In the work results of research on electrodischarge machining (EDM) of titanium alloy Ti10V2Fe3Al with (α + β) structure were presented. Preliminary heat treatment of samples allows to obtain different morphology and volume fraction of the α phase. The main goal of research was to assessment of the material microstructure impact on EDM technological factors (ie. material removal rate, tool wear) and morphology of technological surface layer. Electrodischarge machining is alternative and increasingly used method of titanium alloys machining. Research allowed to indicate the possibilities and limitations of use EDM in this area. It is especially important in the aspect of parts produced for aircraft industry and related requirements for the technological surface layer quality.