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Abstract

Geopolymer is synthesized by polycondensation of SiO4 and AlO4 aluminosilicate complexes, tetrahedral frames linked with shared sialate oxygen. This paper studies the effect of the solids-to-fluids (S/L) and Na2SiO3/NaOH proportions on the preparing of metakaolin inorganic membrane geopolymer. By consolidating a mixture of metakaolin with sodium hydroxide, sodium silicate and foaming agent, the geopolymer membrane was made in required shape about 1 cm and cured at 80°C for 24 hours. After the curing process, the properties of the samples were tested on days 7. Sodium silicate (Na2SiO3) and sodium hydroxide (NaOH) solution were utilized as an alkaline activator with a NaOH fixation fixed at 10 M. The geopolymer inorganic membrane tests were set up with various S/L proportions (0.8, 1.0, 1.2 and 1.4) and Na2SiO3/NaOH proportions (0.5, 1.0, 1.5, 2.0 and 2.5). Aluminium (Al) powder as a foaming agent was used to create bubbles in porous structure and provide details on the development of membrane geopolymers. This metakaolin membrane, based on the geopolymer, was synthesized by a suspension that depends on the fast cementing mechanism of high-temperature slurries. Porous geopolymeric circles provided a homogeneous composition and quantitative distribution of pores. The water absorption, density, impact toughness testing and microstructure analyses were studied. However, considering the promising results, an adjustment in the mix design of the metakaolin inorganic membrane geopolymer mixtures could increase their mechanical properties without negatively affecting the mechanical properties and porosity, making these sustainable materials a suitable alternative to traditional porous cement concrete.
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Authors and Affiliations

Masdiyana Ibrahim
1 2
ORCID: ORCID
Wan Mastura Wan Ibrahim
2 3
ORCID: ORCID
Mohd Mustafa Al Bakri Abdullah
1 2
ORCID: ORCID
Ahmad Syauqi Sauffi
1 2
ORCID: ORCID
Petrica Vizureanu
4
ORCID: ORCID

  1. Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, 02100, Padang Besar, Perlis, Malaysia
  2. Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CeGeoGTech), 02600, Arau, Perlis, Malaysia
  3. Universiti Malaysia Perlis (UniMAP), Faculty of Mechanical Engineering Technology, 02600, Arau, Perlis, Malaysia
  4. Gheorghe Asachi Technical University of Iasi, Faculty of Materials Science and Engineering, 700050, Iasi, Romania
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Abstract

Geopolymer is widely studied nowadays in various scope of studies. Some of the ongoing studies are the study of the various materials towards the geopolymer strength produced. Meanwhile, some of the studies focus on the mixing of the geopolymer itself. This paper discussed the phase analysis of metakaolin/dolomite geopolymer for different solid to the liquid ratio which was, 0.4, 0.6, 0.8, and 1.0, and the properties that affected the geopolymer based on the phases. The constant parameters in this study were the percentage of metakaolin and dolomite used. The metakaolin used was 80% meanwhile dolomite usage was 20%. Besides that, the molarity of NaOH used is 10M and the alkaline activator ratio used is 2.0. All the samples were tested at 28 days of curing. The results show that the 0.8 solid to the liquid ratio used gave better properties compare to other solid to liquid ratio. The phases analyzed were quartz, sillimanite, mullite, and faujasite. The 0.8 S/L ratio shows the better properties compared to others by the test of phase analysis, compressive strength morphology analysis, and functional group analysis.
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Authors and Affiliations

Ahmad Syauqi Sauffi
1
ORCID: ORCID
Wan Mastura Wan Ibrahim
1
ORCID: ORCID
Mohd Mustafa Al Bakri Abdullah
2
ORCID: ORCID
Masdiyana Ibrahim
1
ORCID: ORCID
Romisuhani Ahmad
1
ORCID: ORCID
Fakhryna Ahmad Zaidi
1
ORCID: ORCID

  1. Universiti Malaysia Perlis (UniMAP), Faculty of Engineering Technology, P. O. Box 77, d/a Pejabat, Pos Besar, 01007 Kangar, Perlis, Malaysia
  2. Universiti Malaysia Perlis (UniMAP), Centre of Excellence Geopolymer and Green Technology, School of Material Engineering, P. O. Box 77, d/a Pejabat, Pos Besar, 01007 Kangar, Perlis, Malaysia

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