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Abstract

In this study, cubic and cylindrical cement mortar specimens were first subjected to high temperatures, then the cubic and cylindrical specimens were taken out and conducted with uniaxial compressive test and splitting tensile test, respectively. The effect of the length to side ratio on the uniaxial compressive properties and the effect of thickness-to-diameter ratio on the splitting tensile properties of cement mortar specimens after high temperature were studied. Test results show that: (1) With temperature increasing from 25°C (room temperature) to 400°C, the compressive strength and elastic modulus of cubic specimens with three kinds of side lengths decrease; the decreasing rates of compressive strength and elastic modulus of cubic specimen with side length of 70.7 mm is higher than those of cubic specimens with side length of 100 mm and 150 mm, and the strain at the peak stress of cubic specimens with three kinds of side lengths increase. (2) After the same temperature, the tensile strength of cylindrical specimen decreases with the thickness-to-diameter ratio increasing from 0.5 to 1.0. The decreasing rate of tensile strength of cylindrical specimen with thickness-to-diameter ratio is highest when the temperature is 25°C (room temperature), followed by that after the temperature of 200°C, and that after the temperature of 400°C is the lowest.

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Authors and Affiliations

L.X. Xiong
X.J. Zhang
Z.Y. Xu
D.X. Geng
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Abstract

The effects of Mg and Ca on sulfide modification of sulphur steel were studied to elucidate the difference between micromagnesium treatment and micro-calcium treatment for the inclusion of sulphur steel. The results show that the inclusions in the steel appeared with an oxide core of Al2O3 and MnS wrapped. After the addition of Mg, the core was changed to spinel, and the MnS coating was changed to Mn-Mg-S. After Ca was added, the core was changed to Ca-Al-O, and the MnS coating was changed to Mn-Ca-S. The Mg content was higher than Ca content in the sulfides of the steel. Therefore, Mg was more effective than Ca in terms of sulfide modification with the same content of Mg and Ca in steel, but the yielding rate of Mg was lower than that of Ca. The Mg content in the oxide core was higher than Mg of the coating of the inclusions in the steel treated with Mg or Mg-Ca. In contrast, the Ca content in the oxide core was lower than Ca of the coating of the inclusions in the steel treated with Ca or Mg-Ca. MnS formed and precipitated during the melt solidification process. The complex sulfide (Mg-Mn-S) was precipitated around MgO·Al2O3 in the Mg treated steel during the cooling process. CaS inclusion was precipitated on the CaO·Al2O3 inclusions in the liquid Ca-treated steel. Thus, CaS was formed first, whereas MnS was formed during the cooling process, followed by the formation of complex sulfide (CaS+MnS), which finally precipitated around CaO·Al2O3 in the Ca-treated steel.

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Authors and Affiliations

J. Tian
T. Qu
D. Wang
H. Wang
Z. Xu
E. Xinrui

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