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Abstract

Binary vapour-liquid equilibrium of thymoquinone and carbon dioxide at the isothermal conditions was carried out at temperature 323.15 K and pressures from 6 to 10 MPa. The experimental data were fitted to the Soave-Redlich-Kwong equation of state. Results could be used for selection of process parameters in separation of volatiles from raw oil or for evaluation of existing separation technologies.

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Authors and Affiliations

Karina Gurgenova
Rafał Bogeł-Łukasik
Paweł Wawrzyniak
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Abstract

Chemical heat pumps (CHP) use reversible exothermal and endothermal chemical reactions to increase the temperature of working fluids. In comparison to the “classical” vapour compression chemical heat pumps, CHP enables us to achieve significantly higher temperatures of a heated medium which is crucial for the potential application, e.g. for production of superheated steam. Despite the advantages presented, currently, there are no installations using CHP for lowgrade waste heat recovery available on the market. The scaling up of industrial processes is still one of the greatest challenges of process engineering. The aim of the theoretical and experimental concept study presented here was to evaluate a method of reclaiming energy from low temperature waste streams and converting it into a saturated steam of temperature from 120 to 150 ◦C, which can be useful in industry. A chemical heat pump concept, based on the dilution and concentration of phosphoric acid, was used to test the method in the laboratory scale. The heat of dilution and energy needed for water evaporation from the acid solutionwere experimentally measured. The cycle of successive processes of dilution and concentration has been experimentally confirmed. A theoretical model of the chemical heat pump was tested and coefficient of performance measured.

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Authors and Affiliations

Marzena Czapnik
Michał Tylman
Maciej Jaskulski
Paweł Wawrzyniak
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Abstract

Fresh water is essential for life. More and more countries around the world are facing scarcity of drinking water, which affects over 50% of the global population. Due to human activity such as industrial development and the increasing greenhouse effect, the amount of drinking water is drastically decreasing. To address this issue, various methods of sea and brackish water desalination are used. In this study, an energy analysis (specific energy consumption, SEC) of two laboratory membrane processes, reverse osmosis (RO) and pervaporation (PV), was conducted. A model feed system saline water at 0.8, and 3.5% wt. NaCl was used. The efficiency and selectivity of membranes used in PV and RO were examined, and power of the devices was measured. The desalination processes were found to have a high retention factor (over 99%) for both PV and RO. For PV, the permeate fluxes were small but they increased with increasing feed flow rate, process temperature and salt content in the feed. The calculated SEC values for both laboratory processes ranged from 2 to 70 MWh/m 3. Lowering the process temperature, which consumes 30 to 60% of the total energy used in the PV process, can be an important factor in reducing energy consumption.
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Authors and Affiliations

Izabela Gortat
1
ORCID: ORCID
Joanna Marszałek
1
ORCID: ORCID
Paweł Wawrzyniak
1

  1. Lodz University of Technology, Faculty of Process and Environmental Engineering, Wólczańska 213, 93-005 Łódź, Poland

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