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Abstract

This study investigates the corrosion characteristics of Q235 steel and 16Mn steel in the sulfur-containing alkaline solution. The composition and the morphology of the corrosion products were analyzed by XPS and SEM respectively. The electrochemical behavior of Q235 steel and 16Mn steel was evaluated by potentiodynamic polarization curve and EIS. The results indicated that the corrosion rate of Q235 steel is greater than 16Mn steel in the early corrosion. Pitting and selective corrosion appeared on the surface of the two steels, and the surface product layer was granular and defective. XPS and EDS indicate that the structurally stable iron oxide is formed on the surface of the two steels. Electrochemical results show the corrosion kinetics of Q235 steel and 16Mn steel are simultaneously controlled by the charge transfer and ion diffusion, and the formation mechanism of corrosion products was clarified.
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Authors and Affiliations

Bianli Quan
1
ORCID: ORCID
Zhiping Xie
2
ORCID: ORCID

  1. Guizhou University, College of Materials and Metallurgy, Guiyang, 550025, China
  2. Guizhou Normal University, School of Mechanical & Electrical Engineering, Guiyang, 550025, China
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Abstract

In order to identify the influence of different Mn, Cd, V and Zr content on the properties of Al-Cu casting alloys in hydraulic valves, orthogonal test methods were used to prepare alloy test bars with different elements and contents. Tensile tests were performed on the test bars so obtained. The microstructure of alloys with different compositions is studied. The results show that adding approximately 0.4% of Mn can not only form a strengthening phase but also reduce the excessive segregation of the matrix along the grain boundary. A Cd content of 0.2% can promote the formation of micro Cd spheres in the softer aluminum matrix. Hard spots increase the wear resistance of the material; however, an excess of Cd will cause element segregation and deteriorate the mechanical properties of the valve body. Zr and V refine the grains in the alloy; however, an excess of these elements will lead to a large area of segregation. If proper heat treatment is lacking, the mechanical properties of the valve body deteriorate.

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Authors and Affiliations

Rong Li
ORCID: ORCID
Lunjun Chen
Qi. Zeng
ORCID: ORCID
Ming Su
Zhiping Xie
ORCID: ORCID

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