio
1
ORCID: ORCID
J. Kamińska
1
ORCID: ORCID
K. Major-Gabryś
2
ORCID: ORCID
M. Angrecki
1
ORCID: ORCID

  1. ŁUKASIEWICZ Research Network - Foundry Research Institute, Zakopianska 73, 30-418 Cracow, Poland
  2. AGH University of Science and Technology, Faculty of Foundry Engineering, Mickiewicza 30, 30-059 Cracow, Poland
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Abstract

The aim of this study is to demonstrate the possibility of using moulding sands based on inorganic binders hardened in a microwave chamber in the technology of ablation casting of aluminium alloys. The essence of the ablation casting technology consists in this that a mould with a water-soluble binder is continuously washed with water immediately after being poured with liquid alloy until its complete erosion takes place. The application of an environmentally friendly inorganic binder improves the ecology of the whole process, while microwave hardening of moulding sands allows moulds to be made from the sand mixture containing only a small amount of binder.

The studies described in this article included microwave-hardened sand mixtures containing the addition of selected inorganic binders available on the market. The strength of the sands with selected binders added in an amount of 1.0; 1.5 and 2.0 parts by mass was tested. As a next step, the sand mixtures with the strength optimal for ablation casting technology, i.e. about 1.5 MPa, were selected and tested for the gas forming tendency. In the four selected sand mixtures, changes occurring in the samples during heating were traced. Tests also included mould response to the destructive effect of ablation medium, which consisted in the measurement of time necessary for moulds to disintegrate while washed with water. Tests have shown the possibility of using environmentally friendly, microwave-hardened moulding sands in ablation casting of aluminium alloys.

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Authors and Affiliations

S. Puzio
ORCID: ORCID
J. Kamińska
ORCID: ORCID
M. Angrecki
ORCID: ORCID
K. Major-Gabryś
ORCID: ORCID
Download PDF Download RIS Download Bibtex

Abstract

The ablation casting technology consists in pouring castings in single-use moulds made from the mixture of sand and water-soluble binder. After pouring the mould with liquid metal the mould is destructed (washed out) using a stream of cooling medium, which in this case is water. The process takes place while the casting is still solidifying.

The following paper focuses on testing the influence of the modified ablation casting of aluminum alloy on casts properties produced in moulds with hydrated sodium silicate binder. The authors showed that the best kind of moulding sands for Al alloy casting will be those hardened with physical factors – through dehydration. The analysis of literature data and own research have shown that the moulding sand with hydrated sodium silicate hardened by dehydration is characterized by sufficient strength properties for the modified ablation casting of Al alloys. In the paper the use of microwave hardened moulding sands has been proposed.

The moulds were prepared in the matrix specially designed for this technology. Two castings from the AlSi7Mg alloy were made; one by traditional gravity casting and the other by gravity casting using ablation.

The conducted casts tests showed that the casting made in modified ablation casting technology characterizes by higher mechanical properties than the casting made in traditional casting technology. In both experimental castings the directional solidification was observed, however in casting made by ablation casting, dimensions of dendrites in the structure at appropriate levels were smaller.

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Authors and Affiliations

K. Major-Gabryś
ORCID: ORCID
M. Hosadyna-Kondracka
ORCID: ORCID
S. Puzio
ORCID: ORCID
J. Kamińska
ORCID: ORCID
M. Angrecki
ORCID: ORCID
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Abstract

Ablation casting is a technological process in which the increased cooling rate causes microstructure refinement, resulting in improved mechanical properties of the final product. This technology is particularly suitable for the manufacture of castings with intricate shapes and thin walls. Currently, the ablation casting process is not used in the Polish industry. This article presents the results of strength tests carried out on moulding sands based on hydrated sodium silicate hardened in the Floster S technology, intended for ablation casting of the AlSi7Mg (AK7) aluminium alloy. When testing the bending and tensile strengths of sands, parameters such as binder and hardener content were taken into account. The sand mixtures were tested after 24h hardening at room temperature. The next stage of the study describes the course of the ablation casting process, starting with the manufacture of foundry mould from the selected moulding mixture and ending in tests carried out on the ready casting to check the surface quality, structure and mechanical properties. The results were compared with the parallel results obtained on a casting gravity poured into the sand mould and solidifying in a traditional way at ambient temperature.

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Authors and Affiliations

J. Kamińska
ORCID: ORCID
M. Angrecki
ORCID: ORCID
S. Puzio
ORCID: ORCID
M. Hosadyna-Kondracka
ORCID: ORCID
K. Major-Gabryś
ORCID: ORCID

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