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Abstract

The paper reports the study of the complexation processes in aqueous solution of α-CD and DMSO. Cyclodextrins (CDs) (sometimes called cycloamyloses) are cyclic oligosaccharides formed by glucose units interconnected by α-(1,4) linkages; α-CD is one of three the most common CDs. It consists of six glucopyranose units. The speed of ultrasonic waves has been measured by the resonance method on ResoscanTM System apparatus. Some collateral data, such as density and heat capacity of the system, have also been measured. On the basis of the experimental data the excess adiabatic compressibility was determined. The extremes of the excess adiabatic compressibility function for different mixture compositions allowed us to establish the composition of molecular complexes formed in the solution. The obtained results suggest the formation of the α-CD with DMSO inclusion complexes with chemical stoichiometric ratio value of 1:1.
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Authors and Affiliations

Milena Kaczmarek-Klinowska
Tomasz Hornowski
Andrzej Skumiel
Monika Jażdżewska
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Abstract

The temperature dependence of the particle size distribution (PSD) of the magnetic fluid with an additional biocompatible dextran layer was studied using a ultrasonic method. The measurements of the ultrasound velocity and attenuation were carried out as a function of the volume concentration of magnetite particles at temperatures ranging from 15°C to 40°C. In order to extract the PSD from ultrasonic measurements, the theoretical model of Vinogradov-Isakovich was used. The extraction of PSD from the ultrasonic data requires also the measurements the density and viscosity of the ferrofluid samples. The calculated PSD of the magnetic fluid with an additional biocompatible layer shows a greater thermal stability than that of a magnetic fluid with a single surfactant layer.
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Authors and Affiliations

Leszek Dąbek
Tomasz Hornowski
Arkadiusz Józefczak
Andrzej Skumiel
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Abstract

Ultrasonic emulsifying processes of immiscible liquids can be used to obtain stable emulsions. The authors used an ultrasonic sandwich head with an energy concentrator to obtain a suitable value of the energy density necessary for the emerge of ultrasonic cavitation. Two piezoelectric ring (Dext = 50 mm) transducers of Pz-26 type produced by FERROPERM were used to design the ultrasonic sandwich head. The frequency of the ultrasonic wave was 18.4 kHz and the excitation time of the ultrasonic transducer exiting 5 minutes. Visible bubbles during the generation of ultrasonic waves appeared in the mixture after exceeding the cavitation threshold. The authors determined also the cavitation threshold by measuring the electrical voltage conducted to the transducers. To receive long-lasting emulsion, the electrical voltage attained 300 Vpeak. The dispersion dependence on the emulsifying time was determined. The emulsion of linseed oil and water was stable through some months without surfactants.
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Authors and Affiliations

Andrzej Skumiel
Arkadiusz Józefczak
Krzysztof Heller
Tomasz Hornowski
Katarzyna Wielgusz

Authors and Affiliations

Krzysztof Klimaszewski
Sebastian Borucki
Jacek Łuczak
Dariusz Zmarzły
Michał Kunicki
Andrzej Cichoń
Franciszek Witos
Czesław Leśnik
Dariusz Pleban
Milan Timko
Tomasz Rogala
Piotr Serafin
Tadeusz Gudra
Jerzy Filipiak
Dariusz Banasiak
Krzysztof Herman
Krzysztof Opieliński
Tomasz Hejczyk
Krzysztof Jasek
Mateusz Pasternak
Michał Grabka
Witold Kardyś
Andrzej Milewski
Adam Kawalec
Marta Okoń-Fąfara
Bartłomiej Fąfara
Aneta Olszewska
Piotr Pruchnicki
Marcin Wrzosek
Józef Nicpoń
Przemysław Podgórski
Tadeusz Pustelny
Marcin Szugajew
Olga Stec
Grzegorz Szerszeń
Daria Wotzka
Agnieszka Boruń
Adam Bald
Marzena Dzida
Sylwia Jężak
Monika Geppert-Rybczyńska
Katarzyna Kaczmarek
Tomasz Hornowski
Arkadiusz Józefczak
M. Kubovčíková
A. Skumiel
Z. Rozynek
M. Timko
Peter Kopcansky
Bogumił Linde
Vyacheslav N. Verveyko
Marina V. Verveyko
Darya V. Verveyko
Andrey Yu. Verisokin
Nikita S. Chebrov
Witold Mikulski
Danuta Augustyńska
Bożena Smagowska

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