Y and V codoped SrBi ₂Nb ₂O ₉ ceramics, which have been characterized by XRD, FTIR and SEM techniques, were prepared through molten salt using NaCl-KCl medium. Through X-ray diffraction analysis, all prepared samples were matched by undoped SrBi ₂Nb ₂O ₉. The lattice parameters do not depend on the amount of dopants. Under the optimized experimental conditions, the compounds are composed of small crystallites of varying size and orientation, resulting in many micros train defects. FTIR spectra revealed that the dopant promotes a slight decrease in the 612 cm ^–1 band. A plate-like morphology was revealed by scanning electron microscopy, while Nyquist plots indicate non-Debye relaxation for all compounds. V and Y were incorporated into SrBi ₂Nb ₂O ₉ lattice in order to reduce dielectric loss tangent. Thus, the codoping increases the of SrB _1.9Y _0.1Nb _1.95V _0.05O ₉ (Y0.1V0.05) ceramic whereas, they were significantly decreased in the case of SrBi _1.8Y _0.2Nb ₂O ₉ (Y0.2) ceramic. Y0.1V0.05 sample makes up the highest efficient charge transfer, followed by Y0.2 sample representing the lowest.

In this study, Strontium Bismuth Niobate (SrBi2-xTmxNb2O9 with 0 ≤ x ≤ 0.1) doped by Tm was synthesized using by the hydrothermal method. The microstructure and electrical properties were mainly investigated. XRD analysis showed a single-phase orthorhombic structure for Tm-doped SrBi2Nb2O9 samples. The crystallite size is anisotropic and the strain is apparently independent of Tm amount. Dielectric properties for doped SrBi2Nb2O9 with Tm3+ ion have the same trend discussed for the pure sample. FTIR resulats showed that NbO6 octahedral is formed, on one hand, and on the other hand, it shows that spectras for doped and undoped samples are nearly the same. The Cross-section of ceramics showed the plate-like morphology, also the distribution of the pore in ceramics are observed for all samples. Tm dopants produce only minor changes in the impendence parameter values at room temperature. The luminescent (PL) properties of Tm-doped SrBi2Nb2O9 ceramic powders were investigated. The optimum Tm3+ concentration for the maximum PL intensity was found to be at x = 0.075.